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    TRANSITION METAL ION COMPLEX, METHOD FOR PRODUCING THE SAME, AND METHOD FOR PRODUCING POLYMER
    11.
    发明申请
    TRANSITION METAL ION COMPLEX, METHOD FOR PRODUCING THE SAME, AND METHOD FOR PRODUCING POLYMER 审中-公开
    过渡金属离子复合物，其制备方法和制备聚合物的方法

    公开(公告)号：US20120172552A1

    公开(公告)日：2012-07-05

    申请号：US13418505

    申请日：2012-03-13

    申请人： Taichi SENDA ,  Hidenori Hanaoka

    发明人： Taichi SENDA ,  Hidenori Hanaoka

    IPC分类号： C08F4/76 ,  C08F110/00 ,  C08F120/10 ,  C07F7/28

    CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F10/00 ,  C08F110/14 ,  C08F210/14 ,  C08F232/00 ,  C08F2420/02 ,  C08F4/6592 ,  C08F2500/03 ,  C08F212/08 ,  C08F2500/25

    摘要： A transition metal ion complex represented by formula (1): wherein M represents a group-IV element of the periodic table, A represents a group-XIV element of the periodic table, D represents a group-XVI element of the periodic table, Cp represents a group having a cyclopentadienyl type anion skeleton, E represents a counter anion, R1-R6 represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an aralkyl group, a silyl group substituted with a hydrocarbon, an alkoxy group, an aryloxy group, an aralkyl oxy group or an amino group substituted with hydrocarbon, and X1 represents an alkyl group, an aryl group or an aralkyl group.

    摘要翻译： 由式（1）表示的过渡金属离子络合物：其中M表示周期表的IV族元素，A表示周期表的基团-XIV元素，D表示周期表的基团-XVI元素，Cp 表示具有环戊二烯基型阴离子骨架的基团，E表示抗衡阴离子，R1-R6表示氢原子，卤素原子，烷基，芳基，芳烷基，被烃取代的甲硅烷基，烷氧基 基团，芳氧基，芳烷基氧基或被烃取代的氨基，X1表示烷基，芳基或芳烷基。

    Process for producing metallocene compound
    13.
    发明授权
    Process for producing metallocene compound 失效
    金属茂化合物的制备方法

    公开(公告)号：US07652159B2

    公开(公告)日：2010-01-26

    申请号：US11660933

    申请日：2005-07-11

    申请人： Taichi Senda ,  Noriyuki Hida ,  Hidenori Hanaoka

    发明人： Taichi Senda ,  Noriyuki Hida ,  Hidenori Hanaoka

    IPC分类号： C07F7/00

    CPC分类号： C07F17/00 ,  C08F10/00 ,  C08F2420/02 ,  C08F4/6592

    摘要： The invention provides a process for producing a metallocene compound of formula (3) wherein R1 to R9 independently denote a hydrogen atom, a halogen atom, an alkyl, or the like; R10 denotes a halogen atom, an alkyl, an alkoxy, or the like; X5 and X6 independently denote a hydrogen atom, a halogen atom, or the like; and M denotes a transition metal atom of Group 4 of the Periodic Table, which process is characterized by reacting a silicon-substituted cyclopentadiene compound of formula (1) wherein R1 to R10 independently denote the same as described above; R11 denotes a hydrocarbon group or a tri-substituted silyl; and R12 to R14 independently denote a halogen atom or a hydrocarbon group, with a transition metal compound of the following formula (2) wherein M denotes the same as described above; X1, X2, X3, and X4 independently denotes a hydrogen atom, a halogen atom, an alkyl, or the like, in a solvent containing an aromatic hydrocarbon.

