公开(公告)号：US09046797B2

公开(公告)日：2015-06-02

申请号：US13983994

申请日：2012-03-01

申请人： Atsushi Fujii ,  Hideaki Matsuoka ,  Haruyuki Tsuji ,  Nobuhiro Nakamura ,  Kazuhisa Shida

发明人： Atsushi Fujii ,  Hideaki Matsuoka ,  Haruyuki Tsuji ,  Nobuhiro Nakamura ,  Kazuhisa Shida

IPC分类号： G03G5/00 ,  G03G7/00 ,  G03G5/10 ,  G03G5/14 ,  G03G5/05

CPC分类号： G03G7/0053 ,  G03G5/0507 ,  G03G5/0525 ,  G03G5/10 ,  G03G5/104 ,  G03G5/142 ,  G03G5/144

摘要： To provide a process for producing an electrophotographic photosensitive member that can not easily cause any fog due to an increase in dark attenuation, a conductive layer is formed with use of a coating liquid for conductive layer prepared with use of a solvent, a binder material and metal oxide particles. The metal oxide particles (P) and binder material (B) in the coating liquid for conductive layer are in a mass ratio (P/B) of from 1.5/1.0 to 3.5/1.0. The metal oxide particle is a titanium oxide particle coated with tin oxide doped with phosphorus or tungsten. Where powder resistivity of the metal oxide particle is represented by x (Ω·cm) and powder resistivity of the titanium oxide particle as a core particle constituting the metal oxide particle is represented by y (Ω·cm), the y and the x satisfy the following relations (i) and (ii): 5.0×107≦y≦5.0×109  (i) 1.0×102≦y/x≦1.0×106  (ii).

摘要翻译： 为了提供一种用于制造由于暗衰减增加而不容易引起灰雾的电子照相感光构件的制造方法，使用通过使用溶剂，粘合剂材料和粘合剂材料制备的导电层用涂布液形成导电层， 金属氧化物颗粒。 用于导电层的涂布液中的金属氧化物颗粒（P）和粘合剂材料（B）的质量比（P / B）为1.5 / 1.0至3.5 / 1.0。 金属氧化物颗粒是涂覆有掺杂有磷或钨的氧化锡的氧化钛颗粒。 当金属氧化物颗粒的粉末电阻率由x（＆OHgr·cm）表示，作为构成金属氧化物颗粒的核心颗粒的氧化钛颗粒的粉末电阻率由y（＆Omega; cm）表示时，y和 x满足以下关系式（i）和（ii）：5.0×107＆nlE; y＆nlE; 5.0×109（i）1.0×102＆nlE; y / x＆nlE; 1.0×106（ii）。

公开(公告)号：US08778580B2

公开(公告)日：2014-07-15

申请号：US13384149

申请日：2010-09-03

申请人： Haruyuki Tsuji ,  Atsushi Fujii ,  Hideaki Matsuoka

发明人： Haruyuki Tsuji ,  Atsushi Fujii ,  Hideaki Matsuoka

IPC分类号： G03G5/04

CPC分类号： G03G5/144 ,  G03G5/102 ,  G03G5/142

摘要： An electrophotographic photosensitive member having a specific conductive layer and promising less variation in light-area potential and residual potential in reproducing images repeatedly, and a process cartridge and an electrophotographic apparatus which have such an electrophotographic photosensitive member are provided. Where a test in which a voltage of −1.0 kV having only a DC voltage component is continuously applied to the conductive layer for 1 hour is conducted, the conductive layer has volume resistivity satisfying the following mathematical expressions (1) and (2), as values before and after the test: −2.00≦(log|ρ2|−log|ρ1|)≦2.00  (1), and 1.0×108≦ρ1≦2.0×1013  (2), where, in the expressions (1) and (2), ρ1 is volume resistivity (Ω·cm) of the conductive layer as measured before the test and ρ2 is volume resistivity (Ω·cm) of the conductive layer as measured after the test.

