公开(公告)号：US11547990B2

公开(公告)日：2023-01-10

申请号：US17455974

申请日：2021-11-22

申请人： THE CHEMOURS COMPANY FC, LLC

发明人： Mario Joseph Nappa

IPC分类号： C07C21/18 ,  B01J23/26 ,  B01J27/12 ,  C07C17/25 ,  B01J35/10 ,  B01J37/26 ,  B01J27/132

摘要： A dehydrochlorination process is disclosed. The process involves contacting RfCHClCH2Cl with a chromium oxyfluoride catalyst in a reaction zone to produce a product mixture comprising RfCCl═CH2, wherein Rf is a perfluorinated alkyl group.

公开(公告)号：US11311863B2

公开(公告)日：2022-04-26

申请号：US16923324

申请日：2020-07-08

申请人： Chevron Phillips Chemical Company LP

发明人： Ryan W. Snell ,  Gabriela Alvez-Manoli

IPC分类号： B01J29/08 ,  B01J27/13 ,  B01J29/60 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/24 ,  B01J37/26 ,  C10G55/00 ,  B01J29/62 ,  B01J29/63 ,  B01J29/74 ,  B01J29/76 ,  B01J35/00 ,  B01J35/10 ,  B01J37/22

摘要： A process of making an aromatization catalyst comprising: (a) mixing a zeolite, a binder, and water to form a mixture; (b) extruding the mixture to form a green extrudate; (c) drying the green extrudate to form a dried green extrudate; (d) calcining the dried green extrudate to form a support, wherein calcining the dried green extrudate is the only calcination step in the process; (e) washing the support to form a washed support; (f) drying the washed support to form a dried washed support; (g) impregnating the dried washed support with a Group 8-10 transition metal compound and at least one halide-containing compound to form a metalized-halided material; and (h) vacuum drying the metalized-halided material to form a dried metalized-halided material which is the aromatization catalyst.

公开(公告)号：US11141718B2

公开(公告)日：2021-10-12

申请号：US16251196

申请日：2019-01-18

申请人： Chevron Phillips Chemical Company LP

发明人： Ryan W. Snell ,  Xianghong Hao

IPC分类号： B01J29/74 ,  B01J37/06 ,  B01J37/02 ,  B01J35/10 ,  B01J23/42 ,  B01J29/62 ,  C10G35/095 ,  C10G45/70 ,  B01J27/138 ,  B01J27/10 ,  B01J27/12 ,  B01J37/08 ,  B01J37/22 ,  B01J37/24 ,  B01J37/26 ,  B01J37/30 ,  B01J37/00 ,  B01J23/58

摘要： Methods for producing supported catalysts containing a transition metal and a bound zeolite base are disclosed. These methods employ a step of washing the bound zeolite base in the presence of an alkali metal, prior to impregnating the bound zeolitic support with the transition metal. Alkali metals such as potassium and cesium may be used.

公开(公告)号：US11103856B2

公开(公告)日：2021-08-31

申请号：US15972757

申请日：2018-05-07

申请人： Chevron Phillips Chemical Company LP

发明人： Ryan W. Snell ,  Gabriela Alvez-Manoli

IPC分类号： B01J29/62 ,  B01J27/13 ,  B01J29/60 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/24 ,  B01J37/26 ,  C10G55/00 ,  B01J29/08 ,  B01J29/63 ,  B01J29/74 ,  B01J29/76 ,  B01J35/00 ,  B01J35/10 ,  B01J37/22

摘要： A process of making an aromatization catalyst comprising: (a) mixing a zeolite, a binder, and water to form a mixture; (b) extruding the mixture to form a green extrudate; (c) drying the green extrudate to form a dried green extrudate; (d) calcining the dried green extrudate to form a support, wherein calcining the dried green extrudate is the only calcination step in the process; (e) washing the support to form a washed support; (f) drying the washed support to form a dried washed support; (g) impregnating the dried washed support with a Group 8-10 transition metal compound and at least one halide-containing compound to form a metalized-halided material; and (h) vacuum drying the metalized-halided material to form a dried metalized-halided material which is the aromatization catalyst.

公开(公告)号：US20210094911A1

公开(公告)日：2021-04-01

申请号：US17050139

申请日：2019-04-25

申请人： SOLVAY SA

发明人： Sebastian HASENSTAB-RIEDEL ,  Jan Hendrick NISSEN ,  Helmut BECKERS ,  Simon STEINHAUER ,  Thomas DREWS ,  Holger PERNICE

IPC分类号： C07C407/00 ,  B01J27/12 ,  B01J37/26

摘要： The present invention relates to the preparation of perfluorinated or partially fluorinated peroxides which avoids the use of carbonyl fluoride (COF2).

