公开(公告)号：US20190331012A1

公开(公告)日：2019-10-31

申请号：US16507730

申请日：2019-07-10

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Youssef BELMABKHOUT ,  Osama SHEKHAH

IPC: F01N3/08 ,  B01J20/22 ,  F01N3/022 ,  B01D53/02

Abstract: In general, this disclosure describes method of capturing and storing CO2 on a vehicle. The method includes contacting an vehicle exhaust gas with one or more of a first metal organic framework (MOF) composition sufficient to separate CO2 from the exhaust gas, contacting the separated CO2 with one or more of a second MOF composition sufficient to store the CO2 and wherein the one or more first MOF composition comprises one or more SIFSIX-n-M MOF and wherein M is a metal and n is 2 or 3. Embodiments also describe an apparatus or system for capturing and storing CO2onboard a vehicle.

公开(公告)号：US20190322690A1

公开(公告)日：2019-10-24

申请号：US16458833

申请日：2019-07-01

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Osama SHEKHAH ,  Youssef BELMABKHOUT

IPC: C07F15/04 ,  C07F7/02 ,  B01J37/04 ,  B01J20/30 ,  B01J20/22 ,  B01J31/16 ,  B01J37/00

Abstract: A green route for preparing a metal organic framework include mixing metal precursor with a ligand precursor to form a solvent-free mixture; adding droplets of water to the mixture; heating the mixture at a first temperature after adding the water; and isolating the metal organic framework material including the metal and the ligand.

公开(公告)号：US20190255511A1

公开(公告)日：2019-08-22

申请号：US16402597

申请日：2019-05-03

Applicant: King Abdullah University of Science and Technology

Inventor： Dalal ALEZI ,  Youssef BELMABKHOUT ,  Mohamed EDDAOUDI

IPC: B01J20/22 ,  B01D53/047 ,  B01D53/02

Abstract: Embodiments of the present disclosure describe methods of removing one or more compounds from a fluid comprising contacting a metal-organic framework (MOF) composition having a square-octahedral topology with a fluid containing one or more of CH4 and O2, sorbing one or more of CH4 and O2 with the MOF composition, and storing one or more of the CH4 and O2 with the MOF composition.

公开(公告)号：US20190282949A1

公开(公告)日：2019-09-19

申请号：US16431860

申请日：2019-06-05

Applicant: King Abdullah University of Science and Technology ,  SAUDI ARABIAN OIL COMPANY

Inventor： Mohamed EDDAOUDI ,  Amandine CADIAU ,  Prashant M. BHATT ,  Karim ADIL ,  Youssef BELMABKHOUT

IPC: B01D53/02 ,  B01J20/28 ,  C07F15/04 ,  C07F15/02 ,  C07F9/00 ,  B01J20/34 ,  B01J20/22 ,  C07F5/06

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.

公开(公告)号：US20190270078A1

公开(公告)日：2019-09-05

申请号：US16412512

申请日：2019-05-15

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Karim ADIL ,  Youssef BELMABKHOUT ,  Amandine CADIAU

IPC: B01J31/16 ,  B01D53/02 ,  B01J20/22

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands. Methods for capturing chemical species from fluid compositions comprise contacting a metal organic framework characterized by the formula [MaMbF6-n(O/H2O)w(Ligand)x(solvent)y]z with a fluid composition and capturing one or more chemical species from the fluid composition.

公开(公告)号：US20180264434A1

公开(公告)日：2018-09-20

申请号：US15532839

申请日：2015-12-04

Applicant: King Abdullah University of Science and Technology

Inventor： Dalal ALEZI ,  Youssef BELMABKHOUT ,  Mohamed EDDAOUDI

IPC: B01J20/22 ,  B01D53/047

CPC classification number: B01J20/226 ,  B01D53/02 ,  B01D53/047 ,  B01D53/0476 ,  B01D2253/204 ,  B01D2257/104 ,  B01D2257/7025 ,  B01D2258/05 ,  B01D2259/4525 ,  F17C11/007 ,  Y02C20/20

Abstract: B&A: 4053.022PCT1 KAUST: 2014-099-02 26 ABSTRACT Embodiments provide a method of storing a compound using a metal organic framework (MOF). The method includes contacting one or more MOFs with a fluid and sorbing one or more compounds, such as O2 and CH4. O2 and CH4 can be sorbed simultaneously or in series. The metal organic framework can be an M-soc-MOF, wherein M can include aluminum, iron, gallium, indium, vanadium, chromium, titanium, or scandium.

