公开(公告)号：US20150051361A1

公开(公告)日：2015-02-19

申请号：US14526559

申请日：2014-10-29

Applicant: THE UNIVERSITY OF TOKYO ,  SHOWA DENKO K.K.

Inventor： Kyoko NOZAKI ,  Shingo ITO ,  Yoshikuni OKUMURA ,  Junichi KURODA

IPC: C08F18/02

CPC classification number: C08F18/02 ,  C08F110/02 ,  C08F210/02 ,  C08F210/06 ,  C08F216/08 ,  C08F218/02 ,  C08F220/10 ,  C08F226/02 ,  C08F4/80 ,  C08F2500/03 ,  C08F214/02 ,  C08F214/00

Abstract: The present invention relates to a method for producing a high-molecular-weight copolymer of polar group-containing allyl monomers including monomer units represented by formulae (3) and (4) (in the formulae, R1 represents a hydrogen atom (H) or hydrocarbon group having 1 to 6 carbon atoms; R2 represents —OH, —OCOR3 (R3 represents hydrocarbon group having 1 to 5 carbon atoms), —N(R4)2 (R4 represents a hydrogen atom or hydrocarbon group having 1 to 5 carbon atoms); and n and m are a value representing the molar ratio of each of the monomer units), which has few branches and unsaturated group at the molecular end, by copolymerizing olefin and an allyl compound using a metal complex of group 10 elements in the periodic system represented by formula (I) as a catalyst

Abstract translation: 本发明涉及包含由式（3）和（4）表示的单体单元的含极性基团的烯丙基单体的高分子量共聚物的制造方法（式中，R1表示氢原子（H）或 具有1至6个碳原子的烃基; R 2表示-OH，-OCOR 3（R 3表示具有1至5个碳原子的烃基），-N（R 4）2（R 4表示氢原子或具有1至5个碳原子的烃基 ）; n和m是表示分子末端具有很少分支和不饱和基团的单体单元的摩尔比的值，通过使用第10族元素的金属络合物使烯烃和烯丙基化合物共聚， 由式（I）表示的周期性体系作为催化剂