公开(公告)号：US20060009353A1

公开(公告)日：2006-01-12

申请号：US10963667

申请日：2004-10-13

申请人： Yeping Cai ,  William Faris ,  Jeffery Riley ,  Robert Riley ,  David Tolle ,  Jon Wagner ,  Shizhong Zhao

发明人： Yeping Cai ,  William Faris ,  Jeffery Riley ,  Robert Riley ,  David Tolle ,  Jon Wagner ,  Shizhong Zhao

IPC分类号： B01J23/02

CPC分类号： B01J23/63 ,  B01J21/063 ,  B01J21/066 ,  B01J23/02 ,  B01J23/10 ,  B01J23/58 ,  B01J23/6484 ,  B01J23/78 ,  B01J23/83 ,  B01J23/8474 ,  B01J35/0053 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/10 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1094 ,  Y02P20/52

摘要： A promoted calcium-alumina supported reforming catalyst that is particularly useful for reforming reactions where low H2/CO ratio synthesis gas, such as less than 2.3 is generated directly is disclosed. The catalyst comprises from about 25 wt % to about 98 wt % alumina, from about 0.5 wt % to about 35 wt % calcium oxide, from about 0.01 wt % to about 35 wt % of a promoter, and from about 0.05 wt % to about 30 wt % of an active metal. The promoter is selected from the group consisting of titanium, zirconium, yttrium, niobium, elements of the lanthanum-series, such as, without limitation, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, ytterbium, and combinations thereof. The active metal is selected from the group consisting of nickel, cobalt, rhodium, ruthenium, palladium, platinum, iridium and combinations thereof as active metal, wherein the calcium oxide is combined with the alumina to form aluminum-rich calcium aluminates.

摘要翻译： 公开了一种促进的钙 - 氧化铝载体重整催化剂，其特别可用于重整反应，其中低H 2 / CO比合成气如小于2.3直接产生。 催化剂包含约25重量％至约98重量％的氧化铝，约0.5重量％至约35重量％的氧化钙，约0.01重量％至约35重量％的助催化剂和约0.05重量％至约 30重量％的活性金属。 助催化剂选自钛，锆，钇，铌，镧系元素，例如但不限于镧，铈，镨，钕，ium，钐，铕，钆，镱和组合 其中。 活性金属选自镍，钴，铑，钌，钯，铂，铱及其组合作为活性金属，其中氧化钙与氧化铝组合以形成富铝的铝酸钙。

公开(公告)号：US20060009352A1

公开(公告)日：2006-01-12

申请号：US10888645

申请日：2004-07-09

申请人： Shizhong Zhao ,  Yeping Cai ,  X.D. Hu ,  Jurgen Ladebeck ,  Jon Wagner

发明人： Shizhong Zhao ,  Yeping Cai ,  X.D. Hu ,  Jurgen Ladebeck ,  Jon Wagner

IPC分类号： B01J23/10

CPC分类号： B01J23/63 ,  B01J21/063 ,  B01J21/066 ,  B01J23/02 ,  B01J23/10 ,  B01J23/58 ,  B01J23/6484 ,  B01J23/78 ,  B01J23/83 ,  B01J23/8474 ,  B01J35/0053 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/10 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1094 ,  Y02P20/52

摘要： A promoted calcium-alumina supported reforming catalyst that is particularly useful for reforming reactions where low H2/CO ratio synthesis gas, such as less than 2.3 is generated directly is disclosed. The catalyst comprises from about 25 wt % to about 98 wt % alumina, from about 0.5 wt % to about 35 wt % calcium oxide, from about 0.01 wt % to about 35 wt % of a promoter, and from about 0.05 wt % to about 30 wt % of an active metal. The promoter is selected from the group consisting of titanium, zirconium, yttrium, niobium, elements of the lanthanum-series, such as, without limitation, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, ytterbium, and combinations thereof. The active metal is selected from the group consisting of nickel, cobalt, rhodium, ruthenium, palladium, platinum, iridium and combinations thereof as active metal, wherein the calcium oxide is combined with the alumina to form aluminum-rich calcium aluminates.

摘要翻译： 公开了一种促进的钙 - 氧化铝载体重整催化剂，其特别可用于重整反应，其中低H 2 / CO比合成气如小于2.3直接产生。 催化剂包含约25重量％至约98重量％的氧化铝，约0.5重量％至约35重量％的氧化钙，约0.01重量％至约35重量％的助催化剂和约0.05重量％至约 30重量％的活性金属。 助催化剂选自钛，锆，钇，铌，镧系元素，例如但不限于镧，铈，镨，钕，ium，钐，铕，钆，镱和组合 其中。 活性金属选自镍，钴，铑，钌，钯，铂，铱及其组合作为活性金属，其中氧化钙与氧化铝组合以形成富铝的铝酸钙。