    摘要翻译： 本发明提供一种制备式（3）的茂金属化合物的方法，其中R 1至R 9独立地表示氢原子，卤素原子，烷基等; R 10表示卤素原子，烷基，烷氧基等; X 5和X 6独立地表示氢原子，卤素原子等; 并且M表示周期表第4族的过渡金属原子，该方法的特征在于使式（1）的硅取代的环戊二烯化合物（其中R 1至R 10独立地表示与上述相同的基团） R 11表示烃基或三取代甲硅烷基; 和R 12至R 14独立地表示卤素原子或烃基，与下式（2）的过渡金属化合物，其中M表示与上述相同的基团; X 1，X 2，X 3和X 4独立地表示在含有芳香族烃的溶剂中的氢原子，卤素原子，烷基等。

    Transition Metal Complex, Process For Producing Said Transition Metal Complex, Substituent-Carrying Fluorene Compound, Process For Producing Said Fluorene Compound, Catalyst Component For Olefin Polymerization, Catalyst For Olefin Polymerization, and Process For Producing Olefin Polymer
    15.
    发明申请
    Transition Metal Complex, Process For Producing Said Transition Metal Complex, Substituent-Carrying Fluorene Compound, Process For Producing Said Fluorene Compound, Catalyst Component For Olefin Polymerization, Catalyst For Olefin Polymerization, and Process For Producing Olefin Polymer 失效

    公开(公告)号：US20080161514A1

    公开(公告)日：2008-07-03

    申请号：US11795967

    申请日：2006-01-24

    申请人： Taichi Senda ,  Hidenori Hanaoka ,  Shinya Nakahara ,  Kenji Sogoh

    发明人： Taichi Senda ,  Hidenori Hanaoka ,  Shinya Nakahara ,  Kenji Sogoh

    IPC分类号： C07F7/08 ,  C07F7/28 ,  C07F7/30 ,  C08F10/00 ,  B01J31/22

    CPC分类号： C08F10/00 ,  B01J31/2295 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/02 ,  C08F210/02 ,  C08F210/16 ,  C08F2420/02 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/659 ,  C08F4/6592 ,  C08F232/00 ,  C08F2500/17 ,  C08F2500/25 ,  C08F210/14

    摘要： A transition metal complex represented by the general formula [1]; a catalyst component for olefin polymerization comprising said transition metal complex; a catalyst for olefin polymerization using said transition metal complex as a catalyst component for olefin polymerization; a process for producing an olefin polymer comprising the step of polymerizing an olefin in the presence of said catalyst for olefin polymerization; a substituent-carrying fluorene compound; a process for producing said substituent-carrying fluorene compound; and a process for producing said transition metal complex using said substituent-carrying fluorene compound: wherein M is the group 4 transition metal atom in the periodic table of elements; A is the group 16 atom therein; J is the group 14 atom therein; R1, R2, R3, R4, R5, R6, X1 and X2 are independently of one another (1) a substituent selected from the group consisting of (1-1) an alkyl group having 1 to 20 carbon atoms, which may be substituted by a halogen atom, (1-2) an aralkyl group having 7 to 20 carbon atoms, which may be substituted by a halogen atom, (1-3) an aryl group having 6 to 20 carbon atoms, which may be substituted by a halogen atom, (1-4) a substituent-carrying silyl group having 1 to 20 carbon atoms, which substituent is a hydrocarbyl group, and said hydrocarbyl group may be substituted by a halogen atom, (1-5) a disubstituent-carrying amino group having 2 to 20 carbon atoms, which substituent is a hydrocarbyl group, and said hydrocarbyl group may be substituted by a halogen atom, (1-6) an alkoxy group having 1 to 20 carbon atoms, which may be substituted by a halogen atom, (1-7) an aralkyloxy group having 7 to 20 carbon atoms, which may be substituted by a halogen atom, and (1-8) an aryloxy group having 6 to 20 carbon atoms, which may be substituted by a halogen atom, (2) a halogen atom or (3) a hydrogen atom; R1 and R2, R2 and R3, and R3 and R4 may be linked to each other, respectively, to form respective rings; R5 and R6 may be linked to each other to form a ring; R7, R8, R9 and R10 are independently of one another (1) a substituent selected from the group consisting of (1-1) an alkyl group having 1 to 20 carbon atoms, which may be substituted by a halogen atom, (1-2) an aralkyl group having 7 to 20 carbon atoms, which may be substituted by a halogen atom, (1-3) an aryl group having 6 to 20 carbon atoms, which may be substituted by a halogen atom, (1-4) a substituent-carrying silyl group having 1 to 20 carbon atoms, which substituent is a hydrocarbyl group, and said hydrocarbyl group may be substituted by a halogen atom, (1-5) a disubstituent-carrying amino group having 2 to 20 carbon atoms, which substituent is a hydrocarbyl group, and said hydrocarbyl group may be substituted by a halogen atom, (1-6) an alkoxy group having 1 to 20 carbon atoms, which may be substituted by a halogen atom, (1-7) an aralkyloxy group having 7 to 20 carbon atoms, which may be substituted by a halogen atom, and (1-8) an aryloxy group having 6 to 20 carbon atoms, which may be substituted by a halogen atom, (2) a halogen atom or (3) a hydrogen atom; at least two of R7, R8, R9 and R10 are the substituent selected from the above-mentioned group or a halogen atom; R7 and R8 may be linked to each other to form a ring; and R9 and R10 may be linked to each other to form a ring.

