LITHIUM NICKEL-BASED COMPOSITE OXIDE AS A POSITIVE ELECTRODE ACTIVE MATERIAL FOR RECHARGEABLE SOLID-STATE BATTERIES

    公开(公告)号:US20250054967A1

    公开(公告)日:2025-02-13

    申请号:US18719283

    申请日:2022-12-16

    Applicant: Umicore

    Abstract: A positive electrode active material comprises Li, M′, and oxygen. M′ comprises Ni in a content x, Mn in a content y, Co in a content z, D in a content a, Zr in a content b, wherein 55.0 mol %≤x≤95.0 mol %, 0.0 mol %≤y≤40.0 mol %, 0.0 mol %≤z≤40.0 mol %, 0.0 mol %≤a≤2.0 mol %, and 0.01 mol %≤b≤5.0 mol %. D is at least one element other than Li, Ni, Mn, Co, and O. The positive electrode active material has a Zr content ZrX and a carbon content C. ZrX is expressed as a molar fraction compared to the sum of molar fractions of Co, Mn, Ni, and Zr. C is expressed in wt. % by total weight of the positive electrode active material. The ratio of ZrX to C is between 52−0.413·x and 42−0.413·x.

    A POLYMER ELECTROLYTE
    22.
    发明公开

    公开(公告)号:US20240063433A1

    公开(公告)日:2024-02-22

    申请号:US18268293

    申请日:2021-12-23

    Applicant: UMICORE

    CPC classification number: H01M10/0565 H01M10/0525 H01M2300/0082

    Abstract: A polymer electrolyte suitable for use in lithium-ion secondary batteries is obtained by reaction between: at least one polyether polymer [polymer (P)], said polymer (P) comprising: at least 70.0% by moles of oxyethylene units; from 0.0 to 10.0% by moles of oxypropylene units; and from 1.00 to 4.0% by moles of recurring units derived from at least one monomer and at least one polysiloxane compound. Said at least one polysiloxane compound is grafted to said at least one polymer (P) through reaction of at least a fraction of the —CH═CH2 moiety of monomer (M) with the H—Si moiety of the polysiloxane compound.

    METHOD FOR PREPARING A POSITIVE ELECTRODE ACTIVE MATERIAL FOR RECHARGEABLE BATTERIES

    公开(公告)号:US20240030425A1

    公开(公告)日:2024-01-25

    申请号:US18265587

    申请日:2021-12-17

    Applicant: UMICORE

    Abstract: Method for manufacturing positive electrode active material for batteries comprising Li, O and M, wherein M consists of: —Co between 5 and 35 mol %; —Mn less than 35 mol %; —A less than 10 mol %, A being an element from: B, Mg, Al, Nb, Ti, W, Y, Ca, S, P, Zr, Sn, Si and W, and—The balance Ni, Which comprises: Step 1: preparing a liquid slurry of a lithium mixed metal oxide powder, Step 2: mixing the powder before or after or during step 1 with a cation selected from: Ala3+, La3+, Co2+, Co3+, Mn2+, Mn3+, Mn4+, Mn6+, Zn2+, Cu+, Cu2+, B3+, Mg2+, and with an anion having a general formula A′yOz′−x′, wherein A′ is: B, Al, Sn, Si, P, W, wherein 0.5≤x≤4, 0.5≤y′≤2 and 1≤z′≤≤12; Step 3: drying said slurry; Step 4: heating the slurry resulting from steps 1 and 2 or the dried slurry from step 3.

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