Fluorinated heterocycles and their use in liquid-crystal mixtures
    12.
    发明申请
    Fluorinated heterocycles and their use in liquid-crystal mixtures 有权
    氟化杂环及其在液晶混合物中的应用

    公开(公告)号:US20050258399A1

    公开(公告)日:2005-11-24

    申请号:US11117280

    申请日:2005-04-28

    摘要: In the compound of the formula (I), where: R1, R2 are each independently, for example, H or a straight-chain or branched alkyl radical p, q are each independently 0 or 1, i.e. at the value zero, —H is present at the appropriate position instead of —F M1 is —CO—O—, —O—CO—, —CH2—O—, —O—CH2—, —CF2—O—, —O—CF2—, —CH═CH—, —CF═CF—, —C≡C—, —CH2—CH2—CO——O—,—O—CO—CH2—CH2—, —CH2—CH2—, —CF2—CF2—, —(CH2)4—, —OC(═O)CF═CF— or a single bond A1 is, for example, 1,4-phenylene R5 has the same possible definitions as specified for R1 and R2, with the exception of -M1-A1-R5, but independently of the definition of R1 and R2 X is H, F, OF3, CF3, OCF2H with the following provisos: a) at least one of p, q has to be 1 b) R1 and R2 must not at the same time be H c) R2 and X must not at the same time be H.

    摘要翻译: 在式(I)的化合物中,其中:R 1,R 2各自独立地为例如H或直链或支链烷基p, q各自独立地为0或1,即在零值时,-H存在于适当的位置,而不是-FM 1是-CO-O-,-O-CO-,-CH O 2,-O-CH 2 - , - CO 2 -O - , - O-CF 2 -O - , - O-CH 2 > - , - CH-CH-,-CF-CF-,-C≡C-, - CH 2 -CH 2 -CO-O - , - O -CO-CH 2 -CH 2 - , - CH 2 -CH 2 - , - CFF - (CH 2)4 - , - OC(-O)CF-CF-(CH 2)2 - 或单键A 1,例如,1,4-亚苯基R 5具有与R 1和R 2相同的可能定义, R< 2>除了-M 1以上的1〜5,但与定义 R 1,R 2,X 2是H,F 3,CF 3,OCF 3, 2 H,具有以下条件:a)至少 p,q中的一​​个必须为1b)R 1和R 2不能同时为H c)R 2和/或 X不能同时为H.

    Fluorinated polycycles and their use in liquid-crystal mixtures

    公开(公告)号:US06955838B2

    公开(公告)日:2005-10-18

    申请号:US10903082

    申请日:2004-07-30

    摘要: Compounds of the formula (I) where: R1, R2 are each independently a) H b) -M1-A1-R5 c) a straight-chain or branched alkyl radical having from 1 to 16 carbon atoms or a straight-chain or branched alkenyl radical having from 2 to 16 carbon atoms, where c1) one or more nonadjacent and nonterminal CH2 groups may be replaced by —O—, —C(═O)O—, —O—C(═O)—, —O—C(═O)—O—, —C(═O)— or —Si(CH3)2—, and/or c2) one CH2 group may be replaced by —C≡C—, cyclopropane-1,2-diyl, cyclobutane-1,3-diyl, cyclohexane-1,4-diyl or phenylene-1,4-diyl, and/or c3) one or more hydrogen atoms may be replaced by F and/or Cl, p, q, r are each independently 0 or 1 M1—is —CO—O—, —O—CO—, —CH2—O—, —O—CH2—, —CF2—O—, —O—CF2—, —CH═CH—, —CF═CF—, —C≡C—, —CH2—CH2—CO—O—, —O—CO—CH2—CH2—, —CH2—CH2—, —CF2—CF2—, —(CH2)4—, —OC(═O)CF═CF— or a single bond, A1 is 1,4-phenylene where one or two hydrogen atoms may be replaced by F, Cl, CN and/or OCF3, or up to three hydrogen atoms may be replaced by fluorine, 1,4-cyclohexylene where one or two hydrogen atoms may be replaced by CH3 and/or F, 1-cyclohexene-1,4-diyl where one hydrogen atom may be replaced by CH3 or F, or 1,3-dioxane-2,5-diyl, R5 has the same possible definitions as R1 and R2 with the exception of -M1-A1-R5, with the provisos that: a) at least one of p, q, r is 1 b) R1 and R2 must not at the same time be H are used in liquid-crystal mixtures.

    Fluorinated oxaanthracenes and their use in liquid-crystal mixtures
    15.
    发明授权
    Fluorinated oxaanthracenes and their use in liquid-crystal mixtures 有权
    氟化氧杂蒽及其在液晶混合物中的应用

    公开(公告)号:US06887533B2

    公开(公告)日:2005-05-03

    申请号:US10808147

    申请日:2004-03-24

    摘要: Compounds of the formula (I) where: X1 is H or F G1-G2 is —CH2—CH— or CH═C— R1, R2 are a) H b) the M2-A2-R5 moiety c) for example, a straight-chain or branched alkyl radical having from 1 to 16 carbon atoms R3 and R4 are each, for example, H, the M2-A2-R5 moiety or a straight-chain or branched alkyl or alkyloxy radical having from 1 to 16 carbon atoms A2 is, for example, 1,4-phenylene, with the provisos that a) when R2 is not H, R1 and R3 have to be H, b) when R2 is H, R4 must not have the definitions c) or d), c) R1, R2, R3 and R4 must not at the same time be H.

