公开(公告)号：US5807961A

公开(公告)日：1998-09-15

申请号：US860013

申请日：1997-06-20

申请人： Toshiya Sawai ,  Masaaki Yazawa ,  Seiji Oikawa ,  Shizuo Murata ,  Masaharu Hayakawa ,  Etsuo Nakagawa

发明人： Toshiya Sawai ,  Masaaki Yazawa ,  Seiji Oikawa ,  Shizuo Murata ,  Masaharu Hayakawa ,  Etsuo Nakagawa

IPC分类号： C08G73/10 ,  C09K19/30 ,  G02F1/1337

CPC分类号： C09K19/3001 ,  C08G73/101 ,  C08G73/1014 ,  C08G73/1017 ,  C08G73/1042 ,  C08G73/106 ,  G02F1/133723 ,  Y10T428/31721

摘要： This invention is directed to a polyimide film useful as use applications for electronic materials; a liquid crystal aligning film using the same; a liquid crystal display element provided with the liquid crystal aligning film; and a polyamic acid used as a raw material of the polyimide constituting the polyimide film. The polyimide used for preparing the above polyimide films, consists of a diamine component, the 50% by mol or more based upon the total diamine, of which is a diamine having a core structure having no polar group such as 1,2-bis(4-(4-aminobenzyl)phenyl)ethane, 1,6-bis(4-(4-aminobenzyl)phenyl)hexane, 1,1-bis(4-(4-aminobenzyl)phenyl)heptane, etc., and a tetracarboxylic acid dianhydride, and if necessary, an aminosilicon compound, is used as a liquid crystal aligning film.

摘要翻译： PCT No.PCT / JP96 / 03029 Sec。 371日期：1997年6月20日 102（e）日期1996年6月20日PCT 1996年10月17日PCT公布。 第WO97 / 14742号公报 日期1997年04月24日本发明涉及可用作电子材料用途的聚酰亚胺膜; 使用其的液晶取向膜; 设置有液晶取向膜的液晶显示元件; 和作为构成聚酰亚胺膜的聚酰亚胺的原料的聚酰胺酸。 用于制备上述聚酰亚胺膜的聚酰亚胺由二胺组分组成，基于总二胺的50摩尔％以上，其为具有不具有极性基团的核心结构的二胺，例如1,2-双（ 4-（4-氨基苄基）苯基）乙烷，1,6-双（4-（4-氨基苄基）苯基）己烷，1,1-双（4-（4-氨基苄基）苯基）庚烷等， 四羧酸二酐，如果需要，使用氨基硅化合物作为液晶取向膜。

公开(公告)号：US5430195A

公开(公告)日：1995-07-04

申请号：US328463

申请日：1994-10-25

申请人： Minoru Nakayama ,  Toshiya Sawai ,  Shizuo Murata

发明人： Minoru Nakayama ,  Toshiya Sawai ,  Shizuo Murata

IPC分类号： C07C217/90 ,  C08G73/10 ,  G02F1/1337 ,  C07C205/35 ,  C07C217/14

CPC分类号： C08G73/105 ,  C07C217/90 ,  G02F1/133723 ,  C07C2101/14 ,  Y10T428/1014 ,  Y10T428/1027

摘要： The present invention is to provide new diamino compounds useful for raw materials for production of liquid crystal aligning films that have excellent aligning properties and uniform and high pretilt angles over the whole display surface of wide substrates without afterimage phenomenons. The liquid crystal aligning films are constituted by a certain polyimide having as a principal constituent a structure unit represented by the formula; ##STR1##

公开(公告)号：US5414126A

公开(公告)日：1995-05-09

申请号：US141600

申请日：1993-10-27

申请人： Minoru Nakayama ,  Toshiya Sawai ,  Shizuo Murata

发明人： Minoru Nakayama ,  Toshiya Sawai ,  Shizuo Murata

IPC分类号： C07C217/90 ,  C08G73/10 ,  G02F1/1337 ,  C07C217/14

CPC分类号： C08G73/105 ,  C07C217/90 ,  G02F1/133723 ,  C07C2101/14 ,  Y10T428/1014 ,  Y10T428/1027

摘要： The present invention is to provide new diamino compounds useful for raw materials for production of liquid crystal aligning films that have excellent aligning properties and uniform and high pretilt angles over the whole display surface of wide substrates without afterimage phenomenons. The liquid crystal aligning films are constituted by a certain polyimide having as a principal constituent a structure unit represented by the formula; ##STR1##

摘要翻译： 本发明提供新的二氨基化合物，其用于生产液晶取向膜的原料，其具有优异的取向性能，在宽的基材的整个显示表面上具有均匀且高的预倾角，而没有残留图像现象。 液晶取向膜由具有下式表示的结构单元作为主要成分的某种聚酰亚胺构成; （4）

