摘要:
A number of process steps are provided that can be combined to produce bridged cyclopentadienyl-fluorenyl metallocenes. The process steps include production of a cyclopentadiene compound from dicyclopentadiene; production and recovery of a fulvene compound using the cyclopentadiene compound; production of a raw metallocene product using the fulvene compound; and recovery of the pure metallocene from the raw product.
摘要:
Olefin polymerization catalysts or catalyst systems comprising a mixture, contact product, reaction product or complex comprising as elements or components: (A) at least one metallocene pre-catalyst compound or polymerization active metallocene compound; (B) at least one titanium containing metallocene compound; and when (A) is a metallocene pre-catalyst compound, (C) at least one activator; provided however: (I) the titanium-containing metallocene compound is inactive or substantially inactive for the polymerization of olefins prior to or concurrently with the use of the catalyst system for olefin polymerization. Also disclosed are processes for producing the catalyst system and polyolefins having desirable combinations of properties, including melt index and molecular weight distribution, which properties are particularly desirable for the manufacture of polyolefin film products, especially LLDPE film A preferred catalyst comprises a zirconium or hafnium metal containing metallocene, an inactivated titanocene and a SiO2 support carrier.
摘要:
An electrical appliance, such as a shredder, having low standby power consumption is provided. A power isolation circuit is positioned to electrically disconnect electronic components of the shredder from the shredder's primary power source. An auxiliary power source may generate or store power for powering electronic components, such as sensors or processors, while the primary power source is disconnected. A power isolation controller may use a timer, light detector, or user interaction sensors to determine whether to reconnect the primary power source to the electronic components.
摘要:
An electrical appliance, such as a shredder, having low standby power consumption is provided. A power isolation circuit is positioned to electrically disconnect electronic components of the shredder from the shredder's primary power source. An auxiliary power source may generate or store power for powering electronic components, such as sensors or processors, while the primary power source is disconnected. A power isolation controller may use a timer, light detector, or user interaction sensors to determine whether to reconnect the primary power source to the electronic components.
摘要:
Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. An improved method for preparing cyclopentadienyl complexes used to produce polyolefins is also provided.
摘要:
A shredder has a jam proof system with a thickness detector having a contact member which displaces as an article is inserted into the shredder and a resistance generating mechanism which provides a resistance force to the contact member, in response to its displacement. The greater the thickness of the article, the greater the resistance force realized. When a predetermined thickness is reached, there is a significant change in the resistance force. The resistance generating mechanism may include at least two spring mechanisms and provide feedback to the user that the inserted article may be too thick. In addition, the thickness detector may include a thickness sensor. The sensor may communicate with a controller to alert the user, and/or alter the operation of the shredder, in response to the thickness of the inserted article. For example, the controller may visually and/or audibly alert the user, or control shredder motor response.
摘要:
An assembly has a bin level detection system having at least one sensor positioned to receive radiation reflected off any material deposited in a bin and to determine an intensity of the reflected radiation. The intensity corresponds to an amount or level of shredded material deposited in the bin. The system may detect radiation from one or more emitters, or, alternatively, detect ambient light entering the bin via a window. A level indicator system may also be provided to indicate the amount of material deposited in the bin, including if the bin is full. The assembly may comprise a shredder and a shredder housing.
摘要:
This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, including polymerization methods using a supported catalyst composition. In one aspect, the present invention encompasses a catalyst composition comprising the contact product of a first metallocene compound, a second metallocene compound, at least one chemically-treated solid oxide, and at least one organoaluminum compound. The new resins were characterized by useful properties in impact, tear, adhesion, sealing, extruder motor loads and pressures at comparable melt index values, and neck-in and draw-down.
摘要:
This invention relates to catalyst compositions, methods, and polymers encompassing at least one first Group 4 metallocene compound comprising bridging η5-cyclopentadienyl-type ligands, in combination with at least one second Group 4 metallocene with non-bridging η5-cyclopentadienyl-type ligands, typically in combination with at least one cocatalyst, and at least one activator. The compositions and methods disclosed herein provide ethylene polymers with a bimodal molecular weight distribution.
摘要:
Disclosed herein is a shredder having a throat for receiving at least one article to be shredded therethrough and a shredder mechanism received in a shredder housing which is driven to shred the at least one article fed therein. At least one sensor emits and detects radiation to detect the presence of the at least one article or shredded particles. The sensor communicates with a controller to operate the shredder mechanism. The controller also calibrates an intensity of the radiation of the sensor(s) to or within a predetermined amount above a minimum level in order to reduce wear and run-on conditions.