    Transition metal complexes, ligands, catalysts for olefin polymerization, and process for production of olefin polymers
    16.
    发明授权
    Transition metal complexes, ligands, catalysts for olefin polymerization, and process for production of olefin polymers 失效
    过渡金属络合物，配体，烯烃聚合用催化剂和烯烃聚合物生产方法

    公开(公告)号：US07241927B2

    公开(公告)日：2007-07-10

    申请号：US11324260

    申请日：2006-01-04

    申请人： Hidenori Hanaoka ,  Taichi Senda ,  Eiji Yoshikawa ,  Satoshi Kobayashi

    发明人： Hidenori Hanaoka ,  Taichi Senda ,  Eiji Yoshikawa ,  Satoshi Kobayashi

    IPC分类号： C07C43/20 ,  C07C43/205 ,  C07C43/215

    CPC分类号： C08F10/00 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/10

    摘要： A transition metal complex represented by the formula (1): wherein M is a Group 4 transition metal, A is a Group 16 element, B is a Group 14 element, n is an integer of 0 or 1, R1, R2, R3 and R4 may be the same or different and each independently denotes a substituent selected from the group consisting of the groups (I) and (II): group (I): hydrogen, alkyl and so on, group (II): alkoxy, alkylthio and so on, provided that at least one of R1, R2, R3 and R4 is a substituent selected from group (II); R5, R6, R7, R8, R9, R10, X1 and X2 may be the same or different and are each hydrogen, halogen, alkyl or the like; and a catalyst for olefin polymerization comprising said complex, an organoaluminum compound and a boron compound are provided.

    摘要翻译： 由式（1）表示的过渡金属络合物：其中M是第4族过渡金属，A是第16族元素，B是第14族元素，n是0或1的整数，R 1， R 2，R 3，R 4和R 4可以相同或不同，并且各自独立地表示选自以下的取代基： 的基团（I）和（II）：基团（I）：氢，烷基等，基团（II）：烷氧基，烷硫基等，条件是R 1， R 2，R 3和R 4是选自（II）组的取代基。 R 5，R 6，R 7，R 8，R 9， R 10，X 1和X 2可以相同或不同，各自为氢，卤素，烷基等; 并提供包含所述络合物，有机铝化合物和硼化合物的烯烃聚合催化剂。

    Olefin polymerization catalyst component
    17.
    发明授权
    Olefin polymerization catalyst component 失效
    烯烃聚合催化剂组分

    公开(公告)号：US5840646A

    公开(公告)日：1998-11-24

    申请号：US695382

    申请日：1996-08-09

    申请人： Hiroaki Katayama ,  Masaaki Nabika ,  Akio Iami ,  Norio Kawamura ,  Hidenori Hanaoka

    发明人： Hiroaki Katayama ,  Masaaki Nabika ,  Akio Iami ,  Norio Kawamura ,  Hidenori Hanaoka

