公开(公告)号：US20240351011A1

公开(公告)日：2024-10-24

申请号：US18686909

申请日：2022-09-07

Applicant: SHELL USA, INC.

Inventor： Roy VAN DEN BERG ,  Erik ZUIDEMA ,  Patrick VANDER HOOGERSTRAETE ,  Wiebe KIJLSTRA ,  Milos ROOSE

IPC: B01J29/44 ,  B01J6/00 ,  B01J21/06 ,  B01J37/00 ,  B01J37/02 ,  C07C5/27

CPC classification number: B01J29/44 ,  B01J6/001 ,  B01J21/06 ,  B01J37/0018 ,  B01J37/0207 ,  B01J37/0209 ,  B01J37/0213 ,  C07C5/2775 ,  B01J2231/52 ,  C07C2529/44

Abstract: A process for the preparation of a catalyst composition, which process comprises: forming a carrier from a mixture comprising a pentasil zeolite, one or more porous refractory oxide binders selected from alumina, amorphous silica-alumina, aluminum phosphate, magnesia, chromia, titania, boria and silica, and an aqueous solution of a zirconia precursor, and impregnating said carrier with metal dopants comprising one or more Group 10 metals selected from platinum, palladium and mixtures thereof in a total amount in the range of from 0.001 to 1 wt. % and, optionally, in the range of from 0.01 to 0.5 wt. % tin, based on the total weight of the catalyst composition; a catalyst composition prepared by said process; and a process for the use of said catalyst composition in xylene isomerisation are provided.

公开(公告)号：US20180318815A1

公开(公告)日：2018-11-08

申请号：US15969062

申请日：2018-05-02

Applicant: ExxonMobil Research and Engineering Company

Inventor： Joseph M. Falkowski ,  Mobae Afeworki ,  Simon C. Weston

IPC: B01J31/16 ,  C07C5/25

CPC classification number: B01J31/1691 ,  B01J31/185 ,  B01J2231/52 ,  B01J2531/0216 ,  B01J2531/48 ,  C07C5/2562 ,  C07C2531/18 ,  C07C2531/22 ,  C07C11/113

Abstract: A novel metal organic framework, EMM-33, is described having the structure of UiO-67 and comprising bisphosphonate linking ligands. EMM-33 has acid activity and is useful as a catalyst in olefin isomerization. Also disclosed is a process of making metal organic frameworks, such as EMM-33, by heterogeneous ligand exchange, in which linking ligands having a first bonding functionality in a host metal organic framework are exchanged with linking ligands having a second different bonding functionality in the framework.

公开(公告)号：US20180057476A1

公开(公告)日：2018-03-01

申请号：US15804874

申请日：2017-11-06

Applicant: FUTERRO S.A.

Inventor： Christian Penu ,  Benjamine Belloncle

IPC: C07D319/12 ,  B01J27/24 ,  B01J31/02 ,  B01J31/04 ,  B01J31/26 ,  C08G18/42 ,  B01J23/02 ,  C04B16/06 ,  C09D167/04

CPC classification number: C07D319/12 ,  B01J23/02 ,  B01J27/24 ,  B01J31/0267 ,  B01J31/0274 ,  B01J31/04 ,  B01J31/26 ,  B01J2231/52 ,  B01J2531/002 ,  B01J2531/004 ,  B01J2531/007 ,  C04B16/0683 ,  C08G18/428 ,  C09D167/04

Abstract: Process for increasingly producing D-Lactide and meso lactide by depolymerizing by back biting polylactide (PLA) said process which comprises: (i) Depolymerizing polylactide into its corresponding dimeric cyclic esters by heating the polylactide in the presence of a catalyst system comprising a catalyst and a co-catalyst in a reaction zone at temperature and pressure at which the polylactide is molten; (ii) Forming a vapor product stream from the reaction zone; (iii) Removing the vapor product stream and optionally condense it; (iv) Recovering, either together or separately meso-lactide, D-lactide and L-lactide.

公开(公告)号：US09714202B2

公开(公告)日：2017-07-25

申请号：US14546667

申请日：2014-11-18

Applicant: CPC CORPORATION, TAIWAN

Inventor： Ming-Yu Huang ,  Jann-Chen Lin ,  Yih-Ping Wang ,  Jung-Chung Wu

IPC: C07C5/29 ,  B01J31/08 ,  B01J31/02

CPC classification number: C07C5/29 ,  B01J31/0202 ,  B01J31/0209 ,  B01J31/08 ,  B01J2231/52 ,  C07C2527/126 ,  C07C2531/02 ,  C07C2531/04 ,  C07C2531/26 ,  C07C2603/74 ,  C07C13/615

Abstract: A method for producing adamantane includes the steps of preparing a catalytic composition including an acidic ionic liquid and a co-catalyst and subjecting a tetrahydrodicyclopentadiene-containing component to isomerization in the presence of the catalytic composition to form adamantane. The acidic ionic liquid includes aluminum chloride and a quaternary onium compound selected from the group consisting of a quaternary ammonium halide, a quaternary phosphonium halide, and a combination thereof. The co-catalyst is an oxygen-containing reagent.