摘要翻译： 提供具有特定导电层的电子照相感光构件，并且重复地再现图像中的光区电位和剩余电位的变化较小，以及具有这种电子照相感光构件的处理盒和电子照相设备。 在进行1小时的连续施加直流电压成分的-1.0kV的电压的试验中，导电层的体积电阻率满足下述数学式（1）和（2），如 测试前后的值：-2.00＆nlE;（log |＆rgr; 2 | -log |＆rgr; 1 |）＆nlE; 2.00（1）和1.0×108＆nlE;＆rgr; 1＆nlE; 2.0×1013（2） 在表达式（1）和（2）中，＆rgr; 1是测试前测量的导电层的体积电阻率（＆OHgr;·cm），2是导电层的体积电阻率（＆OHgr·cm） 在测试后测量。

公开(公告)号：US20130323632A1

公开(公告)日：2013-12-05

申请号：US13984264

申请日：2012-03-01

申请人： Atsushi Fujii ,  Hideaki Matsuoka ,  Haruyuki Tsuji ,  Kazuhisa Shida ,  Nobuhiro Nakamura

发明人： Atsushi Fujii ,  Hideaki Matsuoka ,  Haruyuki Tsuji ,  Kazuhisa Shida ,  Nobuhiro Nakamura

IPC分类号： G03G15/00 ,  G03G21/18

CPC分类号： G03G5/087 ,  G03G5/0507 ,  G03G5/0525 ,  G03G5/104 ,  G03G5/142 ,  G03G5/144 ,  G03G21/1814

摘要： Provided are an electrophotographic photosensitive member in which leakage doesn't easily occur, a process cartridge and an electrophotographic apparatus each including the electrophotographic photosensitive member, and a method of manufacturing the electrophotographic photosensitive member. The electrophotographic photosensitive member includes a conductive layer including titanium oxide particle coated with tin oxide doped with a hetero element. When an absolute value of a maximum current amount flowing through the conductive layer in a case of performing a test of applying −1.0 kV including DC voltage to the conductive layer is defined as Ia, and an absolute value of a current amount flowing through the conductive layer in a case where a decrease ratio of a current amount per minute reaches 1% or less for the first time is defined as Ib, the relations of Ia≦6000 and 10≦Ib are satisfied. A volume resistivity of the conductive layer before the test is 1.0×108 Ω·cm to 5.0×1012 Ω·cm.

摘要翻译： 提供了不容易发生泄漏的电子照相感光构件，各自包括电子照相感光构件的处理盒和电子照相设备以及制造电子照相感光构件的方法。 电子照相感光构件包括导电层，该导电层包括用掺杂有异质元素的氧化锡涂覆的氧化钛颗粒。 在对导电层进行包含直流电压-1.0kV的试验的情况下，流过导电层的最大电流量的绝对值定义为Ia，流过导电性的电流量的绝对值 在每分钟的电流量的降低比率首次达到1％以下的情况下，层被定义为Ib，满足Ia @ 6000和10 @ Ib的关系。 试验前的导电层的体积电阻率为1.0×108Ω·cm〜5.0×1012Ω·cm。

公开(公告)号：US08455170B2

公开(公告)日：2013-06-04

申请号：US13409439

申请日：2012-03-01

申请人： Nobuhiro Nakamura ,  Hideaki Matsuoka ,  Atsushi Fujii ,  Haruyuki Tsuji ,  Kazuhisa Shida

发明人： Nobuhiro Nakamura ,  Hideaki Matsuoka ,  Atsushi Fujii ,  Haruyuki Tsuji ,  Kazuhisa Shida

IPC分类号： G03G5/04

CPC分类号： G03G5/104 ,  G03G5/144

摘要： An electrophotographic photosensitive member is provided in which black spots on an output image are hardly caused by local charge injection from a support to a photosensitive layer. For this purpose, a conductive layer is formed using a coating liquid for a conductive layer prepared using a solvent, a binder material and a metal oxide particle that satisfies the following relation (i): 45≦A×ρ×D≦65 (i) wherein A denotes the surface area of the metal oxide particle per unit mass [m2/g], D denotes the number average particle diameter of the metal oxide particle [μm], and ρ denotes the density of the metal oxide particle [g/cm3]. The metal oxide particle is a titanium oxide particle coated with tin oxide doped with phosphorus.

