公开(公告)号：US20130010039A1

公开(公告)日：2013-01-10

申请号：US13544539

申请日：2012-07-09

申请人： Hiroaki Kida ,  Hiroshi Fukumoto ,  Toru Saito ,  Keitaro Nakano ,  Hiroki Nakane

发明人： Hiroaki Kida ,  Hiroshi Fukumoto ,  Toru Saito ,  Keitaro Nakano ,  Hiroki Nakane

IPC分类号： C09D11/10 ,  B41J2/01

CPC分类号： C09D11/101 ,  B41J2/2107 ,  B41J11/002 ,  C08K3/013 ,  C09D11/322 ,  C09D11/38

摘要： The present invention provides a photocurable ink composition for ink jet recording with excellent curability. The photocurable ink composition for ink jet recording includes polymerizable compounds, a photopolymerization initiator, and a colorant, wherein the polymerizable compounds include a vinyl ether group-containing (meth)acrylate represented by general formula (I): CH2═CR1—COOR2—O—CH═CH—R3  (I) (wherein R1 is a hydrogen atom or a methyl group, R2 is a divalent organic residue having 2 to 20 carbon atoms, and R3 is a hydrogen atom or a monovalent organic residue having 1 to 11 carbon atoms) and phenoxyethyl (meth)acrylate.

摘要翻译： 本发明提供了一种具有优异固化性的喷墨记录用光固化性油墨组合物。 用于喷墨记录的光固化油墨组合物包括可聚合化合物，光聚合引发剂和着色剂，其中可聚合化合物包括由通式（I）表示的含乙烯基醚基的（甲基）丙烯酸酯：CH 2 = CR 1 -COOR 2 -O -CH = CH-R 3（I）（其中R 1为氢原子或甲基，R 2为碳原子数2〜20的二价有机残基，R 3为氢原子或碳原子数为1〜11的1价有机残基 原子）和（甲基）丙烯酸苯氧基乙酯。

公开(公告)号：US09115290B2

公开(公告)日：2015-08-25

申请号：US13544539

申请日：2012-07-09

申请人： Hiroaki Kida ,  Hiroshi Fukumoto ,  Toru Saito ,  Keitaro Nakano ,  Hiroki Nakane

发明人： Hiroaki Kida ,  Hiroshi Fukumoto ,  Toru Saito ,  Keitaro Nakano ,  Hiroki Nakane

IPC分类号： B41J2/01 ,  C09D11/101 ,  B41J2/21 ,  C09D11/322 ,  B41J11/00

CPC分类号： C09D11/101 ,  B41J2/2107 ,  B41J11/002 ,  C08K3/013 ,  C09D11/322 ,  C09D11/38

摘要： The present invention provides a photocurable ink composition for ink jet recording with excellent curability. The photocurable ink composition for ink jet recording includes polymerizable compounds, a photopolymerization initiator, and a colorant, wherein the polymerizable compounds include a vinyl ether group-containing (meth)acrylate represented by general formula (I): CH2═CR1—COOR2—O—CH═CH—R3  (I) (wherein R1 is a hydrogen atom or a methyl group, R2 is a divalent organic residue having 2 to 20 carbon atoms, and R3 is a hydrogen atom or a monovalent organic residue having 1 to 11 carbon atoms) and phenoxyethyl (meth)acrylate.

摘要翻译： 本发明提供了一种具有优异固化性的喷墨记录用光固化性油墨组合物。 用于喷墨记录的光固化油墨组合物包括可聚合化合物，光聚合引发剂和着色剂，其中可聚合化合物包括由通式（I）表示的含乙烯基醚基的（甲基）丙烯酸酯：CH 2 = CR 1 -COOR 2 -O -CH = CH-R 3（I）（其中R 1为氢原子或甲基，R 2为碳原子数2〜20的二价有机残基，R 3为氢原子或碳原子数为1〜11的1价有机残基 原子）和（甲基）丙烯酸苯氧基乙酯。

公开(公告)号：US20120225969A1

公开(公告)日：2012-09-06

申请号：US13337568

申请日：2011-12-27

申请人： Toshiyuki Miyabayashi ,  Tomohito Nakano ,  Hiroki Nakane ,  Hirotoshi Koyano ,  Yoshinobu Sato ,  Hiroshi Sawada ,  Shinichi Kato

发明人： Toshiyuki Miyabayashi ,  Tomohito Nakano ,  Hiroki Nakane ,  Hirotoshi Koyano ,  Yoshinobu Sato ,  Hiroshi Sawada ,  Shinichi Kato

