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    Promoted calcium-aluminate supported catalysts for synthesis gas generation
    1.
    发明申请
    Promoted calcium-aluminate supported catalysts for synthesis gas generation 有权
    促进铝酸钙负载催化剂合成气生成

    公开(公告)号：US20060009352A1

    公开(公告)日：2006-01-12

    申请号：US10888645

    申请日：2004-07-09

    申请人： Shizhong Zhao ,  Yeping Cai ,  X.D. Hu ,  Jurgen Ladebeck ,  Jon Wagner

    发明人： Shizhong Zhao ,  Yeping Cai ,  X.D. Hu ,  Jurgen Ladebeck ,  Jon Wagner

    IPC分类号： B01J23/10

    CPC分类号： B01J23/63 ,  B01J21/063 ,  B01J21/066 ,  B01J23/02 ,  B01J23/10 ,  B01J23/58 ,  B01J23/6484 ,  B01J23/78 ,  B01J23/83 ,  B01J23/8474 ,  B01J35/0053 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/10 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1094 ,  Y02P20/52

    摘要： A promoted calcium-alumina supported reforming catalyst that is particularly useful for reforming reactions where low H2/CO ratio synthesis gas, such as less than 2.3 is generated directly is disclosed. The catalyst comprises from about 25 wt % to about 98 wt % alumina, from about 0.5 wt % to about 35 wt % calcium oxide, from about 0.01 wt % to about 35 wt % of a promoter, and from about 0.05 wt % to about 30 wt % of an active metal. The promoter is selected from the group consisting of titanium, zirconium, yttrium, niobium, elements of the lanthanum-series, such as, without limitation, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, ytterbium, and combinations thereof. The active metal is selected from the group consisting of nickel, cobalt, rhodium, ruthenium, palladium, platinum, iridium and combinations thereof as active metal, wherein the calcium oxide is combined with the alumina to form aluminum-rich calcium aluminates.

    摘要翻译： 公开了一种促进的钙 - 氧化铝载体重整催化剂，其特别可用于重整反应，其中低H 2 / CO比合成气如小于2.3直接产生。 催化剂包含约25重量％至约98重量％的氧化铝，约0.5重量％至约35重量％的氧化钙，约0.01重量％至约35重量％的助催化剂和约0.05重量％至约 30重量％的活性金属。 助催化剂选自钛，锆，钇，铌，镧系元素，例如但不限于镧，铈，镨，钕，ium，钐，铕，钆，镱和组合 其中。 活性金属选自镍，钴，铑，钌，钯，铂，铱及其组合作为活性金属，其中氧化钙与氧化铝组合以形成富铝的铝酸钙。

    Catalyst for production of hydrogen and synthesis gas
    2.
    发明授权
    Catalyst for production of hydrogen and synthesis gas 有权
    生产氢气和合成气的催化剂

    公开(公告)号：US07871961B2

    公开(公告)日：2011-01-18

    申请号：US11458115

    申请日：2006-07-18

    申请人： Shizhong Zhao ,  X.D. Hu ,  David Patrick Tolle ,  David B. Rogers

    发明人： Shizhong Zhao ,  X.D. Hu ,  David Patrick Tolle ,  David B. Rogers

    IPC分类号： B01J23/00

    CPC分类号： C01B3/40 ,  B01J23/6567 ,  B01J35/1009 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/1064 ,  Y02P20/52

    摘要： A high efficiency catalyst for use in a catalytic partial oxidation process for the production of hydrogen or syngas gas from hydrocarbons is disclosed. The catalyst comprises rhenium in combination with a second metal selected from the group of rhenium to second metal of 25:1 to 1:1. the process comprises reacting a feed containing hydrocarbons with an oxygen source at a C/O ratio of about 0.9 to 1.1 in the presence of the catalyst, and wherein the gas hourly space velocity of the feed over the catalyst ranges from about 1,000 hr−1 to about 2,000,000 hr −1. In the process, the catalyst is maintained as a temperature of from about 500° C. to about 1,500° C. as the feed makes contact with the catalyst.

    摘要翻译： 公开了一种用于从烃生产氢气或合成气气体的催化部分氧化工艺中使用的高效催化剂。 该催化剂包含与25:1至1:1的选自铼至第二金属的第二金属组合的铼。 该方法包括在催化剂存在下使包含烃的进料与氧源的C / O比为约0.9至1.1反应，并且其中进料在催化剂上的气时空速约为1,000小时-1 至约2,000,000小时-1。 在该方法中，当进料与催化剂接触时，催化剂保持为约500℃至约1500℃的温度。

    Catalyst for Production of Hydrogen and Synthesis Gas
    3.
    发明申请
    Catalyst for Production of Hydrogen and Synthesis Gas 有权
    催化剂生产氢气和合成气

