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187 条记录 (耗时 0.048 秒)

    METHODS OF PREPARING FLUORINATED CARBOXYLIC ACIDS AND THEIR SALTS
    22.
    发明申请
    METHODS OF PREPARING FLUORINATED CARBOXYLIC ACIDS AND THEIR SALTS 有权
    制备氟化羧酸及其盐的方法

    公开(公告)号：US20120184770A1

    公开(公告)日：2012-07-19

    申请号：US13497173

    申请日：2010-10-21

    申请人： Klaus Hintzer ,  Dennis E. Vogel ,  Miguel A. Guerra ,  Jolanta Ignatowska ,  Gerd-Volker Röschenthaler ,  Oleg Shyshkov ,  Kim M Vogel ,  Tilman C. Zipplies

    发明人： Klaus Hintzer ,  Dennis E. Vogel ,  Miguel A. Guerra ,  Jolanta Ignatowska ,  Gerd-Volker Röschenthaler ,  Oleg Shyshkov ,  Kim M Vogel ,  Tilman C. Zipplies

    IPC分类号： C07C51/16 ,  C07C51/285 ,  C07C51/305 ,  C07C51/23 ,  C25B3/02 ,  C07C51/27 ,  C07C51/29

    CPC分类号： C07C51/27 ,  C07C53/21 ,  C07C59/135

    摘要： A method for preparing fluorinated carboxylic acids and theirs salts is described comprising subjecting a fluorinated alcohol of the general formula (A): A-CH2—OH to at least one first and at least one second oxidizing agent to produce a highly fluorinated carboxylic acid or their salts of the general formula (B): A-COO M+, wherein M+ represents a cation and wherein A in formulas (A) and (B) is the same and A represents the residue: Rf-[0]p-CX″Y″-[0]m-CX′Y′-[0]n-CXY— wherein Rf represents a fluorinated alkyl residue which may or may not contain one or more catenary oxygen atoms, p, m and n are independently from each other either 1 or O, X, X′, X″, Y, Y′ and Y″ are independently from each other H, F, CF3, or C2F5 with the proviso that not all of X, X′, X″, Y, Y′ and Y″ are H; or A represents the residue: R—CFX— wherein X and R are independently selected from a hydrogen, a halogen, or an alkyl, alkenyl, cycloalkyl, or aryl residue, which may or may not contain one or more fluorine atoms and which may or may not contain one or more catenary oxygen atoms; wherein said at least one first oxidizing agent is a compound that can be converted, by action of the second oxidizing agent, into a reactive species capable of oxidizing the fluorinated alcohol.

    摘要翻译： 描述了制备氟化羧酸及其盐的方法，其包括将通式（A）的氟化醇：A-CH 2 -OH置于至少一种第一和至少一种第二氧化剂中以产生高度氟化的羧酸或 其通式（B）的盐：A-COO M +，其中M +表示阳离子，式（A）和（B）中的A相同，A表示残基：Rf- [0] p-CX“ Y“ - [0] m-CX'Y' - [0] n-CXY-其中Rf表示可以或可以不含有一个或多个链状氧原子的氟化烷基残基，p，m和n彼此独立地 1或O，X，X'，X“，Y，Y'和Y”彼此独立地为H，F，CF 3或C 2 F 5，条件是不是全部X，X'，X“，Y， Y'和Y“为H; 或A表示残基：R-CFX-，其中X和R独立地选自氢，卤素或烷基，烯基，环烷基或芳基残基，其可以含有或不含有一个或多个氟原子， 或者可以不包含一个或多个链状氧原子; 其中所述至少一种第一氧化剂是可以通过第二氧化剂的作用转化成能够氧化氟化醇的反应性物质的化合物。

    Curable fluoropolymers containing bromine groups having improved compression set
    25.
    发明授权
    Curable fluoropolymers containing bromine groups having improved compression set 失效
    含有改进的压缩永久变形的含溴基团的可固化含氟聚合物

