公开(公告)号：US08497392B2

公开(公告)日：2013-07-30

申请号：US13255347

申请日：2010-03-11

申请人： Yutaka Maeda ,  Takeshi Akasaka

发明人： Yutaka Maeda ,  Takeshi Akasaka

IPC分类号： C07F7/08

CPC分类号： B82Y40/00 ,  B82Y30/00 ,  C01B32/174

摘要： A process for producing functionalized carbon nanotubes, which can organically modify carbon nanotubes with high efficiency, and in particular, can introduce different organic groups into carbon nanotubes with high efficiency through a series of chemical reactions, is provided.Carbon nanotubes are allowed to react with at least one reagent selected from a silyl-substituted organometallic compound and an organometallic compound to obtain a functionalized carbon nanotube reductant, and this functionalized carbon nanotube reductant is then allowed to react with at least one reagent selected from a silyl halide compound and an organohalogen compound to obtain functionalized carbon nanotubes.

摘要翻译： 提供了可以高效率地有机地改性碳纳米管的功能化碳纳米管的制造方法，特别是能够通过一系列化学反应将不同的有机基团以高效率引入到碳纳米管中。 使碳纳米管与至少一种选自甲硅烷基取代的有机金属化合物和有机金属化合物的试剂反应以获得官能化的碳纳米管还原剂，然后使该官能化的碳纳米管还原剂与至少一种选自以下的试剂反应： 甲硅烷基卤化合物和有机卤素化合物，以获得官能化的碳纳米管。

公开(公告)号：US20120053358A1

公开(公告)日：2012-03-01

申请号：US13255347

申请日：2010-03-11

申请人： Yutaka Maeda ,  Takeshi Akasaka

发明人： Yutaka Maeda ,  Takeshi Akasaka

IPC分类号： C07F7/08 ,  B82Y40/00 ,  B82Y30/00

CPC分类号： B82Y40/00 ,  B82Y30/00 ,  C01B32/174

摘要： A process for producing functionalized carbon nanotubes, which can organically modify carbon nanotubes with high efficiency, and in particular, can introduce different organic groups into carbon nanotubes with high efficiency through a series of chemical reactions, is provided.Carbon nanotubes are allowed to react with at least one reagent selected from a silyl-substituted organometallic compound and an organometallic compound to obtain a functionalized carbon nanotube reductant, and this functionalized carbon nanotube reductant is then allowed to react with at least one reagent selected from a silyl halide compound and an organohalogen compound to obtain functionalized carbon nanotubes.

摘要翻译： 提供了可以高效率地有机地改性碳纳米管的功能化碳纳米管的制造方法，特别是能够通过一系列化学反应将不同的有机基团以高效率引入到碳纳米管中。 使碳纳米管与至少一种选自甲硅烷基取代的有机金属化合物和有机金属化合物的试剂反应以获得官能化的碳纳米管还原剂，然后使该官能化的碳纳米管还原剂与至少一种选自以下的试剂反应： 甲硅烷基卤化合物和有机卤素化合物，以获得官能化的碳纳米管。

公开(公告)号：US5621130A

公开(公告)日：1997-04-15

申请号：US141630

申请日：1993-10-27

申请人： Wataru Ando ,  Takeshi Akasaka ,  Shigeru Nagase ,  Kaoru Kobayashi ,  Hajime Miyazaki

发明人： Wataru Ando ,  Takeshi Akasaka ,  Shigeru Nagase ,  Kaoru Kobayashi ,  Hajime Miyazaki

IPC分类号： B82B1/00 ,  G03G5/05 ,  G03G5/06 ,  C07F7/08 ,  C07F7/18

CPC分类号： G03G5/062 ,  G03G5/0578 ,  G03G5/0605 ,  G03G5/0642

摘要： A photosensitive member having stable electrophotographic characteristics can be constituted by an electroconductive support and a photosensitive layer disposed thereon and containing a novel fullerene compound having an organosilicon group as a charge-transporting substance. The fullerene compound may preferably have a polyhedral structure, particularly that of Buckminsterfullerene (C.sub.60) and be represented by the formula: C.sub.60 (A).sub.n . . . (2), wherein A denotes an organosilicon group represented by the formula: ##STR1## (wherein R.sub.1-1 and R.sub.1-2 independently denote a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted silyl group, a substituted or unsubstituted germyl group, a halogen atom, or a group constituting a substituted or unsubstituted ring by a mutual combination of R.sub.1-1 and R.sub.1-2 together with the Si atom in the formula); and n is an integer of 1 to 5, and a plurality of A in the case of n being two or larger can be the same or different with each other.

摘要翻译： 具有稳定的电子照相特性的感光构件可由导电载体和设置在其上的感光层构成，并含有具有有机硅基团的新型富勒烯化合物作为电荷输送物质。 富勒烯化合物可以优选具有多面体结构，特别是Buckminsterfullerene（C60）的多面体结构，并由下式表示：C60（A）n。 。 。 （2）其中A表示由下式表示的有机硅基团：（1）（其中R1-1和R1-2独立地表示氢原子，取代或未取代的烷基，取代或未取代的芳基， 取代或未取代的烷氧基，取代或未取代的甲硅烷基，取代或未取代的锗基，卤素原子或构成取代或未取代的环的基团，通过R 1和R 2的相互组合与Si 原子在式中）; n为1〜5的整数，n为2以上的情况下的多个A可以相同或不同。