公开(公告)号：US09637425B2

公开(公告)日：2017-05-02

申请号：US13852611

申请日：2013-03-28

Applicant: UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.

Inventor： Kevin P. McGowan ,  Adam S. Veige

IPC: C07C5/25 ,  C07C2/34 ,  B01J23/24 ,  C07C2/32 ,  C07F11/00 ,  B01J31/14 ,  B01J31/18 ,  B01J31/22

CPC classification number: C07C5/2587 ,  B01J23/24 ,  B01J31/143 ,  B01J31/1805 ,  B01J31/183 ,  B01J31/2208 ,  B01J2231/122 ,  B01J2231/52 ,  B01J2531/0244 ,  B01J2531/62 ,  C07B2200/09 ,  C07C2/32 ,  C07C2/34 ,  C07C5/2581 ,  C07C2531/22 ,  C07F11/00 ,  C07F11/005 ,  C08F110/02 ,  C08F4/69353 ,  C07C11/02

Abstract: A catalyst comprising a NCN pincer ligand group VI complex is capable of being used as an olefin polymerization or isomerization catalyst that does not require an expensive cocatalyst. The complex has the NCN pincer ligand in a trianionic form with the group VI in the +3 oxidation state or the +4 oxidation state and complexed to an anionic hydrocarbon group, or the complex has the NCN pincer ligand in a dianionic form with the group VI in the +2 oxidation state. The complex is capable of initiating the polymerization of alkenes without an added activator. The presence of a water scavenger and activator or cocatalyst, such as triisobutylaluminum, increases the catalytic activity. The complex is capable of selectively isomerizing 1-alkenes to cis/trans 2-alkenes.

公开(公告)号：US20160175829A1

公开(公告)日：2016-06-23

申请号：US14909683

申请日：2014-08-04

Applicant: THE GOVERNORS OF THE UNIVERSITY OF ALBERTA

Inventor： Steven H. BERGENS ,  Suneth KALAPUGAMA ,  Prabin NEPAL ,  Elizabeth MCGINITIE

IPC: B01J31/24 ,  B01J19/24 ,  C07C29/56 ,  C07B35/02 ,  C07C45/00 ,  C07C231/12 ,  C07C51/36 ,  C07C67/303 ,  B01J37/02 ,  C07F15/00

CPC classification number: B01J31/2452 ,  B01J19/24 ,  B01J27/053 ,  B01J31/165 ,  B01J31/2295 ,  B01J31/2409 ,  B01J35/02 ,  B01J37/0203 ,  B01J37/0209 ,  B01J2219/24 ,  B01J2231/52 ,  B01J2231/645 ,  B01J2531/0213 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  C07B35/02 ,  C07C29/56 ,  C07C45/00 ,  C07C51/36 ,  C07C67/303 ,  C07C231/12 ,  C07F15/0073

Abstract: The present application provides a composite material and system for use in a heterogeneous flow reactor, which can include: a catalytic polymeric framework comprising catalyst-containing monomeric units each separated by at least one non-catalyst-containing monomeric unit; and a solid support material, wherein the catalytic polymeric framework is covalently or non-covalently immobilized on or in the support material. Each catalyst-containing monomeric subunit in the polymeric framework comprises a transition metal bound to a catalyst ligand. Also provided are methods of manufacture and use of the catalyst system and composite material.

Abstract translation: 本申请提供了一种用于非均相流动反应器的复合材料和系统，其可以包括：催化聚合物框架，其包含含有至少一种不含催化剂的单体单元分离的含催化剂的单体单元; 和固体支持材料，其中催化聚合物骨架共价或非共价固定在载体材料上或载体材料中。 聚合物框架中的每个含催化剂的单体亚单元包含与催化剂配体结合的过渡金属。 还提供了催化剂体系和复合材料的制造和使用方法。

