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公开(公告)号：US20180318816A1
公开(公告)日：2018-11-08
申请号：US15969162
申请日：2018-05-02
Applicant: ExxonMobil Research and Engineering Company
Inventor： Joseph M. Falkowski , Mary S. Abdulkarim , Mobae Afeworki , Randall J. Meyer , Simon C. Weston
CPC classification number: B01J31/1691 , B01J20/226 , B01J31/00 , C07C5/2293 , C07C5/2562 , C07C2531/16 , C07C2531/24 , C07F9/3843 , C07F9/3856 , C07F9/425 , C07C11/10
Abstract: A novel metal organic framework, EMM-39, is described having the structure of UiO-66 and comprising bisphosphonate linking ligands. EMM-39 has acid activity and is useful as a catalyst in olefin isomerization. Also disclosed is a process of making metal organic frameworks, such as EMM-39, by heterogeneous ligand exchange, in which linking ligands having a first bonding functionality in a host metal organic framework are exchanged with linking ligands having a second different bonding functionality in the framework.
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公开(公告)号：US20180318815A1
公开(公告)日：2018-11-08
申请号：US15969062
申请日：2018-05-02
Applicant: ExxonMobil Research and Engineering Company
Inventor： Joseph M. Falkowski , Mobae Afeworki , Simon C. Weston
CPC classification number: B01J31/1691 , B01J31/185 , B01J2231/52 , B01J2531/0216 , B01J2531/48 , C07C5/2562 , C07C2531/18 , C07C2531/22 , C07C11/113
Abstract: A novel metal organic framework, EMM-33, is described having the structure of UiO-67 and comprising bisphosphonate linking ligands. EMM-33 has acid activity and is useful as a catalyst in olefin isomerization. Also disclosed is a process of making metal organic frameworks, such as EMM-33, by heterogeneous ligand exchange, in which linking ligands having a first bonding functionality in a host metal organic framework are exchanged with linking ligands having a second different bonding functionality in the framework.
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Patent Agency Ranking
公开(公告)号：US20220169663A1
公开(公告)日：2022-06-02
申请号：US17310633
申请日：2020-03-30
Applicant: ExxonMobil Research and Engineering Company
Inventor： Joseph M. Falkowski , Mary S. Abdulkarim , Carter W. Abney
Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers, typically as a coordination polymer. MOFs may comprise a plurality of metal centers, and a multidentate organic ligand coordinated via at least two binding sites to the plurality of metal centers to define an at least partially crystalline network structure having a plurality of internal pores, and in which the multidentate organic ligand comprises first and second binding sites bridged together with a third binding site comprising a diimine moiety. The multidentate organic ligand may comprise a reaction product of a vicinal dicarbonyl compound and an amine-substituted salicylic acid to define the first, second and third binding sites. Particular MOFs may comprise 5,59′-(((1E,2E)-ethane-1,2-diylidene)bis-(azaneylylidene))bis(2-hydroxybenzoic acid) as a multidentate organic ligand.
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公开(公告)号：US20220162247A1
公开(公告)日：2022-05-26
申请号：US17310615
申请日：2020-04-01
Applicant: ExxonMobil Research and Engineering Company
Inventor： Joseph M. Falkowski , Pavel Kortunov , Yogesh V. Joshi , Gerardo J. Majano
Abstract: A process for producing a bimetallic, terephthalate metal organic framework (MOF) having a flexible structure and comprising aluminum and iron cations, comprises contacting a water-soluble aluminum salt, a chelated iron compound and 1,4-benzenedicarboxylic acid or a salt thereof with a fluoride-free mixture of water and a polar organic solvent at a reaction temperature of less than 200° C. to produce a solid reaction product comprising the MOF.
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公开(公告)号：US20220089618A1
公开(公告)日：2022-03-24
申请号：US17417418
申请日：2019-12-13
Applicant: ExxonMobil Research and Engineering Company
Inventor： Gerardo J. Majano , Joseph M. Falkowski
Abstract: Metal-organic frameworks (MOFs) are highly porous entities comprising a multidentate ligand coordinated to multiple metal atoms, typically as a coordination polymer. MOFs are usually produced from a solvent in powder form under hydrothermal or solvothermal synthesis conditions. Alternately, powder-form precursors of MOFs may be formed by milling or mulling a substantially solid mixture of a metal salt and a multidentate organic ligand, optionally in the presence of a small amount of a solvent. The powder-form precursors may then undergo heating, typically in the absence of applied shear, to produce the corresponding MOF. Mulling may be differentiated from milling at least in that mulling applies to the substantially solid mixture at a non-constant pressure and milling applies a constant pressure while forming the powder-form precursor. In some cases, mulling may promote more effective formation of the powder-form precursor compared to milling.
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公开(公告)号：US10696558B2
公开(公告)日：2020-06-30
申请号：US15924597
申请日：2018-03-19
Applicant: ExxonMobil Research and Engineering Company
Inventor： Joseph M. Falkowski , David C. Calabro , Yi Du , Mobae Afeworki , Simon C. Weston
IPC: C01B39/04 , C07F3/06 , C07F15/06 , B01J31/16 , C07D235/04 , C07D471/04 , C07F19/00 , C01B39/02 , B01D71/02 , B01D69/14 , B01J20/22 , C07C7/13 , C07C53/10
Abstract: A novel zeolitic imidazolate framework material comprises a partially saturated benzimidazole or a partially saturated substituted benzimidazole as a linking ligand, optionally together with unsaturated benzimidazole or an unsaturated substituted benzimidazole as a further linking ligand.
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公开(公告)号：US10307747B2
公开(公告)日：2019-06-04
申请号：US15969182
申请日：2018-05-02
Applicant: ExxonMobil Research and Engineering Company
Inventor： Joseph M. Falkowski , Mary S. Abdulkarim , Mobae Afeworki , Randall J. Meyer , Simon C. Weston
Abstract: A novel metal organic framework, EMM-42, is described having the structure of UiO-66 and comprising bisphosphonate linking ligands. EMM-42 has acid activity and is useful as a catalyst in olefin isomerization. Also disclosed is a process of making metal organic frameworks, such as EMM-42, by heterogeneous ligand exchange, in which linking ligands having a first bonding functionality in a host metal organic framework are exchanged with linking ligands having a second different bonding functionality in the framework.
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