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26 条记录 (耗时 0.029 秒)

    Polymerization catalysts for unsaturated monomers, novel transition metal compounds, polymerization processes using same, and copolymers
    21.
    发明授权
    Polymerization catalysts for unsaturated monomers, novel transition metal compounds, polymerization processes using same, and copolymers 有权
    不饱和单体的聚合催化剂，新型过渡金属化合物，使用它们的聚合方法和共聚物

    公开(公告)号：US06703459B1

    公开(公告)日：2004-03-09

    申请号：US09701631

    申请日：2000-12-01

    申请人： Tadahiro Sunaga ,  Hiroshi Kouno

    发明人： Tadahiro Sunaga ,  Hiroshi Kouno

    IPC分类号： C08F444

    CPC分类号： C08F4/52

    摘要： This invention relates to polymerization catalysts for unsaturated monomers which are represented by the following general formula [1]: MR1kR2mR3nQh  [1] wherein R1 is selected from ligands having at least one nitrogen, sulfur, phosphorus or oxygen atom; R2 is selected from ligands comprising cyclic hydrocarbons having &pgr;-electrons, and R1 and R2 may be crosslinked with each other; R3 is selected from ligands comprising a hydrogen atom, alkyl groups, aryl groups, silicon-containing alkyl groups and silicon-containing aryl groups; M is a metal selected from the metals of group III of the periodic table; Q is selected from halogen atoms and electron-donating ligands, where Q may be the same or different if h is more than one; k is an integer of 1 to 4; and m, n and h are each 0 or an integer of 1 to 4.

    摘要翻译： 本发明涉及由以下通式[1]表示的不饱和单体聚合催化剂：其中R 1选自具有至少一个氮，硫，磷或氧原子的配体; R 2选自包含具有π电子的环状烃的配体，并且R 1和R 2可以彼此交联; R 3选自包含氢原子，烷基，芳基，含硅烷基和含硅芳基的配体; M是选自周期表第III族金属的金属; Q选自卤素原子和给电子配体，其中如果h大于1，Q可以相同或不同; k为1〜4的整数， m，n和h各自为0或1〜4的整数。

    Preparation of hydrogenated product of cyclic olefin ring-opening metathesis polymer
    22.
    发明授权
    Preparation of hydrogenated product of cyclic olefin ring-opening metathesis polymer 失效
    环烯烃开环复分解聚合物氢化产物的制备

    公开(公告)号：US06197894B1

    公开(公告)日：2001-03-06

    申请号：US09084593

    申请日：1998-05-27

    申请人： Tadahiro Sunaga ,  Masumi Okita ,  Tadashi Asanuma

    发明人： Tadahiro Sunaga ,  Masumi Okita ,  Tadashi Asanuma

    IPC分类号： C08F804

    CPC分类号： C08G61/08

    摘要： An olefin ring-opening metathesis polymer is hydrogenated to obtain a hydrogenated product thereof in high yield. A specialized olefin ring-opening metathesis polymer is hydrogenated in the presence of hydrogen using a catalyst consisting of an amine compound and a metallic complex of an organic phosphorous compound represented by the general formula (1): MHkQmTpZq  (1) wherein k is an integer of 0 or 1, m is an integer of 1 to 3, p is an integer of 0 or 1, q is an integer of 2 to 4, M is ruthenium, rhodium, osmium, iridium, palladium, platinum or nickel atom, H is hydrogen atom, Q is a halogen atom, T is CO, NO, toluene, acetonitrile or tetrahydrofuran, Z is an organic phosphorous compound represented by the general formula (2): PR′1R′2R′3  (2) wherein P is phosphorous atom, R′1, R′2 and R′3 may be the same or different from each other and are individually selected from the group consisting of a linear, branched or cyclic alkyl group, a linear, branched or cyclic alkenyl group, a linear, branched or cyclic aryl group, a linear, branched or cyclic alkoxy group and a linear, branched or cyclic aryloxy group.

    摘要翻译： 将烯烃开环易位聚合物氢化得到其高产率的氢化产物。 使用由胺化合物和由通式（1）表示的有机磷化合物的金属络合物组成的催化剂在氢存在下氢化特定的烯烃开环易位聚合物：其中k为0或1的整数 m为1〜3的整数，p为0或1的整数，q为2〜4的整数，M为钌，铑，锇，铱，钯，铂或镍原子，H为氢原子， Q是卤原子，T是CO，NO，甲苯，乙腈或四氢呋喃，Z是由通式（2）表示的有机磷化合物：其中P是磷原子，R'1，R'2和R'3 可以相同或不同，并且分别选自直链，支链或环状烷基，直链，支链或环状烯基，直链，支链或环状芳基，直链，支链或环状 环状烷氧基和直链，支链或环状芳氧基。

    Metallocene compound, and process for preparing polyolefin by using it
    26.
    发明授权
    Metallocene compound, and process for preparing polyolefin by using it 有权
    茂金属化合物，以及使用它制备聚烯烃的方法

    公开(公告)号：US06342568B1

    公开(公告)日：2002-01-29

    申请号：US09300289

    申请日：1999-04-27

    申请人： Tadahiro Sunaga ,  Kenji Michiue ,  Masahiro Yamashita ,  Yukio Ishii

    发明人： Tadahiro Sunaga ,  Kenji Michiue ,  Masahiro Yamashita ,  Yukio Ishii

    IPC分类号： C08F444

    CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/16

    摘要： There are herein disclosed a novel metallocene compound represented by the formula [1] and a process for preparing a polyolefin comprising the step of polymerizing an olefin in a catalytic system including the metallocene compound. The metallocene compound of the present invention particularly permits the preparation of a polyolefin having a high stereoregularity and a low molecular weight, and it is industrially extremely valuable: wherein R1 and R2 are each selected from the group consisting of an alkyl group, an aryl group and a silicon-containing alkyl group; M is a metal selected from the group IV of the periodic table; Q is carbon or silicon; X is a halogen, an alkyl group or an anionic ligand, and they may be selected so as to be the same or a combination of different ones; i is an integer of 1 to 10; n is an integer of 1 to 4; m is an integer of 0 to 4; and h is an integer of 1 to 3.

    摘要翻译： 本文公开了由式[1]表示的新颖的茂金属化合物和制备聚烯烃的方法，包括在包括茂金属化合物的催化体系中使烯烃聚合的步骤。 本发明的茂金属化合物特别可以制备具有高立构规整性和低分子量的聚烯烃，在工业上是非常有价值的：其中R1和R2各自选自烷基，芳基 和含硅烷基; M是选自周期表第IV族的金属; Q是碳或硅; X是卤素，烷基或阴离子配体，它们可以选择为相同或不同的组合; 我是1到10的整数; n为1〜4的整数， m为0〜4的整数。 h为1〜3的整数。