摘要翻译： 提供一种电子照相感光构件，其中输出图像上的黑点几乎不会由从支持体到感光层的局部电荷注入引起。 为此，使用使用满足以下关系式（i）的溶剂，粘合剂材料和金属氧化物粒子制备的导电层用涂布液形成导电层：45 @ A×rho×D @ 65（i ）其中A表示每单位质量的金属氧化物颗粒的表面积[m2 / g]，D表示金属氧化物颗粒的数均粒径[mum]，rho表示金属氧化物颗粒的密度[g / cm3]。 金属氧化物颗粒是涂覆有掺杂有磷的氧化锡的氧化钛颗粒。

公开(公告)号：US08303736B2

公开(公告)日：2012-11-06

申请号：US12524004

申请日：2008-01-22

申请人： Hideaki Matsuoka

发明人： Hideaki Matsuoka

IPC分类号： C22C21/00

CPC分类号： C22F1/00 ,  B21B3/003 ,  B21B2003/001 ,  B22D11/003 ,  B22D21/007 ,  C22C21/00 ,  C22F1/04

摘要： A casted aluminum alloy obtained by casting a molten metal of an aluminum alloy, an aluminum alloy material obtained by at least heating the casted aluminum alloy, and methods for producing them. In the production of the casted aluminum alloy, a molten metal is obtained by melting an aluminum alloy containing 0.8 to 5 mass % of Fe, 0.15 to 1 mass % of Ti, Zr or the like as third component elements in an specific amount, and a residual part containing Al and inevitable impurities at a certain temperature (melting step). Subsequently, the molten metal is cast into a plate-like shape by a casting mold while cooling the molten metal to a temperature that is lower by at least 10° C. than a solidus temperature of the aluminum alloy at a cooling rate of 150° C./sec. or more and less than 10000° C./sec. (casting step).

摘要翻译： 通过浇铸铝合金的熔融金属，至少加热铸造的铝合金得到的铝合金材料及其制造方法得到的铸造铝合金。 在铸造铝合金的制造中，通过熔化含有0.8〜5质量％的Fe，0.15〜1质量％的Ti，Zr等作为特定量的第3成分的铝合金，得到熔融金属， 在一定温度（熔融步骤）中含有Al和不可避免的杂质的残留部分。 随后，通过铸模将熔融金属浇铸成板状，同时将熔融金属冷却至比铝合金的固相线温度低至少10℃的温度，冷却速度为150° C./sec。 或更多且小于10000℃/秒。 （铸造步骤）。

公开(公告)号：US20050153223A1

公开(公告)日：2005-07-14

申请号：US10630772

申请日：2003-07-31

申请人： Satoshi Kojima ,  Toshiyuki Ehara ,  Hideaki Matsuoka ,  Junichiro Hashizume ,  Ryuji Okamura ,  Koji Hitsuishi ,  Hironori Ohwaki ,  Kazuto Hosoi

发明人： Satoshi Kojima ,  Toshiyuki Ehara ,  Hideaki Matsuoka ,  Junichiro Hashizume ,  Ryuji Okamura ,  Koji Hitsuishi ,  Hironori Ohwaki ,  Kazuto Hosoi

IPC分类号： G03G5/082 ,  G03G15/04

CPC分类号： G03G5/08221 ,  G03G5/08278

摘要： An electrophotographic photosensitive member production process is provided having the steps of placing a cylindrical substrate having a conductive surface in a first film-forming chamber, and decomposing a source gas with high-frequency power to deposit on the cylindrical substrate a first layer formed of a non-single-crystal material, taking out of the first film-forming chamber the cylindrical substrate with the first layer deposited thereon, and placing the cylindrical substrate with the first layer deposited thereon in a second film-forming chamber, and decomposing a source gas with a high-frequency power to deposit on the first layer a second layer having an upper-part blocking layer formed of a non-single-crystal material. Even where abnormal growth portions called spherical protuberances are present on the photosensitive member surface, they can be made not to appear on images, and image defects can vastly be remedied.

