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公开(公告)号:US08314056B2
公开(公告)日:2012-11-20
申请号:US13096104
申请日:2011-04-28
申请人: Dorota Sendor-Müller , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Sven Müller , Wolfgang Wick
发明人: Dorota Sendor-Müller , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Sven Müller , Wolfgang Wick
IPC分类号: C11D17/00
CPC分类号: C11D3/3757 , C11D1/72 , C11D3/2086 , C11D11/0023
摘要: The invention relates to low-alkaline and bleach-free dishwasher detergents having a pH value (20° C.) between 8 and 12, comprising a) 10 to 60 wt % of citrate, b) 1.5 to 30 wt % anionic copolymer, comprising i) unsaturated monocarboxylic acid(s) A ii) unsaturated dicarboxylic acid(s) B, characterized by good cleaning action, particularly improved cleaning of tea.
摘要翻译: 本发明涉及具有8-12之间的pH值(20℃)的低碱性和无漂白洗碗机洗涤剂,其包含a)10至60重量%的柠檬酸盐,b)1.5至30重量%的阴离子共聚物,其包含 i)不饱和一元羧酸A ii)不饱和二羧酸B,其特征在于良好的清洁作用,特别是改进的茶清洁。
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公开(公告)号:US20100222247A1
公开(公告)日:2010-09-02
申请号:US12720919
申请日:2010-03-10
申请人: Johannes Zipfel , Nadine Warkotsch , Arnd Kessler , Christian Nitsch , Sven Müller , Luca Bellomi
发明人: Johannes Zipfel , Nadine Warkotsch , Arnd Kessler , Christian Nitsch , Sven Müller , Luca Bellomi
IPC分类号: C11D3/00
摘要: Liquid, low-alkaline and bleach-free dishwasher detergent having a pH value (20° C.) of 8 to 12 and containing: a) 10 to 60 percent by weight of a builder; b) more than 1.5 percent by weight of a phosphonate; c) 0.1 to 20 percent by weight of an anionic copolymer comprising: i) unsaturated carboxylic acid(s) and ii) sulfonic acid group-containing monomer(s). Detergents according to the invention exhibit a good cleaning power on bleachable dirt, particularly tea stains.
摘要翻译: 具有8至12的pH值(20℃)的液体,低碱性和无漂白洗碗机洗涤剂,其含有:a)10至60重量%的助洗剂; b)超过1.5重量%的膦酸酯; c)0.1至20重量%的阴离子共聚物,其包含:i)不饱和羧酸和ii)含磺酸基团的单体。 根据本发明的洗涤剂对可漂洗的污垢特别是茶渍表现出良好的清洁力。
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公开(公告)号:US20100031976A1
公开(公告)日:2010-02-11
申请号:US12536885
申请日:2009-08-06
申请人: Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
发明人: Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
CPC分类号: C11D3/33 , C11D3/2086 , C11D3/3757 , C11D3/378 , C11D3/3942
摘要: Phosphate-free automatic dishwashing agents containing a) citrate, b) sodium percarbonate, c) nonionic surfactant, d) copolymer encompassing i) monomers from the group of the mono- or polyunsaturated carboxylic acids, ii) monomers of the general formula R1(R2)C═C(R3)—X—R4, in which R1 to R3, mutually independently, denote —H, —CH3, or —C2H5, X denotes an optionally present spacer group that is selected from —CH2—, —C(O)O—, and —C(O)—NH—, and R4 denotes a straight-chain or branched saturated alkyl residue having 2 to 22 carbon atoms or an unsaturated, preferably aromatic residue having 6 to 22 carbon atoms, e) 0.05 to 1 wt % methylglycinediacetic acid, are notable for washing and rinsing results that are comparable or even superior to those of phosphate-containing automatic dishwashing agents.
摘要翻译: 含有a)柠檬酸盐,b)过碳酸钠的无磷酸盐自动洗碗剂,c)非离子表面活性剂,d)共聚物,包括i)单或多不饱和羧酸基团的单体,ii)通式R 1(R 2 )CC(R3)-X-R4,其中R1至R3相互独立地表示-H,-CH3或-C2H5,X表示任选存在的间隔基,其选自-CH 2 - , - C(O) O-和-C(O)-NH-,R 4表示具有2至22个碳原子的直链或支链饱和烷基或不饱和的,优选具有6至22个碳原子的芳族残基,e)0.05至1 重量%甲基甘氨酸二乙酸,对于与含磷酸盐的自动洗碗剂相当甚至更优异的洗涤和漂洗结果是显着的。
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公开(公告)号:US20100029536A1
公开(公告)日:2010-02-04
申请号:US12535956
申请日:2009-08-05
申请人: Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
发明人: Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
IPC分类号: C11D3/36
CPC分类号: C11D3/378 , C11D3/2086 , C11D3/361
摘要: Phosphate-free dishwasher detergents which contain a builder, bleaching agents, a nonionic surfactant, and also a) a copolymer comprising i) sulfonic acid group-containing monomers, ii) further ionic and/or nonionic monomer, and b) phosphonate. The detergents have good scale-inhibiting, cleaning and rinsing results which are comparable to those of phosphate-containing dishwasher detergents or even outdo them.
