公开(公告)号：US20190388846A1

公开(公告)日：2019-12-26

申请号：US16557029

申请日：2019-08-30

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Osama SHEKHAH ,  Youssef BELMABKHOUT

IPC: B01D71/06 ,  B01D53/22 ,  C07F15/04 ,  B01D69/12 ,  B01D71/02

Abstract: Embodiments include a method of making a metal organic framework membrane comprising contacting a substrate with a solution including a metal ion and contacting the substrate with a solution including an organic ligand, sufficient to form one or more layers of a metal organic framework on a substrate. Embodiments further include a defect-free metal organic framework membrane comprising MSiF6(pyz)2, wherein M is a metal, wherein the thickness of the membrane is less than 1,000 μm, and wherein the metal organic framework has a growth orientation along the [110] plane relative to a substrate.

公开(公告)号：US20190282998A1

公开(公告)日：2019-09-19

申请号：US16434472

申请日：2019-06-07

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Karim ADIL ,  Youssef BELMABKHOUT ,  Osama SHEKHAH ,  Prashant M. BHATT ,  Amandine CADIAU

IPC: B01J20/22 ,  B01J20/28 ,  B01J20/30 ,  B01D53/02 ,  C07D241/10 ,  C07F19/00

Abstract: Embodiments of the present disclosure describe metal-organic framework compositions comprising a pillar characterized by the formula (MbF5(O/H2O)), where Mb is selected from periodic groups IIIA, IIIB, IVB, VB, VIB, and VIII; and a square grid characterized by the formula (Ma(ligand)x), where Ma is selected from periodic groups IB, IIA, IIB, IIIA, IVA, IVB, VIB, VIIB, and VIII, ligand is a polyfunctional organic ligand, and x is 1 or more; wherein the pillaring of the square grid with the pillars forms the metal-organic framework.

公开(公告)号：US20190046923A1

公开(公告)日：2019-02-14

申请号：US16159903

申请日：2018-10-15

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Bassem A. ALMAYTHALONY ,  Osama SHEKHAH ,  Youssef BELMABKHOUT

IPC: B01D53/22 ,  B01D53/28 ,  B01D69/02 ,  B01D69/10 ,  B01D67/00 ,  B01D71/02

Abstract: Metal organic framework membranes can be used in gas separation applications.

公开(公告)号：US20180230072A1

公开(公告)日：2018-08-16

申请号：US15952511

申请日：2018-04-13

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Youssef BELMABKHOUT ,  Mohamed Infas Haja MOHIDEEN ,  Karim ADIL ,  Prashant M. BHATT ,  Osama SHEKHAH ,  Valeriya CHERNIKOVA

IPC: C07C7/13 ,  B01J20/02 ,  B01J20/28

CPC classification number: C07C7/13 ,  B01J20/0207 ,  B01J20/226 ,  B01J20/28033 ,  B01J20/2808 ,  C07C9/15 ,  C07C9/18 ,  C07C9/21

Abstract: Embodiments of the present disclosure describe a zeolite-like metal-organic framework composition comprising a metal-organic framework composition with ana topology characterized by the formula [MIII(4, 5-imidazole dicarboxylic acid)2X(solvent)a]n wherein MIII comprises a trivalent cation of a rare earth element, X comprises an alkali metal element or alkaline earth metal element, and solvent comprises a guest molecule occupying pores. Embodiments of the present disclosure describe a method of separating paraffins comprising contacting a zeolite-like metal-organic framework with ana topology with a flow of paraffins, and separating the paraffins by size.

公开(公告)号：US20170137450A1

公开(公告)日：2017-05-18

申请号：US15319505

申请日：2015-06-17

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Osama SHEKHAH ,  Youssef BELMABKHOUT

IPC: C07F15/04 ,  B01J37/04 ,  C07F7/02 ,  B01J20/22 ,  B01J20/30 ,  B01J31/16 ,  B01J37/00

CPC classification number: C07F15/045 ,  B01J20/226 ,  B01J20/3078 ,  B01J20/3085 ,  B01J31/1691 ,  B01J37/009 ,  B01J37/04 ,  B01J2231/005 ,  B01J2531/16 ,  B01J2531/26 ,  B01J2531/847 ,  C07F7/025

Abstract: A green route for preparing a metal organic framework include mixing metal precursor with a ligand precursor to form a solvent-free mixture; adding droplets of water to the mixture; heating the mixture at a first temperature after adding the water; and isolating the metal organic framework material including the metal and the ligand.

公开(公告)号：US20160296883A1

公开(公告)日：2016-10-13

申请号：US15100513

申请日：2014-11-26

Applicant: KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY

Inventor： Mohamed EDDAOUDI ,  Bassem A. ALMAYTHALONY ,  Osama SHEKHAH ,  Youssef BELMABKHOUT

IPC: B01D53/22 ,  B01D71/02 ,  B01D69/10 ,  B01D67/00 ,  B01D69/02

CPC classification number: B01D53/228 ,  B01D53/28 ,  B01D67/0051 ,  B01D69/02 ,  B01D69/10 ,  B01D71/028 ,  B01D2257/504 ,  B01D2325/14 ,  Y02C10/10

Abstract: Metal organic framework membranes can be used in gas separation applications.

Abstract translation: 金属有机骨架膜可用于气体分离应用。