摘要翻译： 提供一种电子照相感光构件制造方法，其具有以下步骤：将具有导电表面的圆柱形基材放置在第一成膜室中，并且以高频电力分解源气体以沉积在圆柱形基板上，形成第一层 非单晶材料，从第一成膜室取出其上沉积有第一层的圆柱形基板，并将其上沉积有第一层的圆柱形基板放置在第二成膜室中，并将源气体 具有高频功率以在第一层上沉积具有由非单晶材料形成的上部阻挡层的第二层。 即使在感光构件表面上存在称为球形隆起物的异常生长部分，也可以使其不会出现在图像上，并且可以大大地补救图像缺陷。

公开(公告)号：US20120121291A1

公开(公告)日：2012-05-17

申请号：US13384149

申请日：2010-09-03

申请人： Haruyuki Tsuji ,  Atsushi Fujii ,  Hideaki Matsuoka

发明人： Haruyuki Tsuji ,  Atsushi Fujii ,  Hideaki Matsuoka

IPC分类号： G03G21/18 ,  G03G15/00

CPC分类号： G03G5/144 ,  G03G5/102 ,  G03G5/142

摘要： An electrophotographic photosensitive member having a specific conductive layer and promising less variation in light-area potential and residual potential in reproducing images repeatedly, and a process cartridge and an electrophotographic apparatus which have such an electrophotographic photosensitive member are provided. Where a test in which a voltage of −1.0 kV having only a DC voltage component is continuously applied to the conductive layer for 1 hour is conducted, the conductive layer has volume resistivity satisfying the following mathematical expressions (1) and (2), as values before and after the test: −2.00≦(log|ρ2|−log|ρ1|)≦2.00  (1), and 1.0×108≦ρ1≦2.0×1013  (2), where, in the expressions (1) and (2), ρ1 is volume resistivity (Ω·cm) of the conductive layer as measured before the test and ρ2 is volume resistivity (Ω·cm) of the conductive layer as measured after the test.

摘要翻译： 提供具有特定导电层的电子照相感光构件，并且重复地再现图像中的光区电位和剩余电位的变化较小，以及具有这种电子照相感光构件的处理盒和电子照相设备。 在进行1小时的连续施加直流电压成分的-1.0kV的电压的试验中，导电层的体积电阻率满足下述数学式（1）和（2），如 测试前后的值：-2.00＆nlE;（log |＆rgr; 2 | -log |＆rgr; 1 |）＆nlE; 2.00（1）和1.0×108＆nlE;＆rgr; 1＆nlE; 2.0×1013（2） 在表达式（1）和（2）中，＆rgr; 1是测试前测量的导电层的体积电阻率（＆OHgr;·cm），2是导电层的体积电阻率（＆OHgr·cm） 在测试后测量。

公开(公告)号：US20100098580A1

公开(公告)日：2010-04-22

申请号：US12524004

申请日：2008-01-22

申请人： Hideaki Matsuoka

发明人： Hideaki Matsuoka

IPC分类号： C22C21/00 ,  B22D23/00 ,  B22D11/124 ,  C22C21/12 ,  C22C21/16 ,  C22C21/04

CPC分类号： C22F1/00 ,  B21B3/003 ,  B21B2003/001 ,  B22D11/003 ,  B22D21/007 ,  C22C21/00 ,  C22F1/04

摘要： A casted aluminum alloy obtained by casting a molten metal of an aluminum alloy, an aluminum alloy material obtained by at least heating the casted aluminum alloy, and methods for producing them. In the production of the casted aluminum alloy, a molten metal is obtained by melting an aluminum alloy containing 0.8 to 5 mass % of Fe, 0.15 to 1 mass % of Ti, Zr or the like as third component elements in an specific amount, and a residual part containing Al and inevitable impurities at a certain temperature (melting step). Subsequently, the molten metal is cast into a plate-like shape by a casting mold while cooling the molten metal to a temperature that is lower by at least 10° C. than a solidus temperature of the aluminum alloy at a cooling rate of 150° C./sec. or more and less than 10000° C./sec. (casting step).

