Abstract:
Fungicidal, insecticidal and acaricidal compositions containing, and methods of combating fungi, insects and acarids using, novel 4,5-bis-(trifluoromethylimino)-thiazolidines of the formula
IN WHICH Z is R-N or
AND R, R'', R'''' and R'''''' each is hydrogen; alkyl, alkenyl or alkynyl with up to 8 carbon atoms optionally substituted by halogen, cyano, lower alkoxy or alkylmercapto; optionally lower-alkylsubstituted cycloalkyl; carbalkoxy; aralkyl with up to 2 carbon atoms in the alkyl moiety; aryl with up to 14 carbon atoms in the ring system, the aryl radicals optionally being substituted by halogen, cyano, nitro, lower alkyl, haloalkyl, lower alkoxy or alkylmercapto; a 5- to 7-membered heterocyclic ring or a radical which together with Z and the N-atom of the thiazolidine ring forms a further 5- to 7-membered ring, the heterocyclic rings optionally being substituted with halogen, cyano, nitro or lower alkyl, or being fused with a benzene ring which is optionally partially hydrogenated.
Abstract:
Perhalogen-2-azapropenes such as perfluoro-2-azapropene and the novel compounds monofluorodichlormethyl isocyanide dichloride and difluoromonochloromethyl isocyanide dichloride are prepared by reacting trichloromethyl isocyanide dichloride with sodium fluoride in an organic solvent at a temperature of from 80* to 220*C. At least 5 moles of sodium fluoride are used to produce the perfluoro compound and no more than 5 moles are used to produce the novel isocyanide dichloride compounds.
Abstract:
Reacting a N-alkyl-amidosulfonyl chloride with a sulfenic acid chloride in the presence of an acid binding agent, optionally in the presence of an inert solvent, at a temperature of about 0*100*C., to form the corresponding N-alkyl-N-(trihalomethylthio)sulfamic acid chlorides, which are new compounds and which are intermediates for the preparation of fungicides.
Abstract:
N - TRIHALOGENMETHYLMERCAPTO - N TRIFLUOROMETHYLAMINO-BENZOIC ACID PHENYL ESTERS, I.E. (OPTIONALLY METHYL, (TRIFLUOROMETHYL, METHOXY, CHLORO OR NITRO - SUBSITUTED)(N - TRIHALOGENMETHYLMERCAPTO-N-TRIFLUOROMETHYL-AMINO)BENZOIC ACID (CARBOXY AND ALKOXYCARBONYL-SUBSITUTED)PHENYL ESTERS, WHICH POSSESS PESTICIDAL, ESPECIALLY ANTIMICROBIAL, PROPERTIES AND WHICH MAY BE PRODUCED BY CONVENTIONAL METHODS.
Abstract:
A PROCESS FOR THE PRODUCTION OF FLUORINATED BEZODIOXANES, WHEREIN A COMPOUND OF THE FORMULA
1-(X-COO-),2-(CCL3-),(R)M-BENZENE
WHEREIN M REPRESENTS AN INTEGER FROM 1 TO 4, R REPRESENTS THE SAME OR DIFFERENT MEMBERS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, HALOGEN, OPTIONALLY SUBSTITUTED ARYL, CHLOROCARBONYL, FLUOROCARBONYL, TRIFLUROACETEYL, ISOCYANATO, CN, NO2, FCOO, SC2F, CLCOO, SO2CL OR TRIHALOGENOMETHYL RADICALS; OR WHEREIN TWO ADJACENT RADICALS R FORM AN OPTIONALLY SUBSTITUTED ANELLATED BENZENE RING, AND X REPRESENTS HALOGEN, TRIFLUOROMETHYL OR TRICHLOROMETHYL, IS REACTED WITH ANHYDROUS HYDROFLUORIC ACID, AND THE RESULTANT NOVEL FLUORINATED BENZODIOXANES OF THE FORMULA.
2-X,2-F,4,4-DI(F-),(R)M-1,3-BENZODIOXAN
WHEREIN R, M AND X ARE AS PREVIOUSLY DEFINED. THE COMPOUNDS OF THIS INVENTION MAY BE EMPLOYED IN THE PRODUCTION OF PLANT PROTECTION AGENTS AND THEY FURTHER HAVE FUNGICIDAL PROPERTIES.
Abstract:
(N-TRIHALOMETHYLTHIO-N-TRIFLUOROMETHYL-AMINO)-BENZAMIDES WHICH POSSESS FUNGICIDAL PROPERTIES AND WHICH MAY BE PRODUCED BY REACTING THE CORRESPONDING FLUOROCARBONYL - N - TRIHALOMETHYLTHIO - N - TRIFLUOROMETHYLANILINES, IN THE PRESENCE OF AN ACID-BINDING AGENT, WITH AMINES.
Abstract:
ANTHRAQUINONE REACTIVE DYESTUFFS USEFUL IN DYEING HYDROXYL AND NITROGEN-CONTAINING TEXTILES HAVING A NUCLEUS CONSISTING OF A 1-AMINO-2-SULFO-4-(SUBSTITUTED OR UNSUBSTITUTED) 4''-AMINO OR ALKYLENEAMINO, TRIAZINYL (SULFONANALINO) ANTHRAQUINONE. THE DYESTUFFS SHOW IMPROVED FASTNESS PROPERTIES.