公开(公告)号：US11592217B2

公开(公告)日：2023-02-28

申请号：US17733563

申请日：2022-04-29

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Sheng Peng ,  Mario Joseph Nappa

IPC: F25B13/00 ,  C07C17/357 ,  C07C21/18

Abstract: A fluoropropene composition comprising Z-1,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, 2,3,3,3-tetrafluoropropene, and optionally 1,1,1,3,3-pentafluoropropane wherein the 2,3,3,3-tetrafluoropropene being present in an amount of 0.00001 to 1.0%. A method of producing the fluoropropene, methods for using the fluoropropene and the composition formed are also disclosed.

公开(公告)号：US20230052956A1

公开(公告)日：2023-02-16

申请号：US17794038

申请日：2021-01-22

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Viacheslav A. Petrov ,  Andrew Jackson ,  Sheng Peng

IPC: C07C17/278 ,  C07C17/04 ,  B01J27/12

Abstract: The present application relates to processes of preparing (E)-1,1,1,4,5,5,5-heptafluoro-4-(trifluoromethyl)pent-2-ene.

公开(公告)号：US11578899B2

公开(公告)日：2023-02-14

申请号：US17840674

申请日：2022-06-15

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Sheng Peng ,  Mario Joseph Nappa

IPC: C07C21/18 ,  F25B13/00 ,  C07C17/357

Abstract: A fluoropropene composition comprising Z-1,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, 2,3,3,3-tetrafluoropropene, and optionally 1,1,1,3,3-pentafluoropropane wherein the 2,3,3,3-tetrafluoropropene being present in an amount of 0.00001 to 1.0%. A method of producing the fluoropropene, methods for using the fluoropropene and the composition formed are also disclosed.

公开(公告)号：US11565987B2

公开(公告)日：2023-01-31

申请号：US17267619

申请日：2019-08-12

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Xuehui Sun

IPC: C07C17/20 ,  C11D7/50 ,  C11D7/30 ,  C09K5/04 ,  C09K3/30 ,  C08J9/14

Abstract: A method of making chlorofluorohydrocarbons including, contacting, a fluorinated hydrocarbon reagent in the vapor phase, with hydrogen chloride (HCl). The reaction is conducted in the presence of an effective amount of a catalyst, at an elevated temperature sufficient to effect hydrochlorination to form a reaction mixture including a chlorofluorohydrocarbon.

公开(公告)号：US11547990B2

公开(公告)日：2023-01-10

申请号：US17455974

申请日：2021-11-22

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Mario Joseph Nappa

IPC: C07C21/18 ,  B01J23/26 ,  B01J27/12 ,  C07C17/25 ,  B01J35/10 ,  B01J37/26 ,  B01J27/132

Abstract: A dehydrochlorination process is disclosed. The process involves contacting RfCHClCH2Cl with a chromium oxyfluoride catalyst in a reaction zone to produce a product mixture comprising RfCCl═CH2, wherein Rf is a perfluorinated alkyl group.

公开(公告)号：US20220402842A1

公开(公告)日：2022-12-22

申请号：US17888628

申请日：2022-08-16

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： XUEHUI SUN ,  Karl Robert KRAUSE

IPC: C07C17/25 ,  C07C21/18

Abstract: The present application provides a process of preparing 3,3,3-trifluoroprop-1-ene, comprising reacting 3-chloro-1,1,1-trifluoropropane with a base in an aqueous solvent component in the absence of a phase transfer catalyst.

公开(公告)号：US20220389298A1

公开(公告)日：2022-12-08

申请号：US17327834

申请日：2021-05-24

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Barbara Haviland Minor ,  Velliyur Nott Mallikarjuna Rao

IPC: C09K5/04 ,  A62D1/02 ,  B60H1/32 ,  C08J9/12 ,  C08J9/14 ,  C09K3/30 ,  C10M171/00 ,  A62D1/00 ,  B01F17/00 ,  F25B45/00

Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

公开(公告)号：US20220348524A1

公开(公告)日：2022-11-03

申请号：US17812203

申请日：2022-07-13

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Xuehui SUN ,  Karl Krause

IPC: C07C17/25

Abstract: A dehydrohalogenation product includes a hydrochlorofluorocarbon mixture of a fluoroolefin of formula RCX═CZQ and a halofluoroalkane of formula RCXYCZQT. R is a perfluorinated alkyl group and X, Z, and Q are independently H or halogen. One of Y and T is H and the other is Cl, Br, or I. About 80% or greater of the hydrochlorofluorocarbon mixture is the fluoroolefin. The dehydrohalogenation product also includes a caustic agent and a solvent. In some embodiments, the dehydrohalogenation product is free of any catalyst, including any phase transfer catalyst.

公开(公告)号：US20220325160A1

公开(公告)日：2022-10-13

申请号：US17850556

申请日：2022-06-27

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： JOSHUA HUGHES ,  Barbara Haviland Minor

IPC: C09K5/04

Abstract: In accordance with the present invention refrigerant compositions are disclosed. The compositions comprise a refrigerant mixture consisting essentially of HFC-32, HFO-1234yf, and CO2. The compositions are useful in processes to produce cooling and heating, in methods for replacing refrigerant R-32, and in refrigeration, air conditioning or heat pump systems. These inventive compositions are match cooling performance for R-32 with GWP less than 400 or less than 300.

公开(公告)号：US11434185B2

公开(公告)日：2022-09-06

申请号：US17218446

申请日：2021-03-31

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Mario Joseph Nappa ,  Xuehui Sun ,  David Richard Corbin

IPC: C07C17/389 ,  C07C17/25 ,  C07C17/087

Abstract: This disclosure relates to processes which involve: contacting a mixture comprising at least one fluoroolefin and at least one impurity with at least one zeolite to reduce the concentration of the at least one impurity in the mixture; and the at least one zeolite is selected from the group consisting of zeolites having pore opening of at least 4 Angstroms and no more than about 5 Angstroms, zeolites having pore opening of at least about 5 Angstroms and Sanderson electronegativity of no more than about 2.6, and mixtures thereof; provided that the at least one zeolite is not zeolite 4A. This disclosure also relates to processes for making at least one hydrotetrafluoropropene product selected from the group consisting of CF3CF═CH2, CF3CH═CHF, and mixtures thereof; and relates to processes for making at least one hydrochlorotrifluoropropene product selected from the group consisting of CF3CCl═CH2, CF3CH═CHCl, and mixtures thereof.