公开(公告)号：US20070100135A1

公开(公告)日：2007-05-03

申请号：US10561393

申请日：2004-06-28

Applicant: Richard Riggs ,  Nicholas Westwood ,  David Smith ,  Colin Morton

Inventor： Richard Riggs ,  Nicholas Westwood ,  David Smith ,  Colin Morton

IPC: C07D491/02

CPC classification number: C07D487/04 ,  C07D491/04

Abstract: The present invention relates to a process for the preparation of furopyrroles of general formula (I), comprising (a) heating a compound of the formula (II) under microwave irradiation optionally in the presence of an inert solvent, wherein A1 and A2 are C1-C18alkyl, C2-C18alkenyl, C2-C18alkynyl, C5-C8cycloalkyl, C5-C8cycloalkenyl, aryl or heteroaryl, A3 is hydrogen, C1-C18alkyl, cyanomethyl, Ar3, —CR30R31—(CH2)m—Ar3 or Y—R32, wherein R30 and R31 independently of each other stand for hydrogen or C1-C4alkyl, or phenyl which can be substitute up to three times with C1-C4alkyl, Ar3 stands for aryl, C5-C8 cloalkyl, C5-C8cycloalkenyl or heteroaryl, which can be substituted one to three times with C1-C9alkyl, C1-C8alkoxy, halogen or phenyl, which can be substituted with C1-C8alkyI or C1-C8alkoxy one to three times, and m stands for 0, 1, 2, 3 or 4, R is C1‘-C18alkyl, in particular C1-C4alkyl, aryl, in particular phenyl, or aralkyl, in particular benzyl, which can be substituted one to three times with C1-C8alkyl, C1-C8alkoxy, or halogen, Y is —C(O)—, —C(O)O—, —C(O)NH—, —SO2NH— or —SO2— and R32 is C1-C18alkyl, Ar3, or aralkyl. The furopyrroles of the general formula (I) can be can be obtained in high yield and high purity by the process of the present invention.

公开(公告)号：US20060276651A1

公开(公告)日：2006-12-07

申请号：US10553776

申请日：2004-05-05

Applicant: Urs Lehmann ,  Colin Morton ,  Beat Schmidhalter ,  Jean-Luc Budry

Inventor： Urs Lehmann ,  Colin Morton ,  Beat Schmidhalter ,  Jean-Luc Budry

IPC: C07F15/06 ,  C07F15/04 ,  C07F15/02 ,  C07F1/08

CPC classification number: G11B7/2478 ,  C09B57/10 ,  C09B67/0033 ,  C09B69/04 ,  G11B7/246 ,  G11B7/2467 ,  G11B7/2472 ,  G11B7/249 ,  G11B7/2492 ,  G11B7/2495 ,  G11B7/2498 ,  G11B7/2531 ,  G11B2007/24612

Abstract: The present invention relates to metal complexes of formula I, compositions comprising the metal complexes, to recording media comprising the metal complexes or compositions and to the use of the compositions in the production of optical recording media: wherein the substituent are, as defined in the description. Use of the metal complexes formula (I) in combination with oxonol dyes results, surprisingly, in a comparatively weak tendency of the oxonol dyes to aggregate in the solid state so that the absorption curve remains advantageously narrow event in the solid state, as a result of which recording media having high reflectivity as well as high sensitivity and good playback characteristics in the desired spectral range are made available.

