公开(公告)号：US12043804B2

公开(公告)日：2024-07-23

申请号：US18180917

申请日：2023-03-09

Applicant: PHILLIPS 66 COMPANY

Inventor： Amit B. Patel ,  Lyda Zambrano ,  Varadharajan Kailasam

IPC: C10G19/02 ,  C10G33/08

CPC classification number: C10G19/02 ,  C10G2300/1003 ,  C10G2300/1014

Abstract: A process comprising creating an immiscible mixture by combining (a) a hydrocarbon feedstock containing contaminants and (b) a wash water, to create the immiscible mixture with at least three distinct layers: a hydrocarbon layer, a rag layer, and a brine layer. In this process a portion of the contaminants are removed from the hydrocarbon mixture where are then transferred to the brine layer. The brine layer is then separated from the immiscible mixture. In this process an alkalinity modifier is added in the process to reduce the emulsions in the immiscible mixture to create the at least three distinct layers.

公开(公告)号：US20240076557A1

公开(公告)日：2024-03-07

申请号：US18355444

申请日：2023-07-20

Applicant: UNIVERSITY OF SOUTH CAROLINA

Inventor： MICHAEL M. ROYKO ,  SAMUEL M. DRUMMOND ,  JOCHEN LAUTERBACH

IPC: C10G19/02

CPC classification number: C10G19/02 ,  C10G2300/202 ,  C10G2300/207

Abstract: Methods for upgrading a bio-oil are described. The methods utilize gaseous ammonia to react with one or more components of a bio-oil and thereby upgrade the bio-oil and separate the resulting mixture into organic and aqueous phases. Both the aqueous phase and the organic phase produced by the process can contain useful species such as ammonium species and an organic phase with increased energy content as compared to the bio-oil.

公开(公告)号：US20180312762A1

公开(公告)日：2018-11-01

申请号：US16025790

申请日：2018-07-02

Applicant: MERICHEM COMPANY

Inventor： Jeffrey Bruce Gomach

IPC: C10G27/10 ,  C10G19/02 ,  C10G27/06 ,  C10G27/04 ,  B01J19/32 ,  B01J19/24

CPC classification number: C10G27/10 ,  B01J19/242 ,  B01J19/32 ,  B01J2219/1943 ,  B01J2219/24 ,  C10G19/02 ,  C10G27/04 ,  C10G27/06 ,  C10G2300/202 ,  C10G2300/4056 ,  C10G2300/4081

Abstract: A process for the removal of residual sulfur compounds from rich liquid caustic is disclosed where a single column containing two reaction zones catalytically oxidizes mercaptans to disulfide oils. The second reaction zone utilizes a bundle of vertical hanging fibers and is maintained as a gas continuous phase comprising from about 20% to about 100% by volume vapor. This process is especially useful as part of a hydrocarbon desulfurization process flow scheme.

公开(公告)号：US20180201845A1

公开(公告)日：2018-07-19

申请号：US15722544

申请日：2017-10-02

Applicant: Chevron U.S.A. Inc.

Inventor： Lin Li

IPC: C10G19/02 ,  C10G57/00

CPC classification number: C10G19/02 ,  C10G57/00 ,  C10G2300/203

Abstract: A process for reducing TAN of hydrocarbon feed oil, comprising: a. combining alkaline earth metal, in an aqueous solution having a pH of 10 to 14, with the hydrocarbon feed oil to make a mixture; b. vigorously mixing the mixture; c. precipitating a metal-naphthenate salt; and d. removing the metal-naphthenate salt to reduce the TAN by 50 to 100%; wherein a weight ratio of the hydrocarbon feed oil to the aqueous solution is from 0.25:1 to 20:1. Also, a process for reducing TAN, comprising: a. combining an inorganic alkaline earth metal salt having a water solubility at 20° C. from 35 to 150 g/100 g water, in an aqueous solution having a pH of 10 to 14, to make a mixture; b. precipitating a metal-naphthenate salt; c. collecting the metal-naphthenate salt at an interface between an oil phase and an aqueous phase; and d. removing the metal-naphthenate salt.

公开(公告)号：US09878300B2

公开(公告)日：2018-01-30

申请号：US14170429

申请日：2014-01-31

Applicant: Poly Shield Technologies Inc.