    公开(公告)号：US06803435B2

    公开(公告)日：2004-10-12

    申请号：US10198426

    申请日：2002-07-18

    申请人： William D. Coggio ,  Peter J. Scott ,  Klaus Hintzer ,  Erik D. Hare

    发明人： William D. Coggio ,  Peter J. Scott ,  Klaus Hintzer ,  Erik D. Hare

    IPC分类号： C08F430

    CPC分类号： C08F214/16 ,  C08F214/265

    摘要： The present invention provides a curable composition comprising a fluoropolymer comprising interpolymerized units derived from (i) CF2═CF—Rf, wherein Rf is fluorine or a C1-C8 perfluoroalkyl, (ii) at toast about 10 mole percent of a hydrogen-containing C2-C9 olefin, based on the total moles of said CF2═CFRf and said olefin, (iii) an average of two or more bromine atoms including one or more terminal bromine atom(s) per fluoropolymer chain, (iv) optionally CX2═CX—R, wherein each X is independently H, F, or Cl and R is a halogen or a C1-C8 alkyl or alkenyl group that may include one or more ether linkage(s), (v) optionally a bromine-containing cure site monomer; (b) optionally, a peroxide curing agent; and (c) optionally, a crosslinking co-agent. The invention also provides methods of making and using such fluoropolymer compositions.

    摘要翻译： 本发明提供一种可固化组合物，其包含含氟聚合物，其包含衍生自（i）CF 2 = CF-R f的共聚单元，其中R f为氟或C 1 -C 8全氟烷基，（ii）在约10摩尔％的含氢C2 -C9烯烃，基于所述CF 2 = CFR f和所述烯烃的总摩尔数，（iii）平均每个含氟聚合物链包括一个或多个末端溴原子的两个或更多个溴原子，（iv）任选地CX2 = CX -R，其中每个X独立地是H，F或Cl，R是可以包括一个或多个醚键的卤素或C 1 -C 8烷基或烯基，（v）任选的含溴固化位点 单体; （b）任选地，过氧化物固化剂; 和（c）任选的交联助剂。 本发明还提供了制备和使用这种含氟聚合物组合物的方法。

    Recovery of fluorinated surfactants from a basic anion exchange resin having quaternary ammonium groups
    28.
    发明授权
    Recovery of fluorinated surfactants from a basic anion exchange resin having quaternary ammonium groups 有权
    从具有季铵基团的碱性阴离子交换树脂中回收氟化表面活性剂

    公开(公告)号：US07807726B2

    公开(公告)日：2010-10-05

    申请号：US11373430

    申请日：2006-03-10

    申请人： Andreas Maurer ,  Klaus Hintzer ,  Werner Schwertfeger ,  Egon Obermaier ,  Astrid Weber

    发明人： Andreas Maurer ,  Klaus Hintzer ,  Werner Schwertfeger ,  Egon Obermaier ,  Astrid Weber

    IPC分类号： C08J5/20

    CPC分类号： C08F6/16 ,  B01J41/05 ,  B01J49/57 ,  C02F2001/422 ,  C02F2101/14 ,  C02F2101/301 ,  C02F2103/38 ,  C08L27/12

    摘要： The invention provides a method for recovery of a fluorinated anionic surfactant from a basic anion exchange resin having quaternary ammonium groups, the method comprising eluting the anion exchange resin with a composition comprising an ammonium salt and a water miscible organic solvent. The method according to the invention may provide one or more of the following advantages. For example, the method can be designed to allow for recovery of substantially all of the fluorinated surfactant from a basic anion exchange resin having quaternary ammonium groups. Also, the liquid used for recovering the surfactant from the anion exchange resin is a simple liquid that can be readily and cost effectively manufactured. Further the process may be carried out in a convenient and easy manner. Furthermore, the method generally does not require large amounts of the eluting composition.