公开(公告)号：US20150315110A1

公开(公告)日：2015-11-05

申请号：US14442856

申请日：2013-11-14

Applicant: TAKASAGO INTERNATIONAL CORPORATION

Inventor： Hisanori ITOH ,  Yoji HORI

IPC: C07C29/56 ,  B01J31/22

CPC classification number: B01J31/22 ,  B01J31/143 ,  B01J31/2295 ,  B01J2231/324 ,  B01J2231/52 ,  B01J2531/31 ,  C07B53/00 ,  C07B2200/07 ,  C07C29/56 ,  C07C2601/14 ,  C07F5/06 ,  C07C35/17

Abstract: An aluminum catalyst is obtained by reacting at least one compound of a specific alkylaluminum compound and a specific hydridoaluminum compound with a specific hydroxy compound. The specific hydroxyl compound is a specific 2-cycloalkyl-6-arylphenol or a specific di(2-cycloalkyl-6-arylphenol). A method for producing isopulegol or optically active isopulegol includes selectively cyclizing citronellal using the aluminum catalyst.

Abstract translation: 通过使特定的烷基铝化合物和特定的氢化铝化合物的至少一种化合物与特定的羟基化合物反应来获得铝催化剂。 特定的羟基化合物是特定的2-环烷基-6-芳基苯酚或特定的二（2-环烷基-6-芳基苯酚）。 异胡列酮或光学活性异胡胆碱的制备方法包括使用铝催化剂选择性环化香茅醛。

公开(公告)号：US09120736B2

公开(公告)日：2015-09-01

申请号：US14112454

申请日：2012-02-25

Applicant: Lukas J. Gooβen ,  Dominik Ohlmann ,  Markus Dierker

Inventor： Lukas J. Gooβen ,  Dominik Ohlmann ,  Markus Dierker

IPC: C07C51/353 ,  B01J31/22 ,  B01J31/24 ,  C07C67/333 ,  C07C67/475 ,  C11C3/00 ,  C10L1/02

CPC classification number: C07C51/353 ,  B01J31/2217 ,  B01J31/2273 ,  B01J31/2278 ,  B01J31/24 ,  B01J2231/52 ,  B01J2231/543 ,  B01J2531/0216 ,  B01J2531/821 ,  B01J2531/824 ,  C07C67/333 ,  C07C67/475 ,  C07C2531/24 ,  C10G2300/1011 ,  C10L1/026 ,  C11C3/00 ,  Y02P30/20 ,  C07C69/533 ,  C07C69/593 ,  C07C57/03 ,  C07C57/13

Abstract: The invention relates to a method for producing compositions containing unsaturated compounds, wherein (A) one or more unsaturated monocarboxylic acids having 10 to 24 C-atoms or esters of said monocarboxylic acids and optionally (B) one or more compounds having at least one C═C double bond (wherein the compounds (B) are different from the compounds (A)) are subjected to a tandem isomerization/metathesis reaction sequence in the presence of a palladium catalyst and a ruthenium catalyst, providing that the palladium catalysts used are compounds that contain at least one structural element Pd—P(R1R2R3), wherein the radicals R1 to R3, independently of one another, each comprise 2 to 10 C-atoms, which may be aliphatic, alicyclic, aromatic or heterocyclic respectively, providing that at least one of the radicals R1 to R3 contains a beta-hydrogen, wherein the palladium catalyst is used as such or is produced in situ, providing that the method is carried out in the absence of substances that have a pKa value of 3 or less.

Abstract translation: 本发明涉及一种生产含有不饱和化合物的组合物的方法，其中（A）一种或多种具有10-24个C原子的不饱和一元羧酸或所述一元羧酸的酯和任选的（B）一种或多种具有至少一个C 在钯催化剂和钌催化剂的存在下，将化合物（B）与化合物（A）不同）进行串联异构化/复分解反应顺序，条件是使用的钯催化剂为化合物 其包含至少一个结构单元Pd-P（R 1 R 2 R 3），其中基团R 1至R 3彼此独立地各自包含2至10个C原子，其可以分别为脂族，脂环族，芳族或杂环，条件是在 基团R1至R3中的至少一个含有β-氢，其中钯催化剂原样使用或原位生产，条件是该方法在不存在物质t 帽子的pKa值为3以下。

公开(公告)号：US08981126B2

公开(公告)日：2015-03-17

申请号：US14000997

申请日：2012-02-23

Applicant: Manuel Alcarazo ,  Hans Bruns ,  Jekaterina Petuskova

Inventor： Manuel Alcarazo ,  Hans Bruns ,  Jekaterina Petuskova

IPC: C07D311/94 ,  C07F9/50 ,  B01J31/24 ,  C07F15/00 ,  C07F1/12

CPC classification number: C07F9/5018 ,  B01J31/2404 ,  B01J2231/4211 ,  B01J2231/52 ,  B01J2531/18 ,  B01J2531/822 ,  B01J2531/847 ,  C07D311/94 ,  C07F1/12 ,  C07F9/02 ,  C07F9/50 ,  C07F9/5022 ,  C07F15/00 ,  C07F15/0073 ,  C07F15/0093