Inventor： Rasmus Norling

IPC: C10L10/00 ,  B01J19/08 ,  B01J19/00 ,  C10G31/06 ,  C10G31/08 ,  C10G33/02 ,  C10G53/04 ,  C10G53/12 ,  C10G19/02 ,  C10G21/06

CPC classification number: B01J19/088 ,  B01J19/008 ,  C10G19/02 ,  C10G21/06 ,  C10G31/06 ,  C10G31/08 ,  C10G33/02 ,  C10G53/04 ,  C10G53/12 ,  C10G2300/202

Abstract: A system and method for cleaning sulfur and other pollutants from bunker oil to be used for fuel in large cargo ships is described. Preferably, the system includes two or more stages having a mixer to create an emulsion of oil and water. One or more treatment chemicals are added to the water before it is mixed with the oil in order to assist in separating the sulfur from the oil and freeing it up so that it can combine with various other molecules present in the water or be dissolved in the water. The emulsion may pass through a microcavitation chamber as well as an electrolysis reactor chamber in order to further clean the fuel oil by removing additional sulfur content. The clean fuel is sent to a fuel service tank for use in a diesel engine combustion cycle.

公开(公告)号：US09803149B2

公开(公告)日：2017-10-31

申请号：US14068068

申请日：2013-10-31

Applicant: General Electric Company

Inventor： Alagarsamy Subbiah ,  Rebika Mayanglambam Devi ,  Nimeshkumar Kantilal Patel ,  Muthukumar Nagu ,  Rhomit Ghosh ,  Sathees Kesavan ,  Ashok Shankar Shetty ,  Manish Joshi

IPC: C10G75/04 ,  C10G29/20 ,  C10G7/10 ,  C10G19/073 ,  C10G75/00 ,  C10G75/02 ,  C10G19/00 ,  C10G19/02 ,  C10G21/20

CPC classification number: C10G75/04 ,  C10G7/10 ,  C10G19/00 ,  C10G19/02 ,  C10G19/073 ,  C10G21/20 ,  C10G29/20 ,  C10G75/00 ,  C10G75/02 ,  C10G2300/4075 ,  C10G2300/44 ,  C10G2300/80

Abstract: Treatment compositions for neutralizing acidic species and reducing hydrochloride and amine salts in a fluid hydrocarbon stream are disclosed. The treatment compositions may comprise at least one amine with a salt precipitation potential index of equal to or less than about 1.0. Methods for neutralizing acidic species and reducing deposits of hydrochloride and amine salts in a hydrocarbon refining process are also disclosed. The methods may comprise providing a fluid hydrocarbon stream and adding a treatment composition to the fluid hydrocarbon stream. The treatment compositions used may have a salt precipitation potential index of equal to or less than about 1.0 and comprise either water-soluble or oil-soluble amines.

公开(公告)号：US09708550B2

公开(公告)日：2017-07-18

申请号：US14360322

申请日：2012-10-16

Applicant: IFP ENERGIES NOUVELLES

Inventor： Frederic Augier ,  Arnaud Baudot ,  Jeremy Gazarian ,  Damien Leinekugel Le Cocq

IPC: C10G19/02 ,  C10G19/08 ,  C10G21/08 ,  C10G21/28 ,  C10G53/06 ,  C10G53/12 ,  C10G21/30 ,  C10G21/12

CPC classification number: C10G53/12 ,  C10G19/02 ,  C10G19/08 ,  C10G21/08 ,  C10G21/12 ,  C10G21/28 ,  C10G21/30 ,  C10G53/06

Abstract: Process of extracting sulphur-containing compounds from a hydrocarbon cut of the gasoline or LPG type by liquid-liquid extraction with a soda solution employing a unit (2) for pretreatment of the feedstock to be treated located upstream of the unit (4) for extraction with soda, said pretreatment unit consisting of a first pretreatment reactor operating in batch mode followed by a second continuous reactor of the piston type operating in piston mode.

公开(公告)号：US09708547B2

公开(公告)日：2017-07-18

申请号：US13172370

申请日：2011-06-29

Applicant: Sunder Ramachandran ,  Vladimir Jovancicevic ,  Ying H. Tsang ,  Michael P. Squicciarini ,  Philippe Prince ,  Jianzhong Yang ,  Kyle C. Cattanach

Inventor： Sunder Ramachandran ,  Vladimir Jovancicevic ,  Ying H. Tsang ,  Michael P. Squicciarini ,  Philippe Prince ,  Jianzhong Yang ,  Kyle C. Cattanach

IPC: C10G29/26 ,  C02F1/68 ,  C10G19/02 ,  C10G19/04 ,  C10G29/20 ,  C10G29/22 ,  B01D53/48 ,  B01D53/52 ,  C02F101/10 ,  C02F103/36 ,  B01D53/14