Abstract translation: 本发明涉及式I的金属络合物，包含金属络合物的组合物，包含金属络合物或组合物的记录介质以及组合物在制备光学记录介质中的用途：其中取代基如 描述。 使用金属络合物配方（I）与氧杂菁染料组合令人惊讶地导致氧固醇染料在固体状态下聚集的相对较弱的趋势，使得吸收曲线在固体状态下仍然有利地是狭窄的事件，结果 其中具有高反射率的记录介质以及在所需光谱范围内的高灵敏度和良好的回放特性是可用的。

公开(公告)号：US20050008974A1

公开(公告)日：2005-01-13

申请号：US10495678

申请日：2002-11-07

Applicant: Colin Morton ,  Taher Yousaf ,  Jean-Luc Budry ,  Beat Schmidhalter ,  Heinz Spahni

Inventor： Colin Morton ,  Taher Yousaf ,  Jean-Luc Budry ,  Beat Schmidhalter ,  Heinz Spahni

IPC: B41M5/26 ,  C07D487/22 ,  C07F15/02 ,  G11B7/004 ,  G11B7/24 ,  G11B7/244 ,  G11B7/248 ,  G11B7/253 ,  G11B7/26 ,  C09B47/04

CPC classification number: C07D487/22 ,  G11B7/248

Abstract: The invention relates to an optical recording medium comprising a substrate and a recording layer, wherein the recording layer comprises a complex of formula (I), or wherein Q2 is a ligand of formula (II), or a tautomer thereof, and R1, R2, R3, R4, R5, R6, R7, and R8 are each dependently of the others H, halogen, cyano, COOR9, CONHR9, CONR9R10, R9, OR9, SR9, NHR9 or NR9R10, wherein R9 and R10 are each independently of the other C6-C10aryl, C4-C9heteroaryl or linear or branched C1-C24alkyl, C3-C24cycloallyl, C2-C24alkenyl, C3-C24cycloalkenyl, C2-C24alkynyl, C1-C12heterocycloalkyl, C1-C12heterocycloalkenyl, unsubstituted or substituted, it also being possible for R1 and R2, R3 and R4, R5 and R6, and R7 and R8, independently of one another, to be bonded by a direct bond or via a bridge O or S, Mm+ is a transition metal cation having 5 or 6 electrons in the outermost occupied d-shell, L1 is a ligand having a sub-structure N—C, P—C or As—C, L2, independently of L1, is a further ligand containing at least one hetero atom N, P, As, O, S, Se or Te, L3− is CN−, SCN−, NCS−, OCN−, NCO−, N3—, L1-O−, L1-S—, L1-CO2−, L1-S03− or L1-P03−, L4−, independently of L3−, is CN−, SCN−, NCS−, OCN−, NCO−, N3−, L3-O−, L3-S−, L3-CO2− L3-SO3− or L3-PO3−, p and q are each independently of the other a number 0 or 1 (formula III), are each a counter-ion, m is a number 1, 2, 3 or 4 equal to the positive charge in Mm+ and n is a number −2, −1, +1 or +2, so that the quotient (formula IV) is not negative. Amorphous solid layers having excellent optical properties are obtained.

Abstract translation: 本发明涉及一种包括基材和记录层的光学记录介质，其中记录层包含式（I）的配合物，或其中Q 2是式（II）的配体或其互变异构体，和 R1，R2，R3，R4，R5，R6，R7和R8各自独立地为H，卤素，氰基，COOR9，CONHR9，CONR9R10，R9，OR9，SR9，NHR9或NR9R10，其中R9和R10各自 独立于其它C 6 -C 10芳基，C 4 -C 9杂芳基或直链或支链C 1 -C 24烷基，C 3 -C 24环烯基，C 2 -C 24烯基，C 3 -C 24环烯基，C 2 -C 24炔基，C 1 -C 12杂环烷基，未取代或取代的C 1 -C 12杂环烯基， R 1和R 2，R 3和R 4，R 5和R 6以及R 7和R 8彼此独立地可以通过直接键合或通过桥O或S键合，M m是具有5个碳原子的过渡金属阳离子 或6个电子，L1是具有子结构NC，PC或As-C，L2的配体，独立于L1，是另一个配体c 保持至少一个杂原子N，P，As，O，S，Se或Te，L3 - 是CN - ，SCN - ，NCS - ，OCN - ，NCO - ， - N3-，L1-O - ，L1-S-，L