ANTIFOULING CATALYST SYSTEMS FOR SELECTIVE ETHYLENE TRIMERIZATION

    公开(公告)号:US20220111375A1

    公开(公告)日:2022-04-14

    申请号:US17066830

    申请日:2020-10-09

    摘要: According to one embodiment, a catalyst system that reduces polymeric fouling may include at least one chromium compound, at least one aluminum compound, and at least one antifouling agent or a derivative thereof. The antifouling agent may have a structure including a central aluminum molecule bound to an R1 group, bound to an R2 group, and bound to an R3 group. One or more of the chemical groups R1, R2, and R3 may be antifouling groups having the structure —O((CH2)nO)mR4, a phosphonium or phosphonium salt, a sulfonate or sulfonate salt, a sulfonium or sulfonium salt, an ester, an anhydride, a polyether, or a long-chained amine-capped compound, where n is an integer from 1 to 20, m is an integer from 1 to 100, and R4 is a hydrocarbyl group. The chemical groups R1, R2, or R3 that do not include an antifouling group, if any, may be hydrocarbyl groups.

    Stabilized oxyborates and their use for oxidative conversion of hydrocarbons

    公开(公告)号:US11192092B1

    公开(公告)日:2021-12-07

    申请号:US17110941

    申请日:2020-12-03

    申请人: Bio2Electric, LLC

    发明人: John A. Sofranko

    摘要: An oxygen transfer agent comprising a metal-boron oxide is provided. The average oxidation state of the metal in the metal-boron oxide is about 3+, and has 10% or less of a stoichiometric excess in moles of Mn with respect to the boron. The oxygen transfer agent may further comprise a magnesia-phosphate cement. The oxygen transfer agent is capable of oxidatively dehydrogenating a hydrocarbon feed at reaction conditions to produce a dehydrogenated hydrocarbon product and water. The oxidative dehydrogenation can take place under reaction conditions of less than 1000 ppm weight molecular oxygen, or in the presence of more than 1000 ppm weight of molecular oxygen. Also provided are methods of using the oxygen transfer agents, and an apparatus for effecting the oxidative dehydrogenation of the hydrocarbon feed.