Abstract:
According to an embodiment, a fuel cell system includes an anode supply circuit is configured for delivering an anode source fluid to anode components. The anode supply circuit includes a primary supply path, a desulfurizer situated along the primary supply path, and a pre-reformer downstream of the desulfurizer and upstream of the anode components. The pre-reformer converts a portion of anode source fluid into an anode reactant and yields a reformed source fluid that includes the anode reactant. A first feedback path carries anode exhaust fluid from the anode components such that at least some heat associated with the anode exhaust fluid facilitates the pre-reformer converting at least some anode source fluid into the anode reactant. A second feedback path carries at least a portion of the reformed source fluid to be mixed with the anode source fluid provided to the desulfurizer.
Abstract:
An electrochemical fuel cell comprises an anode electrocatalyst layer, a cathode electrocatalyst layer, a polymer electrolyte membrane interposed between the anode and cathode electrocatalyst layers, an anode flow field plate, a cathode flow field plate, an anode fluid distribution layer interposed between the anode flow field plate and the anode electrocatalyst layer, and a cathode fluid distribution layer interposed between the cathode flow field plate and the cathode electrocatalyst layer, wherein at least one of the anode and cathode fluid distribution layers decreases in permeability from an inlet to an outlet of the electrochemical fuel cell. Methods for making a substantially fluid impermeable sheet material having a non-uniform pattern of perforations are also provided.
Abstract:
Liquid cooled systems having coolant circulation loops must often operate in below freezing conditions. For instance, in various applications certain fuel cell systems must be able to tolerate repeated shutdown and storage in below freezing conditions. Conventional glycol-based coolants typically used for internal combustion engines are generally unsuitable for use in the associated fuel cell cooling subsystems due to the presence of additives and/or inhibitors which are normally included to deal with problems relating to decomposition of the glycol. With additives or inhibitors present, the coolant conductivity can be sufficiently high as to result in electrical shorting or corrosion problems. However, provided the purity of the coolant is maintained, a pure glycol and water coolant mixture may be used as a fuel cell system coolant to obtain suitable antifreeze protection. Adequate purity can be maintained by including an ion exchange resin unit in the cooling subsystem.
Abstract:
A fuel cell based power supply comprises a main power converter and control that allows the fuel cell stack to be electrically shorted from time-to-time to improve performance. Additionally, the power converter may temporarily disconnect the fuel cell stack from the load after shorting, allowing the fuel cell stack to return to an open circuit voltage, and/or provide current limiting during a period after shorting to provide stable operation while the fuel cell stack powers the load and recharges a power storage device.
Abstract:
A membrane electrode assembly with an improved integrated seal comprises an edge seal having an inboard pad attached to the edge of the electrodes, a flexible coupling adjacent the pad, and a sealing element adjacent the coupling. The sealing element is significantly thicker than the pad, and the flexible coupling isolates the pad from stress experienced in the sealing element. Thus, greater compression can be applied to the sealing element, thereby providing an improved and more reliable seal, without overly compressing and damaging the attached pad.
Abstract:
Disclosed are reactant feed apparatus for liquid-fueled direct feed fuel cells, including miniaturized versions thereof. More specifically, disclosed is a fuel flow device for delivering liquid fuel to such direct feed fuel cells. The fuel flow device comprises a fuel flow-routing device and an enclosure/partition assembly containing the liquid fuel to be delivered. When the fuel flow device is fluidly connected to the fuel cell, it operates to deliver the liquid fuel to an anode flow field thereof by using the pressurized anodic exhaust gases exiting therefrom as the source of power for pumping the liquid fuel from the enclosure into the fuel cell. Also disclosed is a cathode flow field plate that utilizes an array of island members to provide multi-directional oxidant flow channels and expedite the passive delivery of oxidant to, and removal of product water from, a cathode flow field of a liquid-fueled direct feed fuel cell. Further, disclosed are methods for delivering liquid fuel and oxidant to the fuel cells using the above-disclosed devices.
Abstract:
The present invention is generally directed to systems and methods for distributing a non-odorized gas. In one embodiment, an inner pipe containing a non-odorized gas at a first pressure is routed through an outer pipe adapted to contain an odorized fluid at a second pressure less than the first pressure. As a result of the pressure differential, a leak in the inner pipe will not permit the odorized fluid in the outer pipe to flow into the inner pipe. When the non-odorized gas is hydrogen, this prevents a stream of hydrogen gas that is possibly contaminated with odorants from reaching a fuel cell. Furthermore, a leak in the outer pipe or a leak in both the inner and outer pipes will result in the release of the odorized fluid into the environment, allowing leaks to be detected before dangerous or harmful levels are reached.
Abstract:
A process for preparing a graft copolymers is provided comprising exposing a polymeric base material to a dose of ionizing radiation, and then contacting the irradiated base material with a microemulsion comprising at least one fluorostyrenic monomer, water and water-miscible solvent. The graft copolymer may be formed into a membrane, including ion exchange membranes.
Abstract:
Solid polymer fuel cells can operate directly on a fuel comprising a mixture of dimethoxymethane and methanol with both dimethoxymethane and methanol being oxidized at the fuel cell anode. Both being highly soluble in water, a dimethoxymethane and methanol mixture can be supplied as a liquid aqueous fuel solution. As a fuel, a dimethoxymethane and methanol mixture can provide similar power characteristics as methanol in liquid feed solid polymer fuel cells and is found to outperform methanol at high current densities. Additionally, dimethoxymethane acts as a reactive antifreeze additive in the fuel mixture and imparts a strong and distinct odor to the fuel mixture.
Abstract:
A process for preparing a graft copolymer membrane is provided comprising exposing a porous polymeric base film to a dose of ionizing radiation, and then contacting the irradiated base film with an emulsion comprising a fluorostyrenic or fluoronaphthyl monomer. The graft copolymer membrane may be densified to render it substantially gas-impermeable.