Abstract: Phosphenium compounds with the general formula I: in which R1, R2, R3 and R4 are identical or different and represent a linear or branched C1-C6-alkyl radical, which can optionally be substituted, or R1 and R2 and/or R3 and R4 are bonded to one another with the formation of a ring, R5 and R6 stand for a saturated or unsaturated and linear or branched alkyl group, alkenyl group or aryl group, which can have suitable substituents, even heteroatoms as substituents, or a heteroatom-comprising hydrocarbon group, which can have suitable substituents, and the R5 and R6 radicals can form a ring which can be 4- to 20-membered, saturated or unsaturated and alicyclic or heteroalicyclic and can exhibit suitable substituents, X− represents an anion, a process for the preparation thereof, and also the use of these compounds in metal complexes which can be used as catalysts in organic synthesis, are claimed.

Abstract translation: 具有通式I的磷酸酯化合物，其中R 1，R 2，R 3和R 4相同或不同，表示可任选被取代的直链或支链C 1 -C 6烷基，或R 1和R 2和/或R 3和R 4 形成环，R5和R6表示饱和或不饱和的直链或支链烷基，烯基或芳基，其可以具有合适的取代基，甚至杂原子作为取代基，或含杂原子的 烃基，其可以具有合适的取代基，并且R 5和R 6基团可以形成可以是4-至20-元饱和或不饱和和脂环族或杂脂环的环并且可以表现出合适的取代基，X-表示阴离子， 为了制备它们，还要求使用这些化合物在可用作有机合成中的催化剂的金属络合物中。

公开(公告)号：US20140046081A1

公开(公告)日：2014-02-13

申请号：US14112454

申请日：2012-02-25

Applicant: Lukas J. Goossen ,  Dominik Ohlmann ,  Markus Dierker

Inventor： Lukas J. Goossen ,  Dominik Ohlmann ,  Markus Dierker

IPC: C07C51/353 ,  C07C67/333

CPC classification number: C07C51/353 ,  B01J31/2217 ,  B01J31/2273 ,  B01J31/2278 ,  B01J31/24 ,  B01J2231/52 ,  B01J2231/543 ,  B01J2531/0216 ,  B01J2531/821 ,  B01J2531/824 ,  C07C67/333 ,  C07C67/475 ,  C07C2531/24 ,  C10G2300/1011 ,  C10L1/026 ,  C11C3/00 ,  Y02P30/20 ,  C07C69/533 ,  C07C69/593 ,  C07C57/03 ,  C07C57/13

Abstract: The invention relates to a method for producing compositions containing unsaturated compounds, wherein (A) one or more unsaturated monocarboxylic acids having 10 to 24 C-atoms or esters of said monocarboxylic acids and optionally (B) one or more compounds having at least one C═C double bond (wherein the compounds (B) are different from the compounds (A)) are subjected to a tandem isomerization/metathesis reaction sequence in the presence of a palladium catalyst and a ruthenium catalyst, providing that the palladium catalysts used are compounds that contain at least one structural element Pd—P(R1R2R3), wherein the radicals R1 to R3, independently of one another, each comprise 2 to 10 C-atoms, which may be aliphatic, alicyclic, aromatic or heterocyclic respectively, providing that at least one of the radicals R1 to R3 contains a beta-hydrogen, wherein the palladium catalyst is used as such or is produced in situ, providing that the method is carried out in the absence of substances that have a pKa value of 3 or less.

Abstract translation: 本发明涉及一种生产含有不饱和化合物的组合物的方法，其中（A）一种或多种具有10-24个C原子的不饱和一元羧酸或所述一元羧酸的酯和任选的（B）一种或多种具有至少一个C = C双键（其中化合物（B）不同于化合物（A））在钯催化剂和钌催化剂存在下进行串联异构化/复分解反应，条件是所用的钯催化剂是化合物 其包含至少一个结构单元Pd-P（R 1 R 2 R 3），其中基团R 1至R 3彼此独立地各自包含2至10个C原子，其可以分别为脂族，脂环族，芳族或杂环，条件是在 基团R1至R3中的至少一个含有β-氢，其中钯催化剂原样使用或原位生产，条件是该方法在不存在物质的情况下进行 pKa值为3以下。