公开(公告)号：US09995861B2

公开(公告)日：2018-06-12

申请号：US13878625

申请日：2011-10-14

Applicant: William D. Coggio ,  William B. Black ,  Michael F. Weber ,  Huiwen Tai

Inventor： William D. Coggio ,  William B. Black ,  Michael F. Weber ,  Huiwen Tai

IPC: G02B5/02 ,  G02B5/08 ,  G02B5/28

CPC classification number: G02B5/285 ,  G02B5/0242 ,  G02B5/0247 ,  G02B5/0841

Abstract: Low loss, high reflectivity wide band mirror films provide a desired mix of specular reflection and diffuse reflection or scattering to provide semi-specular reflectivity. The mirror films generally include both a specularly reflective multilayer optical film (MOF) having a wide reflection band, and a scattering layer. In some cases a low refractive index TIR layer is sandwiched between the MOF and the scattering layer. In other cases the scattering layer contacts the MOF directly. In embodiments that include the TIR layer, the TIR layer preferably has a nanovoided morphology and includes a plurality of particles and a polymer binder. In embodiments wherein the scattering layer contacts the MOF directly, the scattering layer preferably also has a nanovoided morphology and includes a plurality of particles and a polymer binder.

公开(公告)号：US20130114142A1

公开(公告)日：2013-05-09

申请号：US13641363

申请日：2010-04-15

Applicant: Michael Benton Free ,  Mieczyslaw H. Mazurek ,  Bimal V. Thakkar ,  Kenneth L. Smith ,  Suman K. Patel ,  William D. Coggio ,  Mikhail L. Pekurovsky ,  Raymond C. Chiu

Inventor： Michael Benton Free ,  Mieczyslaw H. Mazurek ,  Bimal V. Thakkar ,  Kenneth L. Smith ,  Suman K. Patel ,  William D. Coggio ,  Mikhail L. Pekurovsky ,  Raymond C. Chiu

IPC: G02B5/124 ,  G02B5/12

CPC classification number: G02B5/124 ,  B32B3/263 ,  B32B3/30 ,  B32B7/12 ,  B32B27/08 ,  B32B27/16 ,  B32B27/304 ,  B32B27/306 ,  B32B27/308 ,  B32B27/32 ,  B32B27/322 ,  B32B27/36 ,  B32B27/40 ,  B32B2250/44 ,  B32B2255/10 ,  B32B2255/12 ,  B32B2255/26 ,  B32B2270/00 ,  B32B2307/418 ,  B32B2307/732 ,  B32B2307/75 ,  G02B5/12 ,  Y10T156/10

Abstract: This disclosure generally relates to retroreflective articles and methods of making such articles.

Abstract translation: 本公开一般涉及回射制品和制造这种制品的方法。

公开(公告)号：US08147966B2

公开(公告)日：2012-04-03

申请号：US12718481

申请日：2010-03-05

Applicant: Thomas P. Klun ,  Naiyong Jing ,  Richard J. Pokorny ,  Zai-Ming Qiu ,  Mark J. Pellerite ,  William D. Coggio ,  Christopher B. Walker, Jr.

Inventor： Thomas P. Klun ,  Naiyong Jing ,  Richard J. Pokorny ,  Zai-Ming Qiu ,  Mark J. Pellerite ,  William D. Coggio ,  Christopher B. Walker, Jr.

IPC: B32B27/40

CPC classification number: C07C235/08 ,  C08G18/3802 ,  C08G18/3825 ,  C08G18/672 ,  C08G18/673 ,  C08G18/792 ,  C08G18/8175 ,  C09D175/16 ,  G02B1/105 ,  G02B1/14 ,  Y10T428/265 ,  Y10T428/3154 ,  Y10T428/31551 ,  C08G18/50

Abstract: Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.