IPC分类号： C08G18/83

CPC分类号： C09D175/16 ,  C08F290/067 ,  C08G18/283 ,  C08G18/672 ,  C08G18/673 ,  C08G18/755 ,  C08G18/48

摘要： For the purpose of providing a urethane(meth)acrylate excellent in emulsifiability in water and a production method thereof, and a light curable aqueous emulsion using the urethane(meth)acrylate having a low viscosity and excellent in the curability, provided is a urethane(meth)acrylate being represented by the following general formula (1) and having a weight average molecular weight of 1,000 to 10,000: A1-O—(CONH—B1-NHCOO—C1-O)n-CONH—B1-NH—COO-D1  (1) wherein in formula (1), n represents a natural number of 1 to 30, A1 represents a residue of a hydroxyl group-containing (meth)acrylate, B1 represents a residue of diisocyanate, C1 represents a residue of a diol of an acyclic hydrocarbon or a cyclic hydrocarbon, and D1 represents a residue of a polyoxyalkylene glycol monoalkyl ether.

摘要翻译： 为了提供在水中的乳化性优异的氨基甲酸酯（甲基）丙烯酸酯及其制造方法，使用粘度低，固化性优异的氨基甲酸酯（甲基）丙烯酸酯的光固化性水性乳液，提供了聚氨酯（ （CONH-B1-NHCOO-C1-O）n-CONH-B1-NH-COO-的重均分子量为1,000〜10000的下述通式（1）表示的（甲基） D1（1）其中，在式（1）中，n表示1〜30的自然数，A1表示含羟基的（甲基）丙烯酸酯的残基，B1表示二异氰酸酯的残基，C1表示二醇的残基 的非环状烃或环状烃，D1表示聚氧亚烷基二醇单烷基醚的残基。

公开(公告)号：US20120225968A1

公开(公告)日：2012-09-06

申请号：US13337581

申请日：2011-12-27

申请人： Tomohito Nakano ,  Toshiyuki Miyabayashi ,  Shinichi Kato ,  Hiroki Nakane ,  Hirotoshi Koyano ,  Yoshinobu Sato ,  Hiroshi Sawada ,  Kenji Kitada

发明人： Tomohito Nakano ,  Toshiyuki Miyabayashi ,  Shinichi Kato ,  Hiroki Nakane ,  Hirotoshi Koyano ,  Yoshinobu Sato ,  Hiroshi Sawada ,  Kenji Kitada

IPC分类号： C09D11/10

CPC分类号： C08F299/06 ,  C08F290/067 ,  C09D11/101

摘要： An ink composition for ink jet providing excellent in the curability based on ultraviolet irradiation in the presence of water or a solvent, the ejection stability with respect to the factors such as dot loss or flight deflection, and the storage stability of ink. Also provided herein is an ink composition for ink jet including: a pigment; a water-soluble organic solvent; a surfactant; at least either of a urethane (meth)acrylate being represented by the following general formula (1) and having a weight average molecular weight of 1,000 to 10,000 and a cross-linked urethane (meth)acrylate having a constitutional unit including the urethane (meth)acrylate; a compound having a radical polymerizable group(s); a photoradical polymerization initiator; and water: A1-O—(CONH—B1—NHCOO—C1—O)n—CONH—B1—NH—COO-D1  (1) where each of A1, B1, C1, D1, and n in formula (1) are described herein.

摘要翻译： 一种用于喷墨的油墨组合物，其在水或溶剂的存在下，基于紫外线照射提供优异的固化性，相对于诸如点损失或飞行偏转等因素的喷射稳定性以及油墨的储存稳定性。 本文还提供了一种用于喷墨的油墨组合物，包括：颜料; 水溶性有机溶剂; 表面活性剂; 氨基甲酸酯（甲基）丙烯酸酯中的至少一种由以下通式（1）表示并具有1,000至10,000的重均分子量和具有包含氨基甲酸酯（甲基）丙烯酸酯的结构单元的交联的聚氨酯（甲基）丙烯酸酯 ）丙烯酸酯; 具有自由基聚合性基团的化合物; 光自由基聚合引发剂; 和水：式（1）中的A1，B1，C1，D1和n各自的A1-O-（CONH-B1-NHCOO-C1-O）n-CONH-B1-NH-COO-D1（1） 在此描述。

