公开(公告)号：US06569912B1

公开(公告)日：2003-05-27

申请号：US09868637

申请日：2001-06-27

申请人： Youichi Oohara ,  Fuminobu Hirose ,  Takeshi Sato ,  Hiroshi Fujiwara ,  Toru Yoshida

发明人： Youichi Oohara ,  Fuminobu Hirose ,  Takeshi Sato ,  Hiroshi Fujiwara ,  Toru Yoshida

IPC分类号： C08J908

CPC分类号： C08J9/149 ,  C08J9/0019 ,  C08J9/0028 ,  C08J9/0038 ,  C08J9/141 ,  C08J2201/03 ,  C08J2203/06 ,  C08J2203/12 ,  C08J2203/14 ,  C08J2325/06

摘要： An extruded styrene resin foam obtained by extrusion-foaming of a styrene resin and excellent in environmental compatibility and excellent in flame retardant property and thermal insulating property, characterized in that it contains, as a blowing agent, 100 to 10% by weight of at least one of saturated hydrocarbons having 3 to 5 carbons and 0 to 90% by weight of other blowing agent, based on the total amount of the blowing agent, and contains (A) a halogenated flame retardant and (B) at least one compound selected from the group consisting of phosphorus type flame retardants containing nitrogen atom in a molecule, tetrazole compounds, cyanuric acid and derivatives thereof, isocyanuric acid and derivatives thereof, metal borates, and boron oxides.

摘要翻译： 通过苯乙烯树脂的挤出发泡得到的挤出发泡苯乙烯树脂发泡体，环境相容性优异，阻燃性和隔热性优异的特征在于，作为发泡剂，含有至少100〜10重量％ （A）卤化阻燃剂和（B）至少一种选自下列化合物的化合物：（A）卤化阻燃剂，（B）至少一种选自 由分子中含有氮原子的磷型阻燃剂组成的组，四唑化合物，氰尿酸及其衍生物，异氰脲酸及其衍生物，金属硼酸盐和氧化硼。

公开(公告)号：US06762212B2

公开(公告)日：2004-07-13

申请号：US10358153

申请日：2003-02-05

申请人： Youichi Oohara ,  Fuminobu Hirose ,  Takeshi Sato ,  Hiroshi Fujiwara ,  Toru Yoshida

发明人： Youichi Oohara ,  Fuminobu Hirose ,  Takeshi Sato ,  Hiroshi Fujiwara ,  Toru Yoshida

IPC分类号： C08J908

CPC分类号： C08J9/149 ,  C08J9/0019 ,  C08J9/0028 ,  C08J9/0038 ,  C08J9/141 ,  C08J2201/03 ,  C08J2203/06 ,  C08J2203/12 ,  C08J2203/14 ,  C08J2325/06

摘要： An extruded styrene resin foam obtained by extrusion-foaming of a styrene resin and excellent in environmental compatibility and excellent in flame retardant property and thermal insulating property, characterized in that it contains, as a blowing agent, 100 to 10% by weight of at least one of saturated hydrocarbons having 3 to 5 carbons and 0 to 90% by weight of other blowing agent, based on the total amount of the blowing agent, and contains (A) a halogenated flame retardant and (B) at least one compound selected from the group consisting of phosphorus type flame retardants containing nitrogen atom in a molecule, tetrazole compounds, cyanuric acid and derivatives thereof, isocyanuric acid and derivatives thereof, metal borates, and boron oxides.

摘要翻译： 通过苯乙烯树脂的挤出发泡得到的挤出发泡苯乙烯树脂发泡体，环境相容性优异，阻燃性和隔热性优异的特征在于，作为发泡剂，含有至少100〜10重量％ （A）卤化阻燃剂和（B）至少一种选自下列化合物的化合物：（A）卤化阻燃剂，（B）至少一种选自 由分子中含有氮原子的磷型阻燃剂组成的组，四唑化合物，氰尿酸及其衍生物，异氰脲酸及其衍生物，金属硼酸盐和氧化硼。

公开(公告)号：US06315932B1

公开(公告)日：2001-11-13

申请号：US09367810

申请日：1999-08-23

申请人： Hiroshi Fujiwara ,  Hiroshi Kobayashi ,  Fuminobu Hirose

发明人： Hiroshi Fujiwara ,  Hiroshi Kobayashi ,  Fuminobu Hirose

IPC分类号： B29C4420

CPC分类号： C08J9/149 ,  C08J2201/03 ,  C08J2203/12 ,  C08J2203/14 ,  C08J2203/142 ,  C08J2325/06

摘要： An extrusion foaming method for obtaining a styrene resin foam by introducing a blowing agent into the resin under pressure by which a foam having excellent heat insulating property and compressive strength can be produced with excellent stability using a blowing agent which is as environmentally safe as possible, characterized in that a foam is obtained by using a blowing agent comprising mainly less than 40% by weight and 5% by weight or more of an ether, and more than 60% by weight and not more than 95% by weight of a saturated hydrocarbon having 3 to 5 carbon atoms, based on the entire amount of the blowing agent, or as required, by using a blowing agent wherein a part of the saturated hydrocarbon in the foregoing blowing agent is replaced by a fluorinated hydrocarbon with concern for the environment, and preferably in that the ratio Z/X of cells constituting the foam wherein X is the average cell size in the direction of extrusion and Z is the average cell size in the direction of thickness is adjusted to 1 or less, preferably 0.8 or less by stretching the foam with heating after the extrusion.

摘要翻译： 一种挤出发泡方法，用于通过使用尽可能环境安全的发泡剂以高稳定性制造具有优异绝热性和抗压强度的泡沫的压力下将发泡剂引入树脂中，从而获得苯乙烯树脂泡沫， 其特征在于，通过使用主要含量小于40重量％和5重量％以上的发泡剂和大于60重量％且不超过95重量％的饱和烃 基于发泡剂的总量，或根据需要，通过使用发泡剂，其中上述发泡剂中的一部分饱和烃被环境中的氟化烃代替，具有3至5个碳原子， 并且优选地，构成泡沫的泡孔的比例Z / X，其中X是挤出方向上的平均泡孔尺寸，Z是在挤出方向上的平均泡孔尺寸 在挤出后通过加热膨胀泡沫将厚度调节至1以下，优选为0.8以下。