Two step heterocyclic nitrogen extraction from petroleum oils

    公开(公告)号:US4671865A

    公开(公告)日:1987-06-09

    申请号:US781282

    申请日:1985-09-27

    IPC分类号: C10G21/16 C10G67/04

    CPC分类号: C10G67/04 C10G21/16

    摘要: The instant invention discloses a method of removing heterocyclic basic nitrogen compounds from petroleum oils which comprises first enhancing the concentration of the heterocyclic basic nitrogen compounds in a portion of the petroleum oil and then extracting the enhanced portion of the heterocyclic basic nitrogen compounds with a two phase system having an aliphatic carboxylic acid as the extracting agent. In the hydrotreating embodiment of this invention a portion of all of the nitrogen compounds are converted to heterocyclic basic nitrogen compounds and thereby more feasibly extracted. In the distillation embodiment of this invention the nitrogen compounds are actually concentrated and thereby result in a more feasible extraction with the aliphatic carboxylic acid.

    Microbiological desulfurization of coal and coal water admixture to
provide a desulfurized fuel
    24.
    发明授权
    Microbiological desulfurization of coal and coal water admixture to provide a desulfurized fuel 失效
    煤炭和煤水混合物的微生物脱硫提供脱硫燃料

    公开(公告)号:US4861723A

    公开(公告)日:1989-08-29

    申请号:US941666

    申请日:1986-12-15

    申请人: Ajay M. Madgavkar

    发明人: Ajay M. Madgavkar

    IPC分类号: C10L9/00

    CPC分类号: C10L9/00

    摘要: The invention disclosed is for a combination of two processes to enable the clean burning of coal in a coal water mixture. First the coal is ground and then treated with a desulfurizing microorganism to desulfurize the coal. After separation the coal is formulated into a coal water admixture in requisite quantities of water to coal, and with proper inclusion of additives, is combusted in a suitable furnace equipped with a means to burn a coal-water mixture. The desulfurized coal, after treatment with a select microorganism, will contain less than 1.0 wt % pyritic (inorganic) sulfur, be low in ash content and be cleanly combustible to capture its latent heat values.

    摘要翻译: 所公开的发明是两种工艺的组合,以使煤在煤水混合物中的清洁燃烧。 首先将煤粉碎,然后用脱硫微生物处理以对煤进行脱硫。 分离后,将煤配制成煤水混合物,其中需要量的水至煤中,并且在合适的包含添加剂的情况下,在装有燃烧煤 - 水混合物的装置的合适的炉中燃烧。 脱硫煤经选择性微生物处理后,含有少于1.0重量%的黄铁矿(无机)硫,灰分含量低,易燃易燃,以捕获其潜热值。

    Two-step heterocyclic nitrogen extraction from petroleum oils
    25.
    发明授权
    Two-step heterocyclic nitrogen extraction from petroleum oils 失效
    从石油油中提取二步杂环氮

    公开(公告)号:US4790930A

    公开(公告)日:1988-12-13

    申请号:US55479

    申请日:1987-05-29

    IPC分类号: C10G67/04 C10G17/04 C10G21/06

    CPC分类号: C10G67/04

    摘要: A process is disclosed for the removal of basic heterocyclic nitrogen compounds from a petroleum crude oil or fraction thereof which comprises first treating the petroleum crude oil or fraction thereof rich in basic heterocyclic nitrogen compounds in a two-phase extraction zone with an extractant consisting essentially of an aqueous solution of a lower carboxylic acid, preferably having between 1 and 15 carbon atoms. The extractant complexes the basic heterocyclic nitrogen compounds to produce a stream of petroleum crude oil or fraction thereof having a smaller content of heterocyclic nitrogen compounds and a stream comprising the lower carboxylic acid extractant with an increased quantity of basic heterocyclic nitrogen compounds. The petroleum crude oil or fraction thereof possessing a reduced quantity of heterocyclic nitrogen compounds is hydrotreated in the presence of hydrogen and a hydrotreating catalyst to further remove the basic heterocyclic nitrogen compounds. The extractant stream is treated in an extractant separation zone to renovate the extractant for recycle to the two-phase extractant zone, substantially free of removed basic heterocyclic nitrogen compounds.

    摘要翻译: 公开了用于从石油原油或其馏分中除去碱性杂环氮化合物的方法,其包括首先在两相萃取区中处理富含碱性杂环氮化合物的石油原油或其馏分,所述萃取剂基本上由 低级羧酸的水溶液,优选具有1至15个碳原子。 萃取剂使碱性杂环氮化合物复合以产生具有较小含量杂环氮化合物的石油原油或其馏分物流,以及包含较低羧基萃取剂的物流与碱性杂环氮化合物的量增加。 在氢气和加氢处理催化剂的存在下,将具有减少量的杂环氮化合物的石油原油或其馏分加氢处理以进一步除去碱性杂环氮化合物。 萃取剂流在萃取剂分离区中处理,以将萃取剂翻新以再循环至两相萃取剂区,基本上不含脱除的碱性杂环氮化合物。