公开(公告)号：US09109125B2

公开(公告)日：2015-08-18

申请号：US13324347

申请日：2011-12-13

申请人： Satoru Miura ,  Hiroki Nakane

发明人： Satoru Miura ,  Hiroki Nakane

IPC分类号： B41J2/01 ,  C09D11/101 ,  B41J11/00 ,  B41J2/21

CPC分类号： B41J2/2107 ,  B41J11/0015 ,  B41J11/002 ,  C09D11/101 ,  C09D11/107 ,  C09D11/30

摘要： An ink composition for ultraviolet curable ink jets including monomer A represented by a general formula (I): CH2═CR1—COOR2—O—CH═CH—R3  (I) (in the formula, ‘R1’ represents a hydrogen atom or methyl group, ‘R2’ represents a divalent organic residue having a carbon number of 2 to 20, and ‘R3’ represents a hydrogen atom or a monovalent organic residue having a carbon number of 1 to 11), and a photopolymerization initiator containing an acylphosphine oxide-based photopolymerization initiator and a thioxanthone-based photopolymerization initiator, in which the total content of the acylphosphine oxide-based photopolymerization initiator and the thioxanthone-based photopolymerization initiator is 8% by mass to 16% by mass with respect to the total mass of the ink composition.

摘要翻译： 用于紫外线固化油墨喷墨的油墨组合物，其包括由通式（I）表示的单体A：CH 2 = CR 1 -COOR 2 -O-CH = CH-R 3（I）（在式中，“R 1”表示氢原子或甲基 基团，“R2”表示碳数为2〜20的二价有机残基，“R3”表示氢原子或碳数为1〜11的1价有机残基），含有酰基氧化膦的光聚合引发剂 的基于光聚合引发剂和噻吨酮系光聚合引发剂，其中酰基氧化膦系光聚合引发剂和噻吨酮系光聚合引发剂的总含量相对于总共质量为8质量％〜16质量％ 墨水组成。

公开(公告)号：US20120133060A1

公开(公告)日：2012-05-31

申请号：US13307106

申请日：2011-11-30

申请人： Hiroki Nakane ,  Jun Ito

发明人： Hiroki Nakane ,  Jun Ito

IPC分类号： H01L23/29 ,  H01L21/56 ,  C08K5/29 ,  C08K5/5397 ,  C08K5/07 ,  C08K5/3432

CPC分类号： C09D11/322 ,  C08K5/053 ,  C08K5/09 ,  C09D11/101

摘要： A radiation-curable ink jet ink composition contains a polymerizable compound, an photopolymerization initiator and polysiloxane, in which the ink composition is used for recording on a package substrate as a recording medium; the polymerizable compound contains one or more kinds of compound having a pentaerythritol skeleton; an HLB value of the polysiloxane is 5 to 12; and the polysiloxane content is 0.1 to 2% by mass with respect to the total amount of the ink composition.

摘要翻译： 辐射固化型喷墨油墨组合物含有可聚合化合物，光聚合引发剂和聚硅氧烷，其中油墨组合物用作记录在作为记录介质的包装基材上; 可聚合化合物含有一种或多种具有季戊四醇骨架的化合物; 聚硅氧烷的HLB值为5〜12; 相对于油墨组合物的总量，聚硅氧烷的含量为0.1〜2质量％。

公开(公告)号：US08564142B2

公开(公告)日：2013-10-22

申请号：US13307075

申请日：2011-11-30

申请人： Jun Ito ,  Hiroki Nakane

发明人： Jun Ito ,  Hiroki Nakane

IPC分类号： H01L23/29

CPC分类号： C09D11/101 ,  C09D11/322

摘要： The invention provides a radiation curable ink jet ink composition including: a monomer equal to or more than 20% by mass and equal to or less than 50% by mass with respect to the total mass of the ink composition, which is represented by the following formula (I); and N-vinylcaprolactam equal to or more than 5% by mass and equal to or less than 15% by mass with respect to the total mass of the ink composition: CH2═CR1—COOR2—O—CH═CH—R3  (I) wherein, R1 is a hydrogen atom or a methyl group, R2 is a divalent organic residue having 2 to 20 carbon atoms, and R3 is a hydrogen atom or monovalent organic residue having 1 to 11 carbon atoms.