    IPC分类号： C07F7/00 ,  C08F4/642 ,  C08F4/643 ,  C08F10/00 ,  C08F210/16 ,  B01J31/00 ,  C07F7/28

    CPC分类号： C07F7/006 ,  C08F10/00 ,  C08F210/16

    摘要： An olefin polymerization catalyst component is represented by the general formula (1); ##STR1## wherein M is titanium, zirconium or hafnium; each of A and A' is the same or different and is a hydrocarbon or halogenated hydrocarbon having 1 to 50 carbon atoms, or a hydrocarbon or halogenated hydrocarbon group having 1 to 50 carbon atoms and a substituent containing an oxygen atom; E is a residual group of an element of the 13th to 15th Groups capable of forming three bonds; each of R and R' is the same or different and is a halogen atom or a hydrocarbon group having 1 to 20 carbon atoms; R" represents a hydrocarbon or halogenated hydrocarbon group containing at least one hetero atom and having 1 to 20 carbon atoms. This component is used in a catalyst to produce an olefin polymer.

    摘要翻译： 烯烃聚合催化剂组分由通式（1）表示; （1）其中M为钛，锆或铪; A和A'各自相同或不同，为碳原子数为1〜50的烃基或卤代烃，或碳原子数为1〜50的烃基或卤代烃基及含有氧原子的取代基。 E是能够形成三键的第十三至第十五组的元素的残留组; R和R'各自相同或不同，为卤素原子或碳原子数1〜20的烃基; R“表示含有至少一个杂原子并具有1至20个碳原子的烃基或卤代烃基。 该组分用于催化剂以制备烯烃聚合物。

    Transition metal complex, process for producing the same, and use
    20.
    发明授权
    Transition metal complex, process for producing the same, and use 失效
    过渡金属络合物，生产过程和使用

    公开(公告)号：US08026324B2

    公开(公告)日：2011-09-27

    申请号：US12531852

    申请日：2008-03-18

    申请人： Hidenori Hanaoka ,  Masaaki Nabika

    发明人： Hidenori Hanaoka ,  Masaaki Nabika

    IPC分类号： C08F4/642 ,  C08F4/6592 ,  C07F17/00 ,  B01J31/22

    CPC分类号： C07F17/00 ,  C08F10/00 ,  C08F210/16 ,  C08F2420/02 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/10

    摘要： A transition metal complex of the following formula (1): in which A represents an atom of Group 16 of the periodic table; B1 represents an atom of Group 14 of the periodic table; M1 represents a transition metal atom of Group 4 of the periodic table; Cp1 represents a group having a cyclopentadiene anion backbone; R1, R2, R3, R4, R5 and R6 represent independently of one another a hydrogen atom, a halogen atom, a C1-20 alkyl group optionally substituted with a halogen atom; R7, R8, R9, R10, R11 and R12 represent independently of one another a hydrogen atom, a C1-20 alkyl group optionally substituted with a halogen atom; and a 1,3-diene comprising R7, R8, R9, R10, R11, R12 and 4 carbon atoms coordinates on M1, and the 1,3-diene may be of either a cis or trans form, or a mixed form thereof, although the coordination form is not limited, and the double bonds may be delocalized. When this transition metal complex is used as a catalytic component, high molecular weight polyolefin is produced with high catalytic activity.

    摘要翻译： 下式（1）的过渡金属络合物：其中A表示周期表第16族的原子; B1表示周期表第14族的原子; M1表示周期表第4族的过渡金属原子; Cp1表示具有环戊二烯阴离子主链的基团; R 1，R 2，R 3，R 4，R 5和R 6彼此独立地表示氢原子，卤素原子，任选被卤素原子取代的C 1-20烷基; R 7，R 8，R 9，R 10，R 11和R 12彼此独立地表示氢原子，任选被卤素原子取代的C 1-20烷基; 和在M 1上配位的包含R7，R8，R9，R10，R11，R12和4个碳原子的1,3-二烯，1,3-二烯可以是顺式或反式，或其混合形式， 虽然协调形式没有限制，双重债券可能会离域。 当该过渡金属络合物用作催化组分时，产生具有高催化活性的高分子量聚烯烃。