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公开(公告)号：US20200147545A1
公开(公告)日：2020-05-14
申请号：US16660029
申请日：2019-10-22
Applicant: ExxonMobil Research and Engineering Company
Inventor： Mohsen S. Yeganeh , Pavel Kortunov , P. Scott Northrop , Xiaozhou Zhang , Giovanni Pilloni , Ning Ma , Robert J. Colby , Qiuzi Li , Zarath M. Summers , Matthew S. Ide
Abstract: The present disclosure relates to a porous liquid or a porous liquid enzyme that includes a high surface area solid and a liquid film substantially covering the high surface area solid. The porous liquid or porous liquid enzyme may be contacted with a fluid that is immiscible with the liquid film such that a liquid-fluid interface is formed. The liquid film may facilitate mass transfer of a substance or substrate across the liquid-fluid interface. The present disclosure also provides methods of performing liquid-based extractions and enzymatic reactions utilizing the porous liquid or porous liquid enzyme of the present disclosure.
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Patent Agency Ranking
公开(公告)号：US09738539B2
公开(公告)日：2017-08-22
申请号：US14744485
申请日：2015-06-19
Applicant: ExxonMobil Research and Engineering Company
Inventor： Edward W. Corcoran, Jr. , Pavel Kortunov , Charanjit S. Paur , Peter I. Ravikovitch , Yu Wang , Avelino Corma Canos , Fernando Rey Garcia , Susana Valencia Valencia , Angel Cantín Sanz , Miguel Palomino Roca
IPC: C01B39/48 , B01J20/18 , B01J29/70 , B01D71/02 , B01D53/04 , B01D53/047 , C01B3/50 , B01D53/02 , B01D53/22 , C01B17/16 , C01B21/04 , C01C1/12 , B01J20/30 , C07C1/20 , C07C1/32 , C07C2/76 , C07C29/00 , C07C41/01 , C01B39/06 , C01B39/08 , C01B37/00 , C01B37/02 , C01B39/12
CPC classification number: C01B39/48 , B01D53/02 , B01D53/04 , B01D53/0407 , B01D53/0462 , B01D53/047 , B01D53/228 , B01D53/229 , B01D71/028 , B01D2253/108 , B01D2256/10 , B01D2256/12 , B01D2256/16 , B01D2256/18 , B01D2256/20 , B01D2256/22 , B01D2256/24 , B01D2256/245 , B01D2256/26 , B01D2257/302 , B01D2257/304 , B01D2257/40 , B01D2257/404 , B01D2257/406 , B01D2257/50 , B01D2257/504 , B01D2257/70 , B01D2257/702 , B01D2257/7022 , B01D2257/80 , B01J20/18 , B01J20/3078 , B01J29/70 , B01J29/86 , B01J29/89 , C01B3/508 , C01B17/167 , C01B21/0466 , C01B37/002 , C01B37/007 , C01B37/02 , C01B39/06 , C01B39/08 , C01B39/12 , C01B2203/0405 , C01B2210/0018 , C01C1/12 , C07C1/20 , C07C1/322 , C07C2/76 , C07C29/00 , C07C41/01 , C07C2529/70 , C07C2529/76 , C07C2529/78 , Y02C10/08
Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1−g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
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公开(公告)号：US09688542B2
公开(公告)日：2017-06-27
申请号：US14744334
申请日：2015-06-19
Applicant: ExxonMobil Research and Engineering Company
Inventor： Edward W. Corcoran, Jr. , Pavel Kortunov , Charanjit S. Paur , Peter I. Ravikovitch , Yu Wang , Avelino Corma Canos , Fernando Rey Garcia , Susana Valencia Valencia , Angel Cantin Sanz , Miguel Palomino Roca
IPC: B01D53/22 , B01D53/02 , B01J20/18 , C01B3/50 , C01B17/16 , C01B21/04 , C01B39/48 , C01C1/12 , B01J29/70 , B01D71/02 , B01D53/04 , B01D53/047 , B01J20/30 , C07C1/20 , C07C1/32 , C07C2/76 , C07C29/00 , C07C41/01 , C01B39/06 , C01B39/08 , C01B37/00 , C01B37/02 , C01B39/12
CPC classification number: C01B39/48 , B01D53/02 , B01D53/04 , B01D53/0407 , B01D53/0462 , B01D53/047 , B01D53/228 , B01D53/229 , B01D71/028 , B01D2253/108 , B01D2256/10 , B01D2256/12 , B01D2256/16 , B01D2256/18 , B01D2256/20 , B01D2256/22 , B01D2256/24 , B01D2256/245 , B01D2256/26 , B01D2257/302 , B01D2257/304 , B01D2257/40 , B01D2257/404 , B01D2257/406 , B01D2257/50 , B01D2257/504 , B01D2257/70 , B01D2257/702 , B01D2257/7022 , B01D2257/80 , B01J20/18 , B01J20/3078 , B01J29/70 , B01J29/86 , B01J29/89 , C01B3/508 , C01B17/167 , C01B21/0466 , C01B37/002 , C01B37/007 , C01B37/02 , C01B39/06 , C01B39/08 , C01B39/12 , C01B2203/0405 , C01B2210/0018 , C01C1/12 , C07C1/20 , C07C1/322 , C07C2/76 , C07C29/00 , C07C41/01 , C07C2529/70 , C07C2529/76 , C07C2529/78 , Y02C10/08
Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1−g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
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公开(公告)号：US20220213125A1
公开(公告)日：2022-07-07
申请号：US17612464
申请日：2019-12-13
Applicant: ExxonMobil Research and Engineering Company
Inventor： Gerardo J. Majano , Joseph M. Falkowski , Scott J. Weigel , Matthew T. Kapelewski , Pavel Kortunov
Abstract: Metal-organic frameworks (MOFs) are highly porous entities comprising a multidentate ligand coordinated to multiple metal atoms, typically as a coordination polymer. MOFs are usually produced in powder form. Extrusion of powder-form MOFs to produce shaped bodies has heretofore proven difficult due to loss of surface area and poor crush strength of MOF extrudates, in addition to phase transformations occurring during extrusion. The choice of mixing conditions and the mixing solvent when forming MOF extrudates can impact these factors. Extrudates comprising a MOF consolidated material may feature the MOF consolidated material having a BET surface area of about 50% or greater relative to that of a pre-crystallized MOF powder material used to form the extrudate. X-ray powder diffraction of the extrudate shows about 20% or less conversion of the MOF consolidated material into a phase differing from that of the pre-crystallized MOF powder material.
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公开(公告)号：US09695056B2
公开(公告)日：2017-07-04
申请号：US14744248
申请日：2015-06-19
Applicant: ExxonMobil Research and Engineering Company
Inventor： Edward W. Corcoran, Jr. , Pavel Kortunov , Charanjit S. Paur , Peter I. Ravikovitch , Yu Wang , Avelino Corma Canos , Fernando Rey Garcia , Susana Valencia Valencia , Angel Cantin Sanz , Miguel Palomino Roca
IPC: B01J20/18 , C01B39/48 , B01J29/70 , B01D71/02 , B01D53/04 , B01D53/047 , C01B3/50 , B01D53/02 , B01D53/22 , C01B17/16 , C01B21/04 , C01C1/12 , B01J20/30 , C07C1/20 , C07C1/32 , C07C2/76 , C07C29/00 , C07C41/01 , C01B39/06 , C01B39/08 , C01B37/00 , C01B37/02 , C01B39/12
CPC classification number: C01B39/48 , B01D53/02 , B01D53/04 , B01D53/0407 , B01D53/0462 , B01D53/047 , B01D53/228 , B01D53/229 , B01D71/028 , B01D2253/108 , B01D2256/10 , B01D2256/12 , B01D2256/16 , B01D2256/18 , B01D2256/20 , B01D2256/22 , B01D2256/24 , B01D2256/245 , B01D2256/26 , B01D2257/302 , B01D2257/304 , B01D2257/40 , B01D2257/404 , B01D2257/406 , B01D2257/50 , B01D2257/504 , B01D2257/70 , B01D2257/702 , B01D2257/7022 , B01D2257/80 , B01J20/18 , B01J20/3078 , B01J29/70 , B01J29/86 , B01J29/89 , C01B3/508 , C01B17/167 , C01B21/0466 , C01B37/002 , C01B37/007 , C01B37/02 , C01B39/06 , C01B39/08 , C01B39/12 , C01B2203/0405 , C01B2210/0018 , C01C1/12 , C07C1/20 , C07C1/322 , C07C2/76 , C07C29/00 , C07C41/01 , C07C2529/70 , C07C2529/76 , C07C2529/78 , Y02C10/08
Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1−g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
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公开(公告)号：US20220162247A1
公开(公告)日：2022-05-26
申请号：US17310615
申请日：2020-04-01
Applicant: ExxonMobil Research and Engineering Company
Inventor： Joseph M. Falkowski , Pavel Kortunov , Yogesh V. Joshi , Gerardo J. Majano
Abstract: A process for producing a bimetallic, terephthalate metal organic framework (MOF) having a flexible structure and comprising aluminum and iron cations, comprises contacting a water-soluble aluminum salt, a chelated iron compound and 1,4-benzenedicarboxylic acid or a salt thereof with a fluoride-free mixture of water and a polar organic solvent at a reaction temperature of less than 200° C. to produce a solid reaction product comprising the MOF.
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