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    Process for the production of power from crude fuels containing high concentrations of sulfur
    22.
    发明授权
    Process for the production of power from crude fuels containing high concentrations of sulfur 失效
    从含有高浓度硫的原油燃料生产电力的过程

    公开(公告)号：US4238922A

    公开(公告)日：1980-12-16

    申请号：US038299

    申请日：1979-05-11

    Applicant: Wayne B. Gitchel

    Inventor： Wayne B. Gitchel

    IPC: C10G27/06 ,  C10L9/02 ,  F02C7/00

    CPC classification number: C10L9/02 ,  C10G27/06

    Abstract: A sulfur bearing fuel is wet oxidized in the presence of an alkaline earth metal carbonate, of which the corresponding sulfate is insoluble. Ash and sulfate salt blown down from the wet oxidation are reacted at high temperature with another portion of the same or a different fuel to reduce the sulfate to sulfide. Carbonation of an aqueous dispersion of the sulfide releases hydrogen sulfide which is converted to elemental sulfur. Carbonate precipitates and is recycled.

    Abstract translation: 含硫燃料在碱土金属碳酸盐存在下进行湿式氧化，其中相应的硫酸盐不溶。 从湿式氧化中吹出的灰分和硫酸盐在高温下与另一部分相同或不同的燃料反应以将硫酸盐还原成硫化物。 硫化物的水分散体的碳酸化释放硫化氢，其转化为元素硫。 碳酸盐沉淀并回收利用。

    Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate
    23.
    发明授权
    Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate 失效
    催化复合材料特别适用于含硫酸石油馏分中硫醇的氧化

    公开(公告)号：US4157312A

    公开(公告)日：1979-06-05

    申请号：US927317

    申请日：1978-07-24

    Applicant: Robert R. Frame

    Inventor： Robert R. Frame

    IPC: B01J21/18 ,  B01J31/02 ,  B01J31/16 ,  B01J31/18 ,  C01G27/06 ,  C10G27/06 ,  C10G27/10 ,  B01J31/12

    CPC classification number: B01J31/1616 ,  B01J31/0239 ,  B01J31/0254 ,  B01J31/183 ,  C10G27/06 ,  C10G27/10 ,  B01J21/18 ,  B01J2231/70 ,  B01J2531/025 ,  B01J2531/845 ,  B01J2540/34

    Abstract: A catalytic composite comprising a metal chelate mercaptan oxidation catalyst and a quaternary ammonium salt impregnated on a solid adsorptive support is disclosed. The quaternary ammonium salt is represented by the structural formula ##STR1## wherein R is a hydrocarbon radical containing up to about 20 carbon atoms and selected from the group consisting of alkyl, cycloalkyl, aryl, alkaryl and aralkyl, R.sub.1 is a substantially straight-chain alkyl radical containing from about 5 to about 20 carbon atoms, R.sub.2 is selected from the group consisting of aryl, alkaryl, and aralkyl, and X is an anion selected from the group consisting of halide, nitrate, nitrite, sulfate, phosphate, acetate, citrate and tartrate. The catalytic composite is particularly adapted to the oxidation of mercaptans contained in a sour petroleum distillate.

    Abstract translation: 公开了一种包含金属螯合硫醇氧化催化剂和浸渍在固体吸附载体上的季铵盐的催化复合材料。 季铵盐由结构式表示，其中R是含有至多约20个碳原子并且选自烷基，环烷基，芳基，烷芳基和芳烷基的烃基，R1是基本上直链的 含有约5至约20个碳原子的烷基，R 2选自芳基，烷芳基和芳烷基，X是选自卤素，硝酸根，亚硝酸根，硫酸根，磷酸根，乙酸根， 柠檬酸盐和酒石酸盐。 催化复合材料特别适用于酸性石油馏出物中所含的硫醇的氧化。

    PROCESSES AND APPARATUS FOR SEPARATING TREATED GASOLINE RANGE HYDROCARBONS FROM SPENT ALKALI SOLUTION
    30.
    发明申请
    PROCESSES AND APPARATUS FOR SEPARATING TREATED GASOLINE RANGE HYDROCARBONS FROM SPENT ALKALI SOLUTION 审中-公开
    从惰性碱解决方案中分离处理的汽油范围的方法和装置

    公开(公告)号：US20160115393A1

    公开(公告)日：2016-04-28

    申请号：US14521166

    申请日：2014-10-22

    Applicant: UOP LLC

    Inventor： Edward Fraser Smith ,  Luigi Laricchia ,  Jonathan Andrew Tertel

    IPC: C10G27/06 ,  C10G67/12 ,  C10G53/14

    CPC classification number: C10G27/06 ,  C10G33/06 ,  C10G53/14 ,  C10G67/12 ,  C10G67/14 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202

    Abstract: Processes and apparatus are provided for treating gasoline range hydrocarbons containing mercaptans to convert the mercaptans to organic disufides. The process involves contacting treated gasoline range hydrocarbons comprising organic disulfides with a coalescing material and separating refined gasoline range hydrocarbons and organic disulfides from spent alkali using a separation device. The apparatus comprises a treatment vessel suitable for housing a catalyst therein for producing treated gasoline range hydrocarbons comprising organic disulfides, as well as a separation device and coalescing material therein for separating gasoline range hydrocarbons and organic disulfides from spent alkali.

    Abstract translation: 提供了用于处理含有硫醇的汽油范围烃以将硫醇转化为有机脱水剂的方法和装置。 该方法包括将包含有机二硫化物的经处理的汽油范围的烃与聚结材料接触，并使用分离装置从废碱中分离精制汽油范围的烃和有机二硫化物。 该装置包括适于容纳其中的催化剂的处理容器，用于生产包含有机二硫化物的经处理的汽油范围的烃，以及用于从废碱中分离汽油范围的烃和有机二硫化物的分离装置和聚结材料。

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