公开(公告)号：US06881855B2

公开(公告)日：2005-04-19

申请号：US10255515

申请日：2002-09-26

申请人： Dieter Heldmann ,  Oliver Schaefer ,  Juergen Stohrer

发明人： Dieter Heldmann ,  Oliver Schaefer ,  Juergen Stohrer

IPC分类号： C07B51/00 ,  C07F7/08 ,  C07F7/12 ,  C07F7/18 ,  C07F7/10

CPC分类号： C07F7/12 ,  C07B51/00 ,  C07F7/0834 ,  C07F7/1804

摘要： Silanes of the formula Ra1R4-a-xSiLx  (I) where each R is identical or different and is a monovalent, optionally substituted hydrocarbon radical which is free of aliphatic carbon—carbon multiple bonds and has from 1 to 18 carbon atoms per radical, R1 is an optionally substituted 2-norbornyl radical, L is a leaving group, a is 1, 2 or 3 and x is 1 or 2, with the proviso that the sum of a+x≦4, are useful for protecting functional groups of organic compounds (2) which have at least one functional group having an active hydrogen atom, preferably as a hydroxyl group —OH, a thiol groups —SH, an amine group —NH— or —NH2, a carboxyl group —COOH, or an amide group —CONH— or —CONH2.

摘要翻译： 公式的硅烷<？in-line-formula description =“In-line Formulas”end =“lead”？> R＆lt; 1＆lt; 1＆gt; R 4-ax （I）<？in-line-formula description =“In-line formula”end =“tail”？>其中每个R相同或不同，为一价， 任选取代的烃基，其不含脂族碳 - 碳多重键，并且每个基团具有1至18个碳原子，R 1是任选取代的2-降冰片基，L是离去基团， 是1,2或3，x是1或2，条件是a + x <= 4的总和可用于保护具有至少一个具有活性氢的官能团的有机化合物（2）的官能团 原子，优选羟基-OH，硫醇基-SH，胺基-NH-或-NH 2，羧基-COOH或酰胺基-CONH-或-CONH 2 。