公开(公告)号：US20180093218A1

公开(公告)日：2018-04-05

申请号：US15564935

申请日：2016-04-07

Applicant: King Abdullah University of Science and Technology ,  SAUDI ARABIAN OIL COMPANY

Inventor： Mohamed EDDAOUDI ,  Amandine CADIAU ,  Prashant M. BHATT ,  Karim ADIL ,  Youssef BELMABKHOUT

IPC: B01D53/02 ,  B01J20/22 ,  B01J20/34 ,  C07F9/00 ,  C07F5/06 ,  C07F15/02 ,  C07F15/04

CPC classification number: B01D53/02 ,  B01D2253/116 ,  B01D2253/204 ,  B01D2256/245 ,  B01D2257/304 ,  B01D2257/504 ,  B01D2257/80 ,  B01D2259/40007 ,  B01J20/226 ,  B01J20/28057 ,  B01J20/28069 ,  B01J20/3425 ,  B01J20/3483 ,  B01J20/3491 ,  C07F5/066 ,  C07F9/00 ,  C07F15/02 ,  C07F15/04 ,  Y02C10/08

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.

公开(公告)号：US20170246584A1

公开(公告)日：2017-08-31

申请号：US15507411

申请日：2015-09-02

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Youssef BELMABKHOUT ,  Osama SHEKHAH

IPC: B01D53/02 ,  B01J20/22 ,  A61M16/22 ,  H01M8/0668

CPC classification number: B01D53/02 ,  A61M16/22 ,  B01D2253/204 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2258/06 ,  B01D2259/4533 ,  B01J20/226 ,  B01J20/28057 ,  B01J20/28083 ,  B01J2220/62 ,  H01M8/0668 ,  Y02C10/08

Abstract: In general, this disclosure describes techniques for removing trace and low concentration CO2 from fluids using SIFSIX-n-M MOFs, wherein n is at least two and M is a metal. In some embodiments, the metal is zinc or copper. Embodiments include devices comprising SIFSIX-n-M MOFs for removing CO2 from fluids. In particular, embodiments relate to devices and methods utilizing SIFSIX-n-M MOFs for removing CO2 from fluids, wherein CO2 concentration is trace. Methods utilizing SIFSIX-n-M MOFs for removing CO2 from fluids can occur in confined spaces. SIFSIX-n-M MOFs can comprise bidentate organic ligands. In a specific embodiment, SIFSIX-n-M MOFs comprise pyrazine or dipryidilacetylene ligands.

公开(公告)号：US20210106973A1

公开(公告)日：2021-04-15

申请号：US17131385

申请日：2020-12-22

Applicant: King Abdullah University of Science and Technology

Inventor： Dalal ALEZI ,  Youssef BELMABKHOUT ,  Mohamed EDDAOUDI

IPC: B01J20/22 ,  B01D53/02 ,  B01D53/047

Abstract: Embodiments of the present disclosure describe methods of removing one or more compounds from a fluid comprising contacting a metal-organic framework (MOF) composition having a square-octahedral topology with a fluid containing one or more of CH4 and O2, sorbing one or more of CH4 and O2 with the MOF composition, and storing one or more of the CH4 and O2 with the MOF composition.

公开(公告)号：US20210069672A1

公开(公告)日：2021-03-11

申请号：US16642525

申请日：2018-09-19

Applicant: King Abdullah University of Science and Technology

Inventor： Sk Md Towsif ABTAB ,  Youssef BELMABKHOUT ,  Prashant BHATT ,  Mohamed EDDAOUDI

IPC: B01J20/22 ,  B01J20/34 ,  B01J20/30 ,  C07F15/02 ,  C07F11/00 ,  C07C63/331 ,  B01D53/02 ,  B01D53/26 ,  B01D53/28

Abstract: Embodiments of the present disclosure describe a metal-organic framework (MOF) composition comprising a plurality of metal clusters, wherein the metal is chromium; and one or more tetratopic ligands; wherein the metal clusters and ligands associate to form a MOF with soc topology. A method of making a MOF comprising contacting a template MOF of formula Fe-soc-MOF and a reactant including chromium in a presence of dimethylformamide sufficient to replace Fe with Cr and form an exchanged MOF of formula Cr-soc-MOF. A method of sorbing water vapor comprising exposing a Cr-soc-MOF to an environment; and sorbing water vapor using the Cr-soc-MOF.