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21.发明申请HYDROCARBOXYLATION OF METHYLENE DIPROPIONATE IN THE PRESENCE OF A PROPIONIC ACID AND A HOMOGENEOUS CATALYST 有权丙酸与均相催化剂存在下亚甲基二苯甲酸的烷基化反应公开(公告)号：US20130261329A1
公开(公告)日：2013-10-03
申请号：US13431402
申请日：2012-03-27
IPC分类号： C07C67/36 , C07C29/149 , C07C51/12
CPC分类号： C07C51/12 , C07C29/149 , C07C51/09 , C07C67/08 , C07C67/36 , C07C59/06 , C07C69/24 , C07C69/675 , C07C31/202
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of methylene dipropionate in the presence of a homogeneous acid catalyst and propionic acid. This invention discloses hydrocarboxylations and corresponding homogeneous acid catalyst and glycolic acid separations. The homogeneous acid catalyst is readily separated from the hydrocarboxylation reaction effluent and recycled and the propionic acid is readily removed from the glycolic acid and the propionic acid is recycled
摘要翻译： 公开了一种在均相酸催化剂和丙酸存在下通过二丙酸亚甲酯的羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的均相酸催化剂和乙醇酸分离。 均相酸催化剂容易从加氢羧化反应流出物中分离并再循环，丙酸容易从乙醇酸中除去，丙酸被再循环
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22.发明申请公开(公告)号：US20120142910A1
公开(公告)日：2012-06-07
申请号：US13396700
申请日：2012-02-15
申请人： Charles Michael Buchanan , Norma Lindsey Buchanan , Robert Thomas Hembre , Juanelle Little Lambert
发明人： Charles Michael Buchanan , Norma Lindsey Buchanan , Robert Thomas Hembre , Juanelle Little Lambert
CPC分类号： C07D233/54 , C08B1/003 , C08B3/00 , C08B3/06 , C08B3/08 , C08B3/10 , C08B3/16 , C08B3/18 , Y02P20/542
摘要： Ionic liquids and cellulose ester compositions and processes and apparatus for producing ionic liquids and cellulose esters. Cellulose esters can be produced by dissolving cellulose in carboxylated ionic liquids and thereafter contacting the cellulose solution with at least one acylating reagent. Cellulose esters produced via the present invention can comprise ester groups that originate from the carboxylated ionic liquid and/or the acylating reagent.
摘要翻译： 离子液体和纤维素酯组合物和用于生产离子液体和纤维素酯的方法和设备。 纤维素酯可以通过将纤维素溶解在羧化离子液体中，然后使纤维素溶液与至少一种酰化剂接触来制备。 通过本发明生产的纤维素酯可以包含源自羧化离子液体和/或酰化试剂的酯基。
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23.发明申请REGIOSELECTIVELY SUBSTITUTED CELLULOSE ESTERS PRODUCED IN A CARBOXYLATED IONIC LIQUID PROCESS AND PRODUCTS PRODUCED THEREFROM 审中-公开在羧基离子液体过程中生产的分离式取代的纤维素酯和由其生产的产物公开(公告)号：US20120101269A1
公开(公告)日：2012-04-26
申请号：US13339814
申请日：2011-12-29
申请人： Charles Michael Buchanan , Norma Lindsey Buchanan , Robert Thomas Hembre , Juanelle Little Lambert , Michael Eugene Donelson , Maryna Grigorievna Gorbunova , Thauming Kuo , Bin Wang
发明人： Charles Michael Buchanan , Norma Lindsey Buchanan , Robert Thomas Hembre , Juanelle Little Lambert , Michael Eugene Donelson , Maryna Grigorievna Gorbunova , Thauming Kuo , Bin Wang
CPC分类号： C07D233/54 , C08B1/003 , C08B3/06 , C08B3/16 , C08B3/28 , C08J5/18 , C08J2301/14 , G02B1/105 , G02B1/14 , G02B5/3083
摘要： This invention relates to novel compositions comprising regioselectively substituted cellulose esters. One aspect of the invention relates to processes for preparing regioselectively substituted cellulose esters from cellulose dissolved in ionic liquids. Another aspect of the invention relates to the utility of regioselectively substituted cellulose esters in applications such as protective and compensation films for liquid crystalline displays.
摘要翻译： 本发明涉及包含区域选择性取代的纤维素酯的新型组合物。 本发明的一个方面涉及从溶解在离子液体中的纤维素制备区域选择性取代的纤维素酯的方法。 本发明的另一方面涉及区域选择性取代的纤维素酯在液晶显示器的保护和补偿膜等应用中的应用。
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公开(公告)号：US20120095207A1
公开(公告)日：2012-04-19
申请号：US13330828
申请日：2011-12-20
申请人： Charles Michael Buchanan , Norma Lindsey Buchanan , Robert Thomas Hembre , Juanelle Little Lambert
发明人： Charles Michael Buchanan , Norma Lindsey Buchanan , Robert Thomas Hembre , Juanelle Little Lambert
CPC分类号： C07D233/54 , C08B1/003 , C08B3/00 , C08B3/06 , C08B3/08 , C08B3/10 , C08B3/16 , C08B3/18 , Y02P20/542
摘要： Ionic liquids and cellulose ester compositions and processes and apparatus for producing ionic liquids and cellulose esters. Cellulose esters can be produced by dissolving cellulose in carboxylated ionic liquids and thereafter contacting the cellulose solution with at least one acylating reagent. Cellulose esters produced via the present invention can comprise ester groups that originate from the carboxylated ionic liquid and/or the acylating reagent.