公开(公告)号：US06746730B1

公开(公告)日：2004-06-08

申请号：US10019260

申请日：2001-12-28

申请人： Satoshi Tanioka ,  Kumiko Fukui ,  Shizuo Murata ,  Hiroshi Ono ,  Itsuo Shimizu

发明人： Satoshi Tanioka ,  Kumiko Fukui ,  Shizuo Murata ,  Hiroshi Ono ,  Itsuo Shimizu

IPC分类号： C09K1900

CPC分类号： G02F1/133723 ,  C08L79/08 ,  C08L2205/02 ,  C09D179/08 ,  C09K19/3001 ,  C09K19/56 ,  Y10T428/10 ,  Y10T428/31721 ,  C08L2666/20

摘要： A varnish composition which comprises a solvent and a polymer component comprising a polyamic acid (B) (having residues which are derived from tetracarboxylic acids and a diamine respectively and which are residues having no side chains or residues having a pendant C1-2 alkyl group or are residues having a composition comprising a mixture of these), a polyamic acid (A) (having residues which are derived from tetracarboxylic acids and a diamine respectively and at least either of which is a residue having a pendant C3+ alkyl group or is a residue having a composition containing that residue), and a soluble polyimide, and in which the proportion of the polyamic acid (A) to the soluble polyimide is 1/99 to 99/1 by weight, the, sum of the polyamic acid (A) and the soluble polyimide accounts for 1 to 80 wt. % of the polymer component, the polyamic acid (B) accounts for 99 to 20 wt. % of the polymer component, and the proportion of the polymer component in the whole varnish composition is 0.1 to 40 wt. %. Also provided is a liquid-crystal display element having an alignment film formed from this varnish composition.

摘要翻译： 一种清漆组合物，其包含溶剂和聚合物组分，所述聚合物组分包含聚酰胺酸（B）（具有衍生自四羧酸的残基和分别为残基且不具有侧链的残基或具有C1-2烷基侧基的残基或 是具有包含这些的混合物的组合物的残基），聚酰胺酸（A）（具有衍生自四羧酸的残基和分别具有二胺的残基，并且其中至少任一个是具有C3 +烷基侧基的残基或残基 具有含有该残基的组合物）和可溶性聚酰亚胺，其中聚酰胺酸（A）与可溶性聚酰亚胺的比例为1/99〜99/1，聚酰胺酸（A） 可溶性聚酰亚胺占1〜80wt。 ％的聚合物组分，聚酰胺酸（B）占99至20wt。 ％的聚合物组分，并且聚合物组分在整个清漆组合物中的比例为0.1至40重量％。 ％。 还提供了具有由该清漆组合物形成的取向膜的液晶显示元件。

公开(公告)号：US5625475A

公开(公告)日：1997-04-29

申请号：US429102

申请日：1995-04-26

申请人： Satoshi Tanioka ,  Shizuo Murata ,  Makoto Kono ,  Masayuki Hirano

发明人： Satoshi Tanioka ,  Shizuo Murata ,  Makoto Kono ,  Masayuki Hirano

IPC分类号： G02F1/1337

CPC分类号： G02F1/133711 ,  G02F1/13378 ,  G02F1/133784 ,  G02F1/133788 ,  Y10T428/1005

摘要： A method for treating an aligning film for a liquid crystal display element wherein an aligning film consisting of an organic high molecular compound formed on a transparent substrate with a transarent electrode is subjected to a robbing treatment and thereafter said aligning film is irradiated with soft X-rays in a gas.A method for preparing a liquid crystal display element comprising the steps of arranging a transparent electrode on a pair of transparent substrates, forming an aligning film consisting of an organic high molecular compound on the said transparent electrode, treating said aligning film by a rubbing treatment, assembling the substrates to face each other with a spacer disposed therebetween, and then applying and sealing to a substrate a liquid crystal material wherein the aligning film is subjected to a robbing treatment and thereafter said aligning film is irradiated with soft X-rays in gas.