摘要翻译： 本发明提供一种可辐射固化喷墨油墨组合物，其包含：相对于油墨组合物的总质量等于或大于20质量％且等于或小于50质量％的单体，其由以下 式（I）; 相对于油墨组合物的总质量，N-乙烯基己内酰胺等于或大于5质量％且等于或小于15质量％：CH2 = CR1-COOR2-O-CH = CH-R3（I） 其中，R1为氢原子或甲基，R2为碳原子数2〜20的二价有机残基，R3为氢原子或碳原子数为1〜11的1价有机残基。

公开(公告)号：US20120189822A1

公开(公告)日：2012-07-26

申请号：US13354606

申请日：2012-01-20

申请人： Jun Ito ,  Hiroki Nakane

发明人： Jun Ito ,  Hiroki Nakane

IPC分类号： B32B3/10 ,  C09D11/10 ,  B41J2/01

CPC分类号： C09D133/08 ,  B41J11/002 ,  C09D11/101 ,  C09D11/30 ,  H01L21/67282 ,  H01L23/544 ,  H01L2223/54486 ,  H01L2924/0002 ,  Y10T428/24802 ,  H01L2924/00

摘要： A radiation-curable ink for ink jet recording contains N-vinylcaprolactam. The N-vinylcaprolactam content is in a range of 5% by mass to 20% by mass, inclusive, relative to the total mass of the ink. The ink is for the purpose of making a marking on a recording medium, and the recording medium is a package substrate or a semiconductor substrate. The ink is applied to the package substrate or the semiconductor substrate, exposed to radiation, and then subjected to a heat treatment at a temperature in a range of 150° C. to 200° C., inclusive.

摘要翻译： 用于喷墨记录的可辐射固化油墨含有N-乙烯基己内酰胺。 N-乙烯基己内酰胺的含量相对于油墨的总质量为5质量％〜20质量％。 墨水用于在记录介质上进行标记，记录介质是封装基板或半导体基板。 将油墨施加到暴露于辐射的封装衬底或半导体衬底上，然后在150℃至200℃的温度范围内进行热处理。

公开(公告)号：US08575768B2

公开(公告)日：2013-11-05

申请号：US13307106

申请日：2011-11-30

申请人： Hiroki Nakane ,  Jun Ito

发明人： Hiroki Nakane ,  Jun Ito

IPC分类号： H01L23/29

CPC分类号： C09D11/322 ,  C08K5/053 ,  C08K5/09 ,  C09D11/101

摘要： A radiation-curable ink jet ink composition contains a polymerizable compound, an photopolymerization initiator and polysiloxane, in which the ink composition is used for recording on a package substrate as a recording medium; the polymerizable compound contains one or more kinds of compound having a pentaerythritol skeleton; an HLB value of the polysiloxane is 5 to 12; and the polysiloxane content is 0.1 to 2% by mass with respect to the total amount of the ink composition.

摘要翻译： 辐射固化型喷墨油墨组合物含有可聚合化合物，光聚合引发剂和聚硅氧烷，其中油墨组合物用作记录在作为记录介质的包装基材上; 可聚合化合物含有一种或多种具有季戊四醇骨架的化合物; 聚硅氧烷的HLB值为5〜12; 相对于油墨组合物的总量，聚硅氧烷含量为0.1〜2质量％。

公开(公告)号：US20120133059A1

公开(公告)日：2012-05-31

申请号：US13307075

申请日：2011-11-30

申请人： Jun Ito ,  Hiroki Nakane

发明人： Jun Ito ,  Hiroki Nakane

IPC分类号： H01L23/29 ,  H01L21/56 ,  C09D7/12 ,  C09D4/02 ,  C09D11/10

CPC分类号： C09D11/101 ,  C09D11/322

摘要： The invention provides a radiation curable ink jet ink composition including: a monomer equal to or more than 20% by mass and equal to or less than 50% by mass with respect to the total mass of the ink composition, which is represented by the following formula (I); and N-vinylcaprolactam equal to or more than 5% by mass and equal to or less than 15% by mass with respect to the total mass of the ink composition: CH2═CR1—COOR2—O—CH═CH—R3  (I) wherein, R1 is a hydrogen atom or a methyl group, R2 is a divalent organic residue having 2 to 20 carbon atoms, and R3 is a hydrogen atom or monovalent organic residue having 1 to 11 carbon atoms.

摘要翻译： 本发明提供一种可辐射固化喷墨油墨组合物，其包含：相对于油墨组合物的总质量等于或大于20质量％且等于或小于50质量％的单体，其由以下 式（I）; 相对于油墨组合物的总质量，N-乙烯基己内酰胺等于或大于5质量％且等于或小于15质量％：CH 2 = CR 1 -COOR 2 -O-CH = CH-R 3（I） 其中，R1为氢原子或甲基，R2为碳原子数2〜20的二价有机残基，R3为氢原子或碳原子数为1〜11的1价有机残基。