Abstract translation: 含氟碳酸酯和氨基甲酸酯（甲基）丙烯酸的添加剂和硬涂层。 硬涂层作为光学装置上的表面层是特别有用的。

公开(公告)号：US20120038984A1

公开(公告)日：2012-02-16

申请号：US13264436

申请日：2010-04-15

Applicant: Suman K. Patel ,  William D. Coggio ,  Mikhail L. Pekurovsky ,  Kenneth L. Smith ,  Michael Benton Free ,  William B. Kolb

Inventor： Suman K. Patel ,  William D. Coggio ,  Mikhail L. Pekurovsky ,  Kenneth L. Smith ,  Michael Benton Free ,  William B. Kolb

IPC: G02B5/124 ,  G02B5/122

CPC classification number: G02B5/124 ,  B32B3/00

Abstract: Retroreflective articles and constructions are disclosed. One exemplary retroreflective article or construction includes a retroreflective layer and a low refractive index layer. In one exemplary embodiment, the low refractive index layer is adjacent to at least a portion of a retroreflective structured major surface of the retroreflective layer.

Abstract translation: 公开了逆反射制品和结构。 一种示例性的逆反射制品或结构包括回射层和低折射率层。 在一个示例性实施例中，低折射率层与回射层的逆反射结构化主表面的至少一部分相邻。

公开(公告)号：US20100160595A1

公开(公告)日：2010-06-24

申请号：US12718481

申请日：2010-03-05

Applicant: Thomas P. Klun ,  Naiyong Jing ,  Richard J. Pokorny ,  Zai-Ming Qiu ,  Mark J. Pellerite ,  William D. Coggio ,  Christopher B. Walker, JR.

Inventor： Thomas P. Klun ,  Naiyong Jing ,  Richard J. Pokorny ,  Zai-Ming Qiu ,  Mark J. Pellerite ,  William D. Coggio ,  Christopher B. Walker, JR.

IPC: C08G69/44 ,  C08G18/70

CPC classification number: C07C235/08 ,  C08G18/3802 ,  C08G18/3825 ,  C08G18/672 ,  C08G18/673 ,  C08G18/792 ,  C08G18/8175 ,  C09D175/16 ,  G02B1/105 ,  G02B1/14 ,  Y10T428/265 ,  Y10T428/3154 ,  Y10T428/31551 ,  C08G18/50

Abstract: Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.

Abstract translation: 含氟碳酸酯和氨基甲酸酯（甲基）丙烯酸的添加剂和硬涂层。 硬涂层作为光学装置上的表面层是特别有用的。

公开(公告)号：US07473462B2

公开(公告)日：2009-01-06

申请号：US11972034

申请日：2008-01-10

Applicant: William D. Coggio ,  Thomas P. Klun ,  George G. I. Moore ,  Naiyong Jing ,  Chuntao Cao ,  Sharon Wang ,  Patricia M. Savu ,  Lan H. Liu ,  Joan M. Noyola

Inventor： William D. Coggio ,  Thomas P. Klun ,  George G. I. Moore ,  Naiyong Jing ,  Chuntao Cao ,  Sharon Wang ,  Patricia M. Savu ,  Lan H. Liu ,  Joan M. Noyola

IPC: B32B27/20 ,  B32B27/26 ,  B32B27/28 ,  B32B27/30 ,  B32B33/00

CPC classification number: C08F14/18 ,  C08F259/08 ,  C08F283/00 ,  C08L51/003 ,  C09D151/003 ,  G02B1/111 ,  Y10T428/24942 ,  Y10T428/259 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31935 ,  C08F2/00 ,  C08L2666/02

Abstract: A low refractive index composition that forms a low refractive index layer on an optical display is formed having a co-crosslinked interpenetrating polymer network of a fluoropolymer phase and an acrylate phase. The fluoropolymer phase is preferably formed from fluoropolymers based on THV or FKM and having either a degree of unsaturation and/or containing a reactive cure site monomer in its polymer backbone. The acrylate phase includes a multifunctional acrylate crosslinker, and more preferably includes a perfluoropolyether acrylate crosslinker. The formed low refractive index layer has improved interfacial adhesion to other layers or substrates contained in the optical display. Further, the mechanical strength and scratch resistance of the either of above low refractive index compositions can be further enhanced through the incorporation of surface functionalized inorganic particle into the formed layer.