摘要翻译： 一种用于液晶显示元件的取向膜的处理方法，其中将由在透明基板上形成的有机高分子化合物与末端电极组成的取向膜进行抢夺处理，然后用软X射线照射所述取向膜， 气体中的光线 一种制备液晶显示元件的方法，包括以下步骤：在一对透明基板上设置透明电极，在所述透明电极上形成由有机高分子化合物组成的取向膜，通过摩擦处理处理所述取向膜， 将基板组装成彼此面对的间隔件，然后对基板施加并密封其中对准膜进行抢劫处理的液晶材料，然后用气体中的软X射线照射所述取向膜。

公开(公告)号：US06949281B1

公开(公告)日：2005-09-27

申请号：US10018540

申请日：2000-06-26

申请人： Satoshi Tanioka ,  Kumiko Fukui ,  Shizuo Murata ,  Hiroshi Ono ,  Itsuo Shimizu

发明人： Satoshi Tanioka ,  Kumiko Fukui ,  Shizuo Murata ,  Hiroshi Ono ,  Itsuo Shimizu

IPC分类号： C08L79/08 ,  C09K19/30 ,  G02F1/1337 ,  C09K19/00

CPC分类号： C09K19/3001 ,  C08L79/08 ,  G02F1/133723 ,  Y10T428/24223

摘要： An object of the present invention is to provide a varnish composition which can achieve totally and with good balance the improvement in various properties including electrical properties such as residual charge, a voltage holding ratio and image sticking, a pre-tilt angle, coating property, alignment property, and so on, which are desired for a liquid crystal aligning film formed. The varnish composition comprises polymer ingredients containing polyamic acid B represented by formula (1), polyamic acid A represented by formula (2) having a side chain of not less than 3 carbon atoms and N-substituted polyamide represented by formula (3), and a solvent for dissolving the polymer ingredients. The varnish composition contains 0.1 to 40% by weight of the polymer ingredients

摘要翻译： 本发明的目的是提供一种清漆组合物，其可以完全平衡地获得各种性能的改进，包括电性能如残留电荷，电压保持率和图像粘附，预倾角，涂布性能， 取向性等，这对于形成的液晶取向膜是期望的。 清漆组合物包含含有式（1）表示的聚酰胺酸B，侧链不少于3个碳原子的式（2）表示的聚酰胺酸A和由式（3）表示的N-取代聚酰胺的聚合物成分，以及 用于溶解聚合物成分的溶剂。 清漆组合物含有0.1-40重量％的聚合物成分

公开(公告)号：US06322956B1

公开(公告)日：2001-11-27

申请号：US09284750

申请日：1999-04-20

申请人： Satoshi Tanioka ,  Shizuo Murata ,  Makoto Kono ,  Masayuki Hirano

发明人： Satoshi Tanioka ,  Shizuo Murata ,  Makoto Kono ,  Masayuki Hirano

IPC分类号： G02F11337

CPC分类号： G02F1/13378 ,  B05C9/14 ,  G02F1/133784 ,  G02F1/133788 ,  Y10S430/168

摘要： Disclosed is a method for producing liquid crystal display devices comprising a step for forming a transparent electrode and a circuit element of semiconductor on the surface of a pair of transparent substrates, and various steps for applying a photoresist, exposing to the light, etching, releasing the photoresist, inspecting the electrodes and circuit elements of semiconductor, forming an insulating film, forming an alignment film, rubbing the alignment film, spreading spacers, applying a sealing agent, fabricating a cell, filling a liquid crystal, pasting a polarizing plate, and connecting a driver IC characterized in that a soft X-ray is irradiated to the substrate in at least one step prior to the rubbing of the alignment films to produce liquid crystal display devices, at a high yield, in which devices number of pixel defect is small.

摘要翻译： 公开了一种用于制造液晶显示装置的方法，包括在一对透明基板的表面上形成透明电极和半导体的电路元件的步骤，以及用于施加光致抗蚀剂，暴露于光，蚀刻，释放的各种步骤 光致抗蚀剂，检查半导体的电极和电路元件，形成绝缘膜，形成取向膜，摩擦取向膜，铺展间隔物，施加密封剂，制造电池，填充液晶，粘贴偏光板和 连接驱动器IC，其特征在于，在摩擦定向膜之前至少一个步骤中将软X射线照射到基板上，以高产率制造液晶显示装置，其中像素缺陷的数量是 小。

公开(公告)号：US5798810A

公开(公告)日：1998-08-25

申请号：US738492

申请日：1996-10-28

申请人： Satoshi Tanioka ,  Shizuo Murata ,  Makoto Kono ,  Masayuki Hirano

发明人： Satoshi Tanioka ,  Shizuo Murata ,  Makoto Kono ,  Masayuki Hirano

IPC分类号： G02F1/1337

CPC分类号： G02F1/133711 ,  G02F1/13378 ,  G02F1/133784 ,  G02F1/133788 ,  Y10T428/1005

摘要： A method for treating an aligning film for a liquid crystal display element and a method for preparing a liquid crystal display element are proposed. The said treating method comprises rubbing a specified aligning film formed on a transparent substrate with a transparent electrode and thereafter radiating soft X-ray for 2 seconds or more in gas. The said preparing method comprises arranging a transparent electrode on a pair of transparent substrates, forming an aligning film consisting of an organic high molecular compound on the said transparent electrode, treating the said aligning film by a rubbing treatment, assembling the substrates face to face each other via a spacer, and then sealing a liquid crystal material. By a method for treating an aligning film according to the invention, it is possible to lower display unevenness of a liquid crystal display element and to improve an yield of product.