    公开(公告)号：US20080056985A1

    公开(公告)日：2008-03-06

    申请号：US11458115

    申请日：2006-07-18

    申请人： Shizhong Zhao ,  X.D. Hu ,  David Patrick Tolle ,  David B. Rogers

    发明人： Shizhong Zhao ,  X.D. Hu ,  David Patrick Tolle ,  David B. Rogers

    IPC分类号： C01B3/26

    CPC分类号： C01B3/40 ,  B01J23/6567 ,  B01J35/1009 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/1064 ,  Y02P20/52

    摘要： A high efficiency catalyst for use in a catalytic partial oxidation process for the production of hydrogen or syngas gas from hydrocarbons is disclosed. The catalyst comprises rhenium in combination with a second metal selected from the group consisting of platinum, iridium, ruthenium, rhodium, and palladium at an atomic ratio of rhenium to second metal of from 25:1 to 1:1. The process comprises reacting a feed containing hydrocarbons with an oxygen source at a C/O ratio of about 0.9 to about 1.1 in the presence of the catalyst, and wherein the gas hourly space velocity of the feed over the catalyst ranges from about 1,000 hr−1 to about 2,000,000 hr−1. In the process, the catalyst is maintained at a temperature of from about 500° C. to about 1,500° C. as the feed makes contact with the catalyst.

    摘要翻译： 公开了一种用于从烃生产氢气或合成气气体的催化部分氧化工艺中使用的高效催化剂。 该催化剂包含铼与选自铂，铱，钌，铑和钯的第二金属组合，原子比为铼与第二金属的比例为25:1至1:1。 该方法包括在催化剂存在下使包含烃的进料与氧源的C / O比为约0.9至约1.1的反应，并且其中进料在催化剂上的气时空速约为1000小时， SUP> -1至约2,000,000小时-1。 在该过程中，当进料与催化剂接触时，催化剂保持在约500℃至约1500℃的温度。

    High surface area, small crystallite size catalyst for fischer-tropsch synthesis
    5.
    发明申请
    High surface area, small crystallite size catalyst for fischer-tropsch synthesis 有权
    高表面积，微晶尺寸催化剂用于费托合成

    公开(公告)号：US20070099797A1

    公开(公告)日：2007-05-03

    申请号：US09851177

    申请日：2001-05-08

    申请人： X.D. Hu ,  Patrick Loi ,  Robert O'Brien

    发明人： X.D. Hu ,  Patrick Loi ,  Robert O'Brien

    IPC分类号： B01J23/56

    CPC分类号： C10G2/332 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8913 ,  B01J23/8986 ,  B01J35/006 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/0221 ,  C10G2/333

    摘要： The Fischer-Tropsch catalyst of the present invention is a transition metal-based catalyst having a high surface area, a smooth, homogeneous surface morphology, an essentially uniform distribution of cobalt throughout the support, and a small metal crystallite size. In a first embodiment, the catalyst has a surface area of from about 100 m2/g to about 250 m2/g; an essentially smooth, homogeneous surface morphology; an essentially uniform distribution of metal throughout an essentially inert support; and a metal oxide crystallite size of from about 40 Å to about 200 Å. In a second embodiment, the Fischer-Tropsch catalyst is a cobalt-based catalyst with a first precious metal promoter and a second metal promoter on an aluminum oxide support, the catalyst having from about 5 wt % to about 60 wt % cobalt; from about 0.0001 wt % to about 1 wt % of the first promoter, and from about 0.01 wt % to about 5 wt % of the second promoter. The high surface area transition metal-based catalysts of the present invention are prepared in a non-acidic solution at a pH greater than about 7.0, and starting with a non-acidic transition metal complex. The resulting product is a catalyst with a uniform distribution of metal throughout the catalyst particles, with a smooth and homogeneous surface morphology, and with slow crystallite growth upon heating.

    摘要翻译： 本发明的费 - 托催化剂是具有高表面积，平滑，均匀的表面形态，钴在整个载体上基本均匀分布的过渡金属基催化剂和小的金属微晶尺寸。 在第一实施方案中，催化剂的表面积为约100m 2 / g至约250m 2 / g; 基本上光滑，均匀的表面形态; 在整个基本上惰性的载体中金属的基本均匀分布; 和金属氧化物微晶尺寸为约至约200埃。 在第二个实施方案中，费 - 托催化剂是在氧化铝载体上具有第一贵金属促进剂和第二金属助催化剂的钴基催化剂，所述催化剂具有约5重量％至约60重量％的钴; 约0.0001重量％至约1重量％的第一助催化剂和约0.01重量％至约5重量％的第二助催化剂。 本发明的高表面积过渡金属基催化剂在pH大于约7.0的非酸性溶液中制备，并从非酸性过渡金属络合物开始。 所得产物是具有均匀的金属分布在整个催化剂颗粒中的催化剂，具有光滑和均匀的表面形态，并且在加热时具有缓慢的微晶生长。