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公开(公告)号：US08148518B2
公开(公告)日：2012-04-03
申请号：US12030387
申请日：2008-02-13
申请人： Charles Michael Buchanan , Norma Lindsey Buchanan , Robert Thomas Hembre , Juanelle Little Lambert
发明人： Charles Michael Buchanan , Norma Lindsey Buchanan , Robert Thomas Hembre , Juanelle Little Lambert
CPC分类号： C07D233/54 , C08B1/003 , C08B3/00 , C08B3/06 , C08B3/08 , C08B3/10 , C08B3/16 , C08B3/18 , Y02P20/542
摘要： Ionic liquids and cellulose ester compositions and processes and apparatus for producing ionic liquids and cellulose esters. Cellulose esters can be produced by dissolving cellulose in carboxylated ionic liquids and thereafter contacting the cellulose solution with at least one acylating reagent. Cellulose esters produced via the present invention can comprise ester groups that originate from the carboxylated ionic liquid and/or the acylating reagent.
摘要翻译： 离子液体和纤维素酯组合物和用于生产离子液体和纤维素酯的方法和设备。 纤维素酯可以通过将纤维素溶解在羧化离子液体中，然后使纤维素溶液与至少一种酰化剂接触来制备。 通过本发明生产的纤维素酯可以包含源自羧化离子液体和/或酰化试剂的酯基。
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公开(公告)号：US07550627B2
公开(公告)日：2009-06-23
申请号：US11075009
申请日：2005-03-08
申请人： Gino Georges Lavoie , Robert Thomas Hembre , Charles Edwan Sumner, Jr. , Joseph Nathaniel Bays , Daniel Burts Compton , Brent Alan Tennant , Bryan Wayne Davenport , David Lange , Thomas Richard Floyd
发明人： Gino Georges Lavoie , Robert Thomas Hembre , Charles Edwan Sumner, Jr. , Joseph Nathaniel Bays , Daniel Burts Compton , Brent Alan Tennant , Bryan Wayne Davenport , David Lange , Thomas Richard Floyd
CPC分类号： C07C51/265 , C07C63/26 , C07C63/15 , C07C63/16 , C07C63/24
摘要： Processes for producing aromatic dicarboxylic acids are disclosed, the processes including a step of combining in a reaction medium a dialkyl aromatic, a solvent comprising water and a saturated organic acid having from 2-4 carbon atoms, and an oxygen-containing gas, at a temperature from about 125° C. to about 155° C., in the presence of a catalyst composition comprising cobalt, manganese, zirconium, and bromine, wherein the weight ratio of cobalt to manganese in the reaction mixture is from about 10 to about 400. The processes provide improved conversion, while reducing the formation of carbon oxides and other by-products.
摘要翻译： 公开了制备芳族二羧酸的方法，该方法包括在反应介质中将二烷基芳族化合物，包含水和具有2-4个碳原子的饱和有机酸的溶剂和含氧气体在一种 温度为约125℃至约155℃，在包含钴，锰，锆和溴的催化剂组合物存在下，其中反应混合物中钴与锰的重量比为约10至约400 该方法提供改进的转化率，同时减少碳氧化物和其它副产物的形成。
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公开(公告)号：US20080194808A1
公开(公告)日：2008-08-14
申请号：US12030387
申请日：2008-02-13
申请人： Charles Michael Buchanan , Norma Lindsey Buchanan , Robert Thomas Hembre , Juanelle Little Lambert
发明人： Charles Michael Buchanan , Norma Lindsey Buchanan , Robert Thomas Hembre , Juanelle Little Lambert
CPC分类号： C07D233/54 , C08B1/003 , C08B3/00 , C08B3/06 , C08B3/08 , C08B3/10 , C08B3/16 , C08B3/18 , Y02P20/542
摘要： Ionic liquids and cellulose ester compositions and processes and apparatus for producing ionic liquids and cellulose esters. Cellulose esters can be produced by dissolving cellulose in carboxylated ionic liquids and thereafter contacting the cellulose solution with at least one acylating reagent. Cellulose esters produced via the present invention can comprise ester groups that originate from the carboxylated ionic liquid and/or the acylating reagent.
摘要翻译： 离子液体和纤维素酯组合物和用于生产离子液体和纤维素酯的方法和设备。 纤维素酯可以通过将纤维素溶解在羧化离子液体中，然后使纤维素溶液与至少一种酰化剂接触来制备。 通过本发明生产的纤维素酯可以包含源自羧化离子液体和/或酰化试剂的酯基。
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公开(公告)号：US06469206B2
公开(公告)日：2002-10-22
申请号：US09792995
申请日：2001-02-26
申请人： Robert Thomas Hembre , Robert Lin
发明人： Robert Thomas Hembre , Robert Lin
IPC分类号： C07C30300
CPC分类号： C07C303/00 , C07C51/54 , Y02P20/127 , C07C53/124 , C07C309/00
摘要： Disclosed is a process for the preparation of trifluoromethanesulfonic acid anhydride by the steps of (1) forming a mixed anhydride comprising a trifluoromethanesulfonyl acyl residue and a carboxyl residue by contacting trifluoromethanesulfonic acid or a derivative thereof with a carboxyl compound selected from ketene, dialkyl ketenes, carboxylic acids, and derivatives of carboxylic acids and (2) subjecting the mixed anhydride to reactive distillation wherein the mixed anhydride undergoes disproportionation to produce triflic anhydride and a higher boiling carboxylic acid anhydride.
摘要翻译： 公开了以下步骤制备三氟甲磺酸酐的方法：（1）通过使三氟甲磺酸或其衍生物与选自乙烯酮，二烷基烯酮的羧基化合物接触，形成包含三氟甲磺酰基残基和羧基残基的混合酸酐， 羧酸和羧酸的衍生物，和（2）使混合酸酐进行反应蒸馏，其中混合酸酐经历歧化以产生三氟甲磺酸酐和较高沸点的羧酸酐。
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