摘要翻译： 提出了一种用于液晶显示元件的取向膜的处理方法和液晶显示元件的制备方法。 所述处理方法包括用透明电极摩擦形成在透明基板上的指定取向膜，然后在气体中辐射软X射线2秒以上。 所述制备方法包括在一对透明基板上布置透明电极，在所述透明电极上形成由有机高分子化合物构成的取向膜，通过摩擦处理对所述取向膜进行处理，将基板面对每个 另一个通过间隔件，然后密封液晶材料。 通过根据本发明的对准膜的处理方法，可以降低液晶显示元件的显示不均匀性并提高产品的收率。

公开(公告)号：US06623913B2

公开(公告)日：2003-09-23

申请号：US09964660

申请日：2001-09-28

申请人： Satoshi Tanioka ,  Shizuo Murata ,  Makoto Kono ,  Masayuki Hirano

发明人： Satoshi Tanioka ,  Shizuo Murata ,  Makoto Kono ,  Masayuki Hirano

IPC分类号： G02F11337

CPC分类号： G02F1/13378 ,  B05C9/14 ,  G02F1/133784 ,  G02F1/133788 ,  Y10S430/168

摘要： Disclosed is a method for producing liquid crystal display devices comprising a step for forming a transparent electrode and a circuit element of semiconductor on the surface of a pair of transparent substrates, and various steps for applying a photoresist, exposing to the light, etching, releasing the photoresist, inspecting the electrodes and circuit elements of semiconductor, forming an insulating film, forming an alignment film, rubbing the alignment film, spreading spacers, applying a sealing agent, fabricating a cell, filling a liquid crystal, pasting a polarizing plate, and connecting a driver IC characterized in that a soft X-ray is irradiated to the substrate in at least one step prior to the rubbing of the alignment films to produce liquid crystal display devices, at a high yield, in which devices number of pixel defect is small.

摘要翻译： 公开了一种用于制造液晶显示装置的方法，包括在一对透明基板的表面上形成透明电极和半导体的电路元件的步骤，以及用于施加光致抗蚀剂，暴露于光，蚀刻，释放的各种步骤 光致抗蚀剂，检查半导体的电极和电路元件，形成绝缘膜，形成取向膜，摩擦取向膜，铺展间隔物，施加密封剂，制造电池，填充液晶，粘贴偏光板和 连接驱动器IC，其特征在于，在摩擦定向膜之前至少一个步骤中将软X射线照射到基板上，以高产率制造液晶显示装置，其中像素缺陷的数量是 小。

公开(公告)号：US5447759A

公开(公告)日：1995-09-05

申请号：US245630

申请日：1994-05-18

申请人： Shizuo Murata ,  Masaharu Hayakawa ,  Yukino Abe

发明人： Shizuo Murata ,  Masaharu Hayakawa ,  Yukino Abe

IPC分类号： C08K5/18 ,  C08K5/34 ,  C08K5/46 ,  C08L79/08 ,  G02F1/133 ,  G02F1/1337

CPC分类号： G02F1/133723 ,  Y10T428/1023 ,  Y10T428/31721

摘要： A liquid crystal alignment film and a liquid crystal display element are provided, according to which a phenomenon of afterimage is slight in the case of liquid crystal display elements of TN mode or STN mode, while a problem of printing phenomenon is solved and a good memory characteristic is obtained in the case of ferroelectric liquid crystal display elements,the liquid crystal alignment film and the liquid crystal display element being characterized in that at least one kind of compounds expressed by the following formula (2) or (3) is added into a liquid crystal alignment film consisting of a polyimide expressed by the following formula (1): ##STR1##

摘要翻译： 提供液晶取向膜和液晶显示元件，根据该液晶取向膜和液晶显示元件，在TN模式或STN模式的液晶显示元件的情况下，残像现象很小，同时解决了打印现象的问题和良好的存储器 在铁电液晶显示元件的情况下获得特征，液晶取向膜和液晶显示元件的特征在于，将至少一种由下式（2）或（3）表示的化合物加入到 （1）＆lt; IMAGE＆gt;（2）＆lt; IMAGE＆gt;（3）由下述式（1）表示的聚酰亚胺构成的液晶取向膜：