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    PROPYLENE-BASED POLYMER COMPOSITION AND USES THEREOF
    3.
    发明申请
    PROPYLENE-BASED POLYMER COMPOSITION AND USES THEREOF 有权
    基于丙烯的聚合物组合物及其用途

    公开(公告)号：US20130137826A1

    公开(公告)日：2013-05-30

    申请号：US13536590

    申请日：2012-06-28

    申请人： Naomi URAKAWA ,  Makoto Nakano ,  Yasuhiro Kitahara ,  Ryosuke Aburaki ,  Akihiro Matsuda

    发明人： Naomi URAKAWA ,  Makoto Nakano ,  Yasuhiro Kitahara ,  Ryosuke Aburaki ,  Akihiro Matsuda

    IPC分类号： C08L23/10

    CPC分类号： C08L23/10 ,  B32B27/32 ,  B32B2270/00 ,  C08F4/65912 ,  C08F4/65927 ,  C08L23/0807 ,  C08L23/0815 ,  C08L23/0853 ,  C08L23/12 ,  C08L23/14 ,  C08L23/142 ,  C08L23/16 ,  C08L27/00 ,  C08L35/06 ,  C08L2205/02 ,  C08L2205/025 ,  C08F110/06 ,  C08F2500/16

    摘要： The propylene-based polymer composition includes a specific amount of a propylene-based polymer (A) having a syndiotactic pentad fraction (rrrr fraction) of 85% or more and containing 90 to 100 mol % of a structural unit derived from propylene; a specific amount of a propylene-based copolymer (B) containing 40 to 89 mol % of a structural unit derived from propylene and 11 to 60 mol % of a structural unit derived from an α-olefin and satisfying a specific equation of intrinsic viscosity [η] and MFR; and specific amount(s) of at least one polymer of an olefin-based thermoplastic elastomer (C), a styrene-based elastomer (D), a propylene/ethylene/α-olefin copolymer (E) and an isotactic propylene-based polymer (F), and optionally an ethylene/vinyl acetate copolymer (G) and/or an ethylene-based polymer (H).

    摘要翻译： 丙烯类聚合物组合物包含特定量的间同立构五单元组分（rrrr分数）为85％以上且含有90〜100摩尔％来自丙烯的结构单元的丙烯类聚合物（A） 特定量的丙烯系共聚物（B），含有40〜89摩尔％的来自丙烯的结构单元和11〜60摩尔％的来自α-烯烃的结构单元，并且满足特性粘度[ eta]和MFR; 和烯烃类热塑性弹性体（C），苯乙烯类弹性体（D），丙烯/乙烯/α-烯烃共聚物（E）和全同立构丙烯类聚合物的至少一种聚合物的特定量 （F）和任选的乙烯/乙酸乙烯酯共聚物（G）和/或乙烯类聚合物（H）。

    Methods of constructing polyolefins having reduced crystallinity using a diimine based catalyst
    4.
    发明授权
    Methods of constructing polyolefins having reduced crystallinity using a diimine based catalyst 有权
    使用二亚胺基催化剂构建结晶度降低的聚烯烃的方法

    公开(公告)号：US08415441B1

    公开(公告)日：2013-04-09

    申请号：US13644703

    申请日：2012-10-04

    申请人： The Florida State University Research Foundation, Inc.

    发明人： Rufina Alamo ,  Geoffrey Coates ,  Carolina Ruiz-Orta

    IPC分类号： C08F110/06 ,  C08F210/00

    CPC分类号： C08F8/00 ,  C08F110/06 ,  C08F4/7006 ,  C08F2500/15 ,  C08F2500/16

    摘要： The invention is a novel family of polyolefins characterized by chain-walking defects of the type that add extra backbone carbons per monomer. These polyolefins display a large decrease in crystallinity relative to polyolefins known in the art. Specifically, the reduction in crystallinity is much greater than for earlier polypropylenes with a matched content of stereo or 1-alkene type defects. The claimed polyolefins can be made by a diimine-based catalyst. The defects in the polyolefin backbone are generated by a chain walking mechanism in which three or more carbons per monomer are added to the polymer backbone instead of two, as in conventional polymerization or copolymerization methods of alpha olefins. The novel polyolefins can be used in applications such as plastic wrapping, thin films, co-extrusion layers or molded parts in the absence of polymer blending or copolymerization. The cost of materials production can be reduced.

    摘要翻译： 本发明是一种新型的聚烯烃系列，其特征在于每单体添加额外的骨架碳的类型的链步行缺陷。 这些聚烯烃相对于本领域已知的聚烯烃显示出大的结晶度降低。 具体来说，结晶度的降低远远大于具有匹配的立体或1-烯烃型缺陷的早先聚丙烯。 所要求保护的聚烯烃可以通过二亚胺基催化剂制备。 聚烯烃主链中的缺陷是通过链式步行机制产生的，其中每个单体的三个或更多个碳被加入聚合物主链而不是两个，如在常规的α-烯烃的聚合或共聚方法中。 在不存在聚合物共混或共聚的情况下，新型聚烯烃可用于塑料包装，薄膜，共挤出层或模制部件等应用中。 可以降低材料生产的成本。

    Polymerization Catalyst Compositions Containing Metallocene Complexes and Polymers Produced by Using the Same
    10.
    发明申请
    Polymerization Catalyst Compositions Containing Metallocene Complexes and Polymers Produced by Using the Same 有权
    含有茂金属络合物和使用其的聚合物的聚合催化剂组合物

    公开(公告)号：US20070232758A1

    公开(公告)日：2007-10-04

    申请号：US11631381

    申请日：2005-07-01

    申请人： Zhaomin Hou ,  Yunjie Luo ,  Xiaofang Li ,  Jens Baldamus

    发明人： Zhaomin Hou ,  Yunjie Luo ,  Xiaofang Li ,  Jens Baldamus

    IPC分类号： C08F4/72 ,  B01J31/22 ,  C08F4/00

    CPC分类号： C08F212/08 ,  C08F10/00 ,  C08F210/02 ,  C08F210/16 ,  C08F297/08 ,  Y10S526/943 ,  C08F4/545 ,  C08F2500/16 ,  C08F2500/03 ,  C08F232/08 ,  C08F210/14 ,  C08F236/08

    摘要： The present invention provides a novel catalyst composition comprising a metallocene complex, and a novel producing method for various polymer compounds. Preferably, the invention provides a novel polymer compound, and a producing method thereof. Specifically, the invention provides a polymerization catalyst composition, comprising: (1) a metallocene complex represented by the general formula (I), including: a central metal M which is a group III metal atom or a lanthanoid metal atom; a ligand Cp* bound to the central metal and including a substituted or unsubstituted cyclopentadienyl derivative; monoanionic ligands Q1 and Q2; and w neutral Lewis base L; and (2) an ionic compound composed of a non-ligand anion and a cation: where w represents an integer of 0 to 3.

    摘要翻译： 本发明提供了包含茂金属络合物的新型催化剂组合物和用于各种聚合物化合物的新型制备方法。 优选地，本发明提供了一种新的高分子化合物及其制备方法。 具体地说，本发明提供了一种聚合催化剂组合物，其包括：（1）由通式（I）表示的茂金属络合物，包括：作为III族金属原子或镧系金属原子的中心金属M; 配体Cp *与中心金属结合并包含取代或未取代的环戊二烯基衍生物; 单阴离子配位体Q 1和Q 2; 和中性路易斯碱L; 和（2）由非配体阴离子和阳离子组成的离子化合物：其中w表示0-3的整数。