    摘要翻译: 式(I)的化合物其中:X 1是H或FG 1 -G 2 O 2是-CH 2 > -CH-或CH-C-R 1,R 2是a)H b)M 2 - c)例如,具有1至16个碳原子的直链或支链烷基R 3和R 4 各自为例如H,M 2 -OR 2 -OR 5部分或直链或支链的 具有1至16个碳原子的烷基或烷氧基是例如1,4-亚苯基,条件是a)当R 2不为H时 R 1和R 3必须是H,b)当R 2是H时,R 4必须 没有定义c)或d),c)R 1,R 2,R 3和R 4, >不能同时被H.

    Fluorinated cyclopenta[a]naphthalenes and their use in liquid-crystal mixtures
    16.
    发明授权
    Fluorinated cyclopenta[a]naphthalenes and their use in liquid-crystal mixtures 有权
    氟化环戊二烯[a]萘及其在液晶混合物中的应用

    公开(公告)号:US06737125B2

    公开(公告)日:2004-05-18

    申请号:US10242128

    申请日:2002-09-12

    IPC分类号: C09K1932

    摘要: Compounds of the formula (I), liquid-crystal mixtures comprising these compounds, and their use in liquid-crystal displays: in which R1 is H, F, CF3, OCF3, OCF2H, OCFH2, an alkyl radical or alkyloxy radical or an alkenyl radical or alkenyloxy radical; R2 is H, an alkyl radical or alkyloxy radical or an alkenyl radical or alkenyloxy radical M1 is —C(═O)O—, —OC(═O)—, —CH2O—, —OCH2—, —OCF2—, —CF2O—, —C≡C—, —CH2CH2—, —CF2CF2—, —CF═CFC(═O)O— or a single bond M2 is —C(═O)O—, —OC(═O)—, —CH2O—, —OCH2—, —CH2CH2—, —CF2CF2— or a single bond; A1 and A2 are &agr;-1,4-diyl, unsubstituted or mono- or disubstituted by F; where &agr; is: phenylene, cyclohexane, 1-cyclohexene or 1,3-dioxane-2,5-diyl; m and n are zero or 1; m+n=0 or 1 L1, L2, L3, L4 and L5 are H or F.

    摘要翻译: 式(I)化合物,包含这些化合物的液晶混合物及其在液晶显示器中的用途:其中R 1是H,F,CF 3,OCF 3,OCF 2 H,OCF 2 H,烷基或烷氧基或其 烯基或烯氧基; R 2是H,烷基或烷氧基或链烯基或烯氧基自由基M 1是-C(= O)O-,-OC(= O) - , - CH 2 O - , - OCH 2 - , - OCF 2 - , - CF 2 O-,-C = C - , - CH 2 CH 2 - , - CF 2 CF 2 - , - CF = CFC(= O)O-或单键M 2是-C O)O-,-OC(= O) - , - CH 2 O - , - OCH 2 - , - CH 2 CH 2 - , - CF 2 CF 2 - 或单键; A 1和A 2是α-1,4-二 F未取代或单取代或二取代; 其中α是:亚苯基,环己烷,1-环己烯或1,3-二恶烷-2,5-二基; m和n是0或1; m + n = 0或1L 1,L 2,L 3,L 4和L 5为H或F.

    Fluorinated phenanthrenes and their use in liquid-crystal mixtures

    公开(公告)号:US07399505B2

    公开(公告)日:2008-07-15

    申请号:US11122856

    申请日:2005-05-05

    CPC分类号: C09K19/32 Y10T428/10

    摘要: Compounds of the formula (I) are described in which M1 is, for example, —CO—O— or a single bond A1 is, for example, 1,4-phenylene, R5 has the same possible definitions specified for R1, with the exception of -M1-A1-R5, but independently of the definition of R1 G1-G2 is CH2CH2, CH═CH, CF2CF2, CF═CF, CF═CH, CH═CF X1, X2, X3, X4, X5 are each independently H or F R1, Y1, Y2 are each independently a) H b) F where Y1, R1, (R1 and Y1) or (R1 and Y2) may also have the definitions c) and/or d), but only in each case not more than one of (R1 and Y1) and of (R1 and Y2) may have the definition d) c) is, for example, a straight-chain or branched alkyl radical having from 1 to 16 carbon atoms or a straight-chain or branched alkenyl radical having from 2 to 16 carbon atoms, d) -M1-A1-R5 with the following provisos: a) at least one of X1, X2, X3, X4, X5, G1-G2 is or contains F b1) when at least one of Y1 and X1 is F and/or G1-G2 contains F, it is possible for R1, X2, X3, X4 not to be F b2) when at least one of R1, X2, X3, X4 is F, it is possible for X1 and Y1 not to be F, and for G1-G2 to be CH2CH2 or CH═CH c) it is not possible for Y2 and X5 simultaneously to be F.