公开(公告)号：US10604417B2

公开(公告)日：2020-03-31

申请号：US16457892

申请日：2019-06-28

申请人： TIANJIN POLYTECHNIC UNIVERSITY

发明人： Yuzhong Zhang ,  Leitao Zhang ,  Hong Li

IPC分类号： C01F17/00 ,  B01D53/02 ,  B01J20/02 ,  B01J20/28 ,  B01J20/30 ,  B01J27/12 ,  B01J35/00 ,  B01J35/10 ,  B01J37/04 ,  B01J37/26 ,  H01M4/58 ,  B82Y30/00 ,  B82Y40/00

摘要： The present application provides a method for preparing lanthanide fluoride two-dimensional porous nanosheets and belongs to the field of novel materials. In the present application, mixing a water-soluble lanthanide metal salt and an aqueous solution of sodium acetate in a nitrogen atmosphere to obtain a mixed solution, and adding an aqueous solution of fluorine-containing salt to the mixed solution obtained for precipitation reaction to produce lanthanide fluoride two-dimensional porous nanosheets. In the preparation process provided by the present application, no additional surfactant or template agent needs to be added, the pollution of the surfactant to the surface of the prepared material is avoided and the tedious after-treatment steps to template agent are reduced. Accordingly, the large-scale production can be realized, and the lanthanide fluoride two-dimensional porous nanosheets constructed by nanoparticles are prepared in large scale by one step. Moreover, no other organic solvents are required, and the pollution to the environment during the preparation process is avoided.

公开(公告)号：US20200086308A1

公开(公告)日：2020-03-19

申请号：US16688688

申请日：2019-11-19

申请人： THE CHEMOURS COMPANY FC, LLC

发明人： Mario Joseph NAPPA

IPC分类号： B01J35/10 ,  B01J37/26 ,  C07C17/25 ,  B01J23/26

摘要： A dehydrochlorination process is disclosed. The process involves contacting RfCHClCH2Cl with a chromium oxyfluoride catalyst in a reaction zone to produce a product mixture comprising RfCCl═CH2, wherein Rf is a perfluorinated alkyl group.

公开(公告)号：US10577294B2

公开(公告)日：2020-03-03

申请号：US16060037

申请日：2016-12-07

申请人： Arkema France

发明人： David Andre ,  Dominique Deur-Bert ,  Dominique Garrait ,  Anne Pigamo ,  Laurent Wendlinger

IPC分类号： C07C17/20 ,  B01J38/46 ,  B01J23/92 ,  B01J37/14 ,  B01J37/18 ,  B01J38/10 ,  B01J38/12 ,  B01J27/32 ,  B01J37/12 ,  B01J37/16 ,  B01J27/132 ,  C07C17/21 ,  B01J23/26 ,  B01J37/26 ,  B01J38/42 ,  B01J38/04 ,  B01J37/24 ,  C07C17/087 ,  C07C19/08

摘要： The present invention relates to a method for fluorinating a chlorinated compound including the steps of (a) placing said chlorinated compound in contact with gaseous hydrogen fluoride within a reactor and in the presence of a fluorination catalyst to produce a fluorinated compound, and (b) regenerating the fluorination catalyst used in step a), the step of regenerating the fluorination catalyst including (c) treating said fluorination catalyst with an oxidizing agent to form an oxidized fluorination catalyst, and (d) treating the oxidized fluorination catalyst obtained in step (c) with a gas mixture including a reducing agent.

公开(公告)号：US10150104B2

公开(公告)日：2018-12-11

申请号：US14935982

申请日：2015-11-09

申请人： Chevron Phillips Chemical Company LP

发明人： An-Hsiang Wu

IPC分类号： B01J29/06 ,  B01J29/62 ,  B01J37/02 ,  B01J37/24 ,  B01J37/26 ,  C07C5/31 ,  B01J37/22 ,  B01J29/60 ,  C07C5/41

摘要： A method of preparing an aromatization catalyst comprising contacting a zeolitic support with a metal-containing compound and a boron-containing compound to produce an impregnated support, and contacting the impregnated support with an activating composition to produce an aromatization catalyst, wherein the activating composition comprises a chlorine-containing compound and a fluorine-containing compound, and wherein the impregnated support is heated in the presence of the activating composition to a temperature in the range of from about 100° C. to about 500° C.

公开(公告)号：US20180057431A1

公开(公告)日：2018-03-01

申请号：US15806138

申请日：2017-11-07

申请人： XI'AN MODERN CHEMISTRY RESEARCH INSTITUTE

发明人： Jian LU ,  Bo WANG ,  Yue QIN ,  Wei MAO ,  Liangang KOU ,  Zhenhua ZHANG ,  Fei HE ,  Wei ZHANG ,  Hui MA ,  Yangbo MA ,  Zhijun HAO ,  Chunying LI ,  Yongmei DU ,  Fengxian LI ,  Sheng HAN

IPC分类号： C07C17/20 ,  C07C17/25 ,  B01J37/26 ,  B01J23/83 ,  B01J27/128 ,  C07C21/18

CPC分类号： C07C17/206 ,  B01J23/83 ,  B01J27/128 ,  B01J37/26 ,  C07C17/25 ,  C07C21/18

摘要： Disclosed in the present invention are a chromium-free gas phase fluorination catalyst and an application thereof. The precursor of the related chromium-free gas phase fluorination catalyst consists of a compound containing iron element, a compound containing rare earth metal element and a compound containing element A, wherein element A is one selected from Ca, Al, Mg and Ti, the precursor is subjected to roasting and fluorination treating to obtain the chromium-free gas phase fluorination catalyst. The precursor of the catalyst is roasted at 400-500° C. and fluoridized with hydrogen fluoride at 350-450° C. to obtain the chromium-free gas phase fluorination catalyst. The catalyst has characteristics of being chromium-free and environment-friendly, good catalytic activity and long life etc. The catalyst can be used for preparing hydrofluoroolefins or hydrochlorofluoroolefins from halohydrocarbons.