摘要:
The present invention relates to a method for the manufacture of cyclododecasulfur, a cyclic sulfur allotrope wherein the number of sulfur (S) atoms in the allotrope's homocyclic ring is 12. The method includes reacting a metallasulfur derivative with an oxidizing agent in a reaction zone to form a cyclododecasulfur-containing reaction mixture.
摘要:
The present invention relates to a process for the production of polymeric sulfur, including a) distilling a mixture of liquid sulfur and a solvent for cycloocta sulfur with a boiling point of less than 444° C. at standard pressure, wherein the bottoms temperature is lower than the boiling temperature of the sulfur and greater than the boiling temperature of the solvent and is at least 120° C.; b) quenching of the sulfur melt obtained as the bottoms product of the distillation according to a) with a non-basic liquid or a mixture of non-basic liquids to a temperature below the melting temperature of sulfur.
摘要:
An organic solvent alone or together with a rubber process oil is added to a powder of .mu.-sulfur, the mixture is granulated, and the granulation product is heated at a temperature lower than 120.degree. C. to evaporate the organic solvent, whereby granular .mu.-sulfur having an improved flowability is obtained. This granular .mu.-sulfur is valuable as a rubber-vulcanizing agent.
摘要:
A novel process for the preparation of insoluble sulfur product comprises the steps of vaporizing sulfur, mixing the vaporized sulfur with from about 1.times.10.sup.-6 % to about 5% hydrogen sulfide, in the essential absence of hydrocarbon oil, quenching the vaporized sulfur in a quenching medium and separating the insoluble sulfur product from the quenching medium.
摘要:
Sulphur is stabilized in a form wholly or partially insoluble in carbon disulphide by incorporating therewith a dixanthogen of the formula ##STR1## wherein R and R.sup.1 are each independently an alkyl, cycloalkyl, aralkyl or aryl group and may be substituted by halogen or alkoxy and n is 2 or 4. The insoluble sulphur can for example be plastic sulphur or white sulphur or substantially wholly insoluble sulphur derived therefrom. The sulphur is particularly useful in the vulcanization of rubber.
摘要:
A process for plasticizing sulfur to obtain a flexible, elastomeric product by reacting a mixture of dicyclopentadiene and a second cyclic diene or a di- or triolefinic terpene with sulfur.
摘要:
A PROCESS FOR PRODUCING INSOLUBLE SULFUR IS DISCLOSED AND INCLUDES THE STEPS OF MELTING AND HEATING SULFUR TO A TEMPERATURE OF FROM 400 TO 800* F. AND THEREAFTER QUICKLY QUENCHING THE MOLTEN SULFUR WITHIN AN AQUEOUS SOLUTION CONTAINING HYDROGEN PEROXIDE.