Abstract translation: 形成在光学显示器上形成低折射率层的低折射率组合物，其具有含氟聚合物相和丙烯酸酯相的共交联互穿聚合物网络。 含氟聚合物相优选由基于THV或FKM的含氟聚合物形成，并且在其聚合物主链中具有不饱和度和/或含有反应性固化位点单体。 丙烯酸酯相包括多官能丙烯酸酯交联剂，更优选包括全氟聚醚丙烯酸酯交联剂。 所形成的低折射率层具有改善的与光学显示器中包含的其它层或基底的界面粘合性。 此外，通过将表面官能化的无机颗粒并入成形层，可以进一步提高上述低折射率组合物中的任一种的机械强度和耐划伤性。

公开(公告)号：US07323514B2

公开(公告)日：2008-01-29

申请号：US11026640

申请日：2004-12-30

Applicant: Naiyong Jing ,  Chuntao Cao ,  Tatsuo Fukushi ,  Timothy J. Tatge ,  William D. Coggio ,  Christopher B. Walker, Jr. ,  Thomas P. Klun ,  William J. Schultz ,  Zai-Ming Qiu

Inventor： Naiyong Jing ,  Chuntao Cao ,  Tatsuo Fukushi ,  Timothy J. Tatge ,  William D. Coggio ,  Christopher B. Walker, Jr. ,  Thomas P. Klun ,  William J. Schultz ,  Zai-Ming Qiu

IPC: C08F259/00

CPC classification number: G02B1/111 ,  Y10T428/24942 ,  Y10T428/3154 ,  Y10T428/31663

Abstract: An economic, optically transmissive, stain and ink repellent, durable low refractive index fluoropolymer composition for use in an antireflection film or coupled to an optical display. In one aspect of the invention, the composition is formed from the reaction product of a fluoropolymer or reactive fluoropolymer, an amino silane ester coupling agent or ester equivalent, a multi-olefinic crosslinker, and optional surface modified inorganic particles or sol gel precursors.

Abstract translation: 用于抗反射膜或耦合到光学显示器的经济，光学透射，防污和防油墨，耐用的低折射率含氟聚合物组合物。 在本发明的一个方面，组合物由含氟聚合物或反应性含氟聚合物，氨基硅烷酯偶联剂或酯当量的反应产物，多烯属交联剂和任选的表面改性的无机颗粒或溶胶凝胶前体形成。

公开(公告)号：US06613846B2

公开(公告)日：2003-09-02

申请号：US09997634

申请日：2001-11-29

Applicant: Klaus Hintzer ,  Robert E. Kolb ,  Peter J. Scott ,  Erik D. Hare ,  William D. Coggio

Inventor： Klaus Hintzer ,  Robert E. Kolb ,  Peter J. Scott ,  Erik D. Hare ,  William D. Coggio

IPC: C08L2722

CPC classification number: C08K5/56 ,  B32B25/08 ,  C08K5/14 ,  C08K5/541 ,  C08K5/5415 ,  C08K5/544 ,  C08K5/57 ,  C08L27/12 ,  C08L83/04 ,  C08L83/06 ,  C08L2666/14

Abstract: The present invention provides a curable fluoroelastomer composition comprising: (a) a fluoroelastomer comprising a cure site component having a halogen capable of participation in a peroxide cure reaction; (b) an organic peroxide; and (c) a siloxane or silazane comprising one or more —SiH groups. The curable fluoroelastomer compositions generally show improved processing and the resulting cured fluoroelastomers generally have improved mechanical and physical properties.

Abstract translation: 本发明提供一种可固化的含氟弹性体组合物，其包含：（a）含氟弹性体，其包含具有能够参与过氧化物固化反应的卤素的固化部位组分;（b）有机过氧化物; 和（c）包含一个或多个-SiH基团的硅氧烷或硅氮烷。可固化的含氟弹性体组合物通常显示改进的加工，所得固化的含氟弹性体通常具有改善的机械和物理性能。

公开(公告)号：US5591804A

公开(公告)日：1997-01-07

申请号：US576097

申请日：1995-12-21

Applicant: William D. Coggio ,  Dirk H. C. Arren ,  Douglas S. Parker ,  Allan T. Worm