    摘要翻译： 本发明提供了从具有季铵基团的碱性阴离子交换树脂中回收氟化阴离子表面活性剂的方法，该方法包括用包含铵盐和水混溶性有机溶剂的组合物洗脱阴离子交换树脂。 根据本发明的方法可以提供一个或多个以下优点。 例如，该方法可被设计成允许从具有季铵基团的碱性阴离子交换树脂中恢复基本上所有的氟化表面活性剂。 此外，用于从阴离子交换树脂中回收表面活性剂的液体是可以容易且成本有效地制造的简单液体。 此外，该方法可以以方便和容易的方式进行。 此外，该方法通常不需要大量的洗脱组合物。

    Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
    29.
    发明授权
    Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant 有权
    使用氟化表面活性剂的氟化单体的水乳液聚合

    公开(公告)号：US07776946B2

    公开(公告)日：2010-08-17

    申请号：US11457502

    申请日：2006-07-14

    申请人： Klaus Hintzer ,  Harald Kaspar ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies

    发明人： Klaus Hintzer ,  Harald Kaspar ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies

    IPC分类号： C08K5/09

    CPC分类号： C08F14/18 ,  C08F2/22

    摘要： The present invention provides an aqueous emulsion polymerization of fluorinated monomers including gaseous fluorinated monomers using a perfluoro ether surfactant as an emulsifier. The perfluoro ether surfactants correspond to formula (I) Rf—O—CF2CF2—X  (I) wherein Rf represents a linear or branched perfluoroalkyl group having 1, 2, 3 or 4 carbon atoms and X represents a carboxylic acid group or salt thereof. In a further aspect, the invention also provides an aqueous fluoropolymer dispersion comprising the perfluoro ether surfactant and the use of such dispersion in the coating or impregnation of substrates.

    摘要翻译： 本发明提供使用全氟醚表面活性剂作为乳化剂的氟化单体的水乳液聚合，包括气态氟化单体。 全氟醚表面活性剂对应于式（I）Rf-O-CF 2 CF 2 -X（I），其中R f表示具有1,2,3或4个碳原子的直链或支链全氟烷基，X表示羧酸基团或其盐。 另一方面，本发明还提供一种包含全氟醚表面活性剂的含氟聚合物水分散体和在底物的涂布或浸渍中使用这种分散体。

    EXPLOSION TAMING SURFACTANTS FOR THE PRODUCTION OF PERFLUOROPOLYMERS
    30.
    发明申请
    EXPLOSION TAMING SURFACTANTS FOR THE PRODUCTION OF PERFLUOROPOLYMERS 有权
    用于生产全氟聚合物的爆炸性表面活性剂

    公开(公告)号：US20080015319A1

    公开(公告)日：2008-01-17

    申请号：US11457236

    申请日：2006-07-13

    申请人： Klaus Hintzer ,  Michael Jurgens ,  Harald Kaspar ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman C. Zipplies

    发明人： Klaus Hintzer ,  Michael Jurgens ,  Harald Kaspar ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman C. Zipplies

    IPC分类号： C08F16/24

    CPC分类号： C08F14/26 ,  C08F2/22

    摘要： A process comprising polymerizing tetrafluoroethylene in an aqueous emulsion in the presence of a non-telogenic surfactant having an anionic portion with the general formula (I): Rf—O-L-CO2—   (I) wherein Rf is selected from a partially fluorinated alkyl group, a perfluorinated alkyl group, a partially fluorinated alkyl group interrupted by one or more oxygen atoms, and a perfluorinated alkyl group interrupted by one or more oxygen atoms, wherein Rf has from 1 to 10 carbon atoms; and L is an alkylene group having the general formula (CX2)n wherein each X is independently selected from Rf, fluorine, and hydrogen and n is selected from 1 to 5, with the proviso that the surfactant contains at least one unit selected from a —CH2— unit and a —CHF— unit. Also provided are aqueous dispersions comprising these surfactants and methods of coating substrates with the aqueous dispersions.

    摘要翻译： 在具有通式（I）的阴离子部分的非脱落剂表面活性剂的存在下，在水乳液中聚合四氟乙烯的方法：<？在线式描述=“在线式”末端=“铅” （I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中 R f选自部分氟化的烷基，全氟化烷基，被一个或多个氧原子间隔的部分氟化烷基和被一个或多个氧原子间隔的全氟烷基，其中 R 1具有1至10个碳原子; 并且L是具有通式（CX 2）n N的亚烷基，其中每个X独立地选自R 1，R 2，R 3， 并且n选自1至5，条件是表面活性剂含有至少一个选自-CH 2 - 单元和-CHF-单元的单元。 还提供了包含这些表面活性剂的水分散体和用水分散体涂覆底物的方法。