摘要翻译： 通过浇铸铝合金的熔融金属，至少加热铸造的铝合金得到的铝合金材料及其制造方法得到的铸造铝合金。 在铸造铝合金的制造中，通过熔化含有0.8〜5质量％的Fe，0.15〜1质量％的Ti，Zr等作为特定量的第3成分的铝合金，得到熔融金属， 在一定温度（熔融步骤）中含有Al和不可避免的杂质的残留部分。 随后，通过铸模将熔融金属浇铸成板状，同时将熔融金属冷却至比铝合金的固相线温度低至少10℃的温度，冷却速度为150° C./sec。 或更多且小于10000℃/秒。 （铸造步骤）。

公开(公告)号：US20060108030A1

公开(公告)日：2006-05-25

申请号：US10530484

申请日：2003-10-09

申请人： Hiroki Yoshioka ,  Masaki Yamanaka ,  Hideaki Matsuoka

发明人： Hiroki Yoshioka ,  Masaki Yamanaka ,  Hideaki Matsuoka

IPC分类号： C22C21/12

CPC分类号： C22C21/003 ,  C22C21/16 ,  C22C21/18

摘要： An aluminum alloy for cutting processing consists essentially of Cu: 1 to 6.5 mass %, Zn: 0.05 to 1 mass %, Bi: 0.1 to 1 mass %, Sn: 0.1 to 1 mass %, B: 100 mass ppm or less, or further includes at least one element as a selective additional element selected from the group consisting of Fe: 0.05 to 1 mass %, Mg: 0.01 to 0.3 mass %, Si: 0.05 to 1 mass % and Ti: 0.01 to 0.5 mass %.

摘要翻译： 用于切割加工的铝合金基本上由Cu：1〜6.5质量％，Zn：0.05〜1质量％，Bi：0.1〜1质量％，Sn：0.1〜1质量％，B：100质量ppm以下，或 进一步包括选自Fe：0.05〜1质量％，Mg：0.01〜0.3质量％，Si：0.05〜1质量％，Ti：0.01〜0.5质量％的选择性添加元素中的至少一种元素。

公开(公告)号：US07033717B2

公开(公告)日：2006-04-25

申请号：US10630772

申请日：2003-07-31

申请人： Satoshi Kojima ,  Toshiyuki Ehara ,  Hideaki Matsuoka ,  Junichiro Hashizume ,  Ryuji Okamura ,  Koji Hitsuishi ,  Hironori Ohwaki ,  Kazuto Hosoi

发明人： Satoshi Kojima ,  Toshiyuki Ehara ,  Hideaki Matsuoka ,  Junichiro Hashizume ,  Ryuji Okamura ,  Koji Hitsuishi ,  Hironori Ohwaki ,  Kazuto Hosoi

IPC分类号： G03G15/04

CPC分类号： G03G5/08221 ,  G03G5/08278

摘要： An electrophotographic photosensitive member production process is provided having the steps of placing a cylindrical substrate having a conductive surface in a first film-forming chamber, and decomposing a source gas with high-frequency power to deposit on the cylindrical substrate a first layer formed of a non-single-crystal material, taking out of the first film-forming chamber the cylindrical substrate with the first layer deposited thereon, and placing the cylindrical substrate with the first layer deposited thereon in a second film-forming chamber, and decomposing a source gas with a high-frequency power to deposit on the first layer a second layer having an upper-part blocking layer formed of a non-single-crystal material. Even where abnormal growth portions called spherical protuberances are present on the photosensitive member surface, they can be made not to appear on images, and image defects can vastly be remedied.

摘要翻译： 提供一种电子照相感光构件制造方法，其具有以下步骤：将具有导电表面的圆柱形基材放置在第一成膜室中，并且以高频电力分解源气体以沉积在圆柱形基板上，形成第一层 非单晶材料，从第一成膜室取出其上沉积有第一层的圆柱形基板，并将其上沉积有第一层的圆柱形基板放置在第二成膜室中，并将源气体 具有高频功率以在第一层上沉积具有由非单晶材料形成的上部阻挡层的第二层。 即使在感光构件表面上存在称为球形隆起物的异常生长部分，也可以使其不会出现在图像上，并且可以大大地补救图像缺陷。