CPC classification number: C10G29/26 ,  B01D53/1468 ,  B01D53/1487 ,  B01D53/1493 ,  B01D53/48 ,  B01D53/52 ,  B01D2251/304 ,  B01D2251/306 ,  B01D2252/103 ,  B01D2252/20 ,  B01D2252/60 ,  B01D2257/304 ,  B01D2257/306 ,  C02F1/683 ,  C02F2101/101 ,  C02F2101/40 ,  C02F2103/365 ,  C10G19/02 ,  C10G19/04 ,  C10G29/205 ,  C10G29/22 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/44

Abstract: Hydrogen sulfide (H2S) and/or mercaptan scavengers are chemicals that remove H2S and/or mercaptans from gas, oil and water. Water-based formulations may be made and used employing scavenging compounds having the formulae: wherein each R1, R2, R3, and R4 are the same or different and are selected from the group consisting of hydrogen, an alkyl, an alkenyl, an aryl, an acyl, a halogen, a hydroxyl, a nitro, an alkyl ester, an aryl ester, an alkyl ether, an aryl ether, a hydroxymethyl, an anhydride group, an amino, and a sulfide. In one non-limiting embodiment the compounds (A) and (B) do not contain nitrogen atoms. Water-based formulations, such as those using a protic solvent with the above compounds, work well as H2S scavengers.

公开(公告)号：US09499754B2

公开(公告)日：2016-11-22

申请号：US14682642

申请日：2015-04-09

Applicant: OTG RESEARCH, LLC

Inventor： Philip Allen Boe

IPC: C10L1/08 ,  C10G53/00 ,  C10G53/14 ,  C10L1/04 ,  C10M175/00

CPC classification number: C10L1/08 ,  C10G17/02 ,  C10G19/02 ,  C10G27/14 ,  C10G53/00 ,  C10G53/14 ,  C10G2300/1007 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L2270/026 ,  C10L2270/04 ,  C10L2290/06 ,  C10L2290/24 ,  C10M175/0016

Abstract: Methods for converting motor oil into fuel generally include forming a conversion mixture of an alcohol and a base, and adding the conversion mixture to motor oil, to form a reaction mixture. The methods can also include adding a high nitrate compound and an amino acid to the reaction mixture and ozonizing the reaction mixture. The result of the methods can include a three phase system in which the bottom phase is asphalt oil, the middle phase is diesel fuel or jet fuel, and the top phase is sulfuric acid. The three phases can be separated to obtain the final diesel fuel or jet fuel product.

Abstract translation: 将机油转化为燃料的方法通常包括形成醇和碱的转化混合物，并将转化混合物加入机油，形成反应混合物。 所述方法还可以包括向反应混合物中加入高硝酸盐化合物和氨基酸，并使反应混合物臭氧化。 方法的结果可以包括三相系统，其中底相是沥青油，中间相是柴油燃料或喷气燃料，顶相是硫酸。 这三个阶段可以分开，以获得最终的柴油燃料或喷气燃料产品。

公开(公告)号：US20160145498A1

公开(公告)日：2016-05-26

申请号：US14927618

申请日：2015-10-30

Applicant: FINA TECHNOLOGY, INC.

Inventor： Fabrice Déhais ,  Xavier Roumeau ,  Jun Wang ,  Ryan Jones ,  Kevin Kelly

IPC: C10G7/10 ,  G01N33/28 ,  G01N21/3577 ,  C10G7/00 ,  C10G7/06

CPC classification number: C10G7/10 ,  C10G7/00 ,  C10G7/06 ,  C10G19/02 ,  C10G2300/203 ,  G01N21/3577 ,  G01N33/2823 ,  G01N2021/3595

Abstract: A method for determining a TAN-IR for naphthenic acids in crude oil or crude oil fraction may include determining an IR spectrum of a sample of the crude oil or crude oil fraction. The method may include determining an IR spectrum of a neutralized sample of the crude oil or crude oil fraction. The method may include utilizing the IR spectra of the sample and the neutralized sample to determine a modified TAN-IR.

Abstract translation: 用于测定原油或原油馏分中环烷酸的TAN-IR的方法可以包括测定原油或原油馏分的样品的IR光谱。 该方法可以包括确定原油或原油馏分的中和样品的IR光谱。 该方法可以包括利用样品的IR光谱和中和的样品来确定修饰的TAN-IR。