Inventor： William D. Coggio ,  Dirk H. C. Arren ,  Douglas S. Parker ,  Allan T. Worm

IPC: C08K5/17 ,  C08F8/00 ,  C08K5/36 ,  C08K5/50 ,  C08L27/16 ,  C08F8/30

CPC classification number: C08F8/00 ,  C08F2800/20

Abstract: A compound having the formula: ##STR1## where Q is an onium ion; A.sup.- is a counterion; R.sup.1, R.sup.2, R.sup.3, and R.sup.4, independently, comprise (a) a non-fluorinated alkyl, cycloalkyl, aryl, or aralkyl group; (b) an onium-containing group; or (c) a group having the formula --(CH.sub.2).sub.n --Y--R.sup.5 in which n is at least two; Y is a spacer arm comprising a --CH.sub.2 --, --O--, --OCH.sub.2 --, --S--, --SO.sub.2 --, or --Z--SO.sub.2-- group; Z is an --R.sup.6 --O--, --N(R.sup.7)--, or --N(H)-- group; R.sup.6 is a substituted or unsubstituted phenylene group; R.sup.7 is a non-fluorinated alkyl, cycloalkyl, aryl, or alkaryl group; and R.sup.5 is a fluorinated group, perfluorinated group, or combination thereof, with the proviso that (i) at least one of R.sup.1, R.sup.2, R.sup.3, and R.sup.4 comprises a group having the formula --(CH.sub.2).sub.n --Y--R.sup.5 ; (ii) the total number of fluorine atoms in said compound is at least 5; and (iii) when Q is a sulfonium ion, there is no R.sup.4 group. The invention further includes curable compositions comprising vinylidene fluoride-containing polymers and the above-described compounds, as well as a method for curing such compositions.

Abstract translation: 具有下式的化合物：其中Q是鎓离子; A-是抗衡离子 R 1，R 2，R 3和R 4独立地包含（a）非氟化烷基，环烷基，芳基或芳烷基; （b）含鎓基团; 或（c）具有式 - （CH 2）n -Y-R 5的基团，其中n至少为2; Y是包含-CH 2 - ， - O - ， - OCH 2 - ， - S - ， - SO 2 - 或-Z-SO 2 - 基团的间隔臂; Z是-R 6 -O-，-N（R 7） - 或-N（H） - 基; R6是取代或未取代的亚苯基; R7是非氟化的烷基，环烷基，芳基或烷芳基; 并且R 5是氟化基团，全氟化基团或其组合，条件是（i）R 1，R 2，R 3和R 4中的至少一个包含具有式 - （CH 2）n -Y-R 5的基团; （ii）所述化合物中的氟原子总数至少为5; 和（iii）当Q是锍离子时，不存在R 4基团。 本发明还包括包含偏二氟乙烯的聚合物和上述化合物的可固化组合物，以及用于固化该组合物的方法。

公开(公告)号：US09588262B2

公开(公告)日：2017-03-07

申请号：US13879839

申请日：2011-10-14

Applicant: William D. Coggio ,  Michael L. Steiner ,  William F. Edmonds ,  Robert F. Kamrath ,  Lan H. Liu ,  Encai Hao

Inventor： William D. Coggio ,  Michael L. Steiner ,  William F. Edmonds ,  Robert F. Kamrath ,  Lan H. Liu ,  Encai Hao

IPC: G02B5/02

CPC classification number: G02B5/02 ,  G02B5/0242 ,  G02B5/0247 ,  G02B2207/107

Abstract: An optical article includes an optical element and a low refractive index layer disposed on the optical element. The low refractive index layer having an effective refractive index of 1.3 or less and including a binder, a plurality of metal oxide particles dispersed in the binder and a plurality of interconnected voids. The low refractive index layer has a haze value of at least 30%.

Abstract translation: 光学制品包括设置在光学元件上的光学元件和低折射率层。 低折射率层具有1.3以下的有效折射率，并且包括粘合剂，分散在粘合剂中的多个金属氧化物颗粒和多个互连的空隙。 低折射率层的雾度值至少为30％。