公开(公告)号：US09790150B2

公开(公告)日：2017-10-17

申请号：US14813415

申请日：2015-07-30

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Andrew Jackson ,  Sheng Peng ,  Mario Joseph Nappa

IPC: C07C17/383 ,  C07C17/278 ,  C07C19/14 ,  C07C17/25 ,  C07C19/12

CPC classification number: C07C17/278 ,  C07C17/25 ,  C07C17/383 ,  C07C19/12 ,  C07C19/14 ,  C07C19/10 ,  C07C21/18

Abstract: Processes for producing branched fluoroalkyl olefins are disclosed. In addition, novel halo-fluoroalkane intermediates are disclosed that may be used in the branched fluoroalkyl olefin production processes. Non-limiting examples of branched fluoroalkyl olefins include branched fluorobutenes, such as 1,3,4,4,4-pentafluoro-3-trifluoromethyl) but-1-ene (HFO-1438ezy). In some aspects, there is disclosed a method for dehydrobrominating 4-bromo-1,1,1,2,4-pentafluoro-2-(trifluoromethyl)butane to produce 1,3,4,4,4-pentafluoro-3-(trifluoromethyl)but-1-ene (HFO-1438ezy).

公开(公告)号：US20210198168A1

公开(公告)日：2021-07-01

申请号：US17055877

申请日：2019-07-08

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Andrew Jackson

IPC: C07C21/18 ,  C07C17/20 ,  B01J23/26 ,  B01J37/26 ,  C07C17/23 ,  C07C17/04

Abstract: A method of synthesizing 3,3,3-trifluoropropene including contacting 1,3,3,3-tetrachloropropane, in the vapor phase, at a temperature sufficient to effect dehydrochlorination to form 1,1,3-trichloro-1-propene. The 1,1,3-trichloro-1-propene is isolated and subsequently contacted, in the vapor phase, with hydrogen fluoride in the presence of a fluorination catalyst at a temperature sufficient to effect formation of 3,3,3-trifluoropropene.

公开(公告)号：US09328042B2

公开(公告)日：2016-05-03

申请号：US14813383

申请日：2015-07-30

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Sheng Peng ,  Andrew Jackson ,  Mario Joseph Nappa

IPC: C07C17/02 ,  C07C17/00 ,  C07C17/20 ,  C07C17/04 ,  C07C17/25

CPC classification number: C07C17/04 ,  C07C17/087 ,  C07C17/25 ,  Y02P20/125 ,  C07C19/01 ,  C07C21/20 ,  C07C21/18

Abstract: The present invention provides an efficient and cost effect synthesis route from a specific starting material of 2,3-dichloro-1,3-butadiene to the desired product of Z-1,1,1,4,4,4-hexafluoro-2-butene.

Abstract translation: 本发明提供了一种从2,3-二氯-1,3-丁二烯的特定原料到Z-1,1,1,4,4,4-六氟-2 丁烯。

公开(公告)号：US20230052956A1

公开(公告)日：2023-02-16

申请号：US17794038

申请日：2021-01-22

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Viacheslav A. Petrov ,  Andrew Jackson ,  Sheng Peng

IPC: C07C17/278 ,  C07C17/04 ,  B01J27/12

Abstract: The present application relates to processes of preparing (E)-1,1,1,4,5,5,5-heptafluoro-4-(trifluoromethyl)pent-2-ene.

公开(公告)号：US11731925B2

公开(公告)日：2023-08-22

申请号：US16320320

申请日：2017-07-24

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Sheng Peng ,  Mario Joseph Nappa ,  Andrew Jackson ,  Robert D. Lousenberg

IPC: C07C17/278 ,  C07C17/25 ,  C07C17/20 ,  C07C21/18 ,  C07C19/08 ,  C07C17/275

CPC classification number: C07C17/278 ,  C07C17/206 ,  C07C17/25 ,  C07C17/275 ,  C07C21/18 ,  C07C17/278 ,  C07C19/10 ,  C07C17/275 ,  C07C19/01 ,  C07C17/25 ,  C07C21/18 ,  C07C17/206 ,  C07C19/10

Abstract: Disclosed herein is a process comprising contacting a haloalkane reactant with an olefin in the presence of a catalyst system that consists of metallic iron and a phosphine to produce a haloalkane insertion product, wherein said haloalkane reactant is an alkane substituted with at least one halogen selected from the group consisting of F, Cl, and combinations thereof. Also disclosed herein is a process comprising contacting CF3CCl3 with CH2═CHX in the presence of a catalyst system that consists of metallic iron and a phosphine to make CF3CCl2CH2CHClX, wherein X═F or Cl. Also disclosed are further reactions in a sequence to produce HFO-1336ze and HCFO-1335zd. Also disclosed herein is a new composition comprising the compound CF3CF2CH═CHCl.

公开(公告)号：US20190077733A1

公开(公告)日：2019-03-14

申请号：US16126560

申请日：2018-09-10

Applicant: The Chemours Company FC, LLC

Inventor： Sheng Peng ,  Andrew Jackson ,  Stephan Brandstadter ,  Mario Joseph Nappa

IPC: C07C17/25 ,  C07C21/185 ,  C07C19/12 ,  C07C17/20 ,  B01J31/02 ,  B01J27/10 ,  B01J27/135 ,  B01J23/745

Abstract: Disclosed herein are methods of producing E-CF3CH═CHCF3 in a liquid phase. Also disclosed are methods of preparing CF3CH2CHClCF3 and CF3CHClCH2CCl3.