摘要翻译: 含有助洗剂,漂白剂,非离子表面活性剂,以及a)包含i)含磺酸基单体的共聚物,ii)其它离子和/或非离子单体和b)膦酸酯的无磷酸盐洗碗机洗涤剂。 洗涤剂具有良好的阻垢,清洁和漂洗结果,与含磷酸盐的洗碗机洗涤剂相当,甚至超过它们。
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公开(公告)号:US07424891B2
公开(公告)日:2008-09-16
申请号:US11377757
申请日:2006-03-16
申请人: Pavel Gentschev , Christian Nitsch , Ulrich Pegelow , Arnd Kessler , Maren Jekel , Johannes Zipfel
发明人: Pavel Gentschev , Christian Nitsch , Ulrich Pegelow , Arnd Kessler , Maren Jekel , Johannes Zipfel
CPC分类号: C11D17/043 , C11D3/3947 , C11D3/3956 , C11D17/045
摘要: Combination products comprising packaging and two liquid cleansers or detergents A and B separated from each other in the packaging and having the following composition: A: 10% to 75% by weight of detergent builder(s), 0.1% to 10% by weight of enzyme(s), 24.9% to 89.9% by weight of water; and B: 10% to 74.9% by weight of detergent builder(s), 25% to 89.9% by weight of water, 0.1% to 15% by weight of bleach, characterized in that the liquid detergent A has a pH value (at 20° C.) between 6 and 9. The combination products of the invention demonstrate improved cleaning power over conventional solid or liquid dishwashing detergents.
摘要翻译: 组合产品包括包装和两个液体清洁剂或洗涤剂A和B在包装中彼此分离并具有以下组成:A:10%至75重量%的洗涤剂助洗剂,0.1重量%至10重量% 24.0%〜89.9%(重量)水; 和B:10%至74.9重量%的洗涤剂助洗剂,25重量%至89.9重量%的水,0.1重量%至15重量%的漂白剂,其特征在于,所述液体洗涤剂A的pH值(在 20℃)之间。在本发明的组合产品中,相对于常规的固体或液体餐具洗涤剂,清洗能力提高了。
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36.
公开(公告)号:US08303721B2
公开(公告)日:2012-11-06
申请号:US12535927
申请日:2009-08-05
申请人: Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
发明人: Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
摘要: A phosphate-free dishwasher detergent which contains a builder, bleaching agents, and also a) a copolymer comprising i) monomers from the group of mono- or polyunsaturated carboxylic acids; ii) monomers of general formula R1(R2)C═C(R3)—X—R4; and iii) optionally further monomers, and b) a nonionic surfactant of general formula R1—CH(OH)CH2O-(AO)w-(A′O)x-(A″O)y-(A′″O)z—R2. The detergent has good cleaning and rinsing results which are comparable to those of phosphate-containing dishwasher detergents or even outdo them.
摘要翻译: 一种含磷酸盐的洗碗机洗涤剂,其含有助洗剂,漂白剂,以及a)包含i)单体或多不饱和羧酸的单体的共聚物; ii)通式R 1(R 2)C = C(R 3)-X-R 4的单体; 和(b)通式为R 1 -CH(OH)CH 2 O-(AO)w - (A'O)x - (A“O)y - (A'”O)z的非离子表面活性剂 -R2。 洗涤剂具有良好的清洗和漂洗结果,与含磷酸盐的洗碗机洗涤剂相当,甚至超过它们。
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公开(公告)号:US20110237482A1
公开(公告)日:2011-09-29
申请号:US13158747
申请日:2011-06-13
申请人: Dorota Sendor-Müller , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Sven Müller , Wolfgang Wick
发明人: Dorota Sendor-Müller , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Sven Müller , Wolfgang Wick
CPC分类号: C11D3/2086 , C11D3/2082 , C11D11/0023 , C11D17/0091
摘要: Phosphate-free, bleach-free automatic dishwashing agents comprising 10 to 60 wt % citrate and from 1 to 30 wt % maleic acid are described, wherein the automatic dishwashing agents are characterized by good cleaning performance, particularly in the improved cleaning of tea stains.
摘要翻译: 描述了含有10至60重量%的柠檬酸盐和1至30重量%的马来酸的不含磷酸盐的漂白剂的自动洗碗剂,其中所述自动洗碗剂的特征在于良好的清洁性能,特别是在改进的茶渍清洁方面。
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公开(公告)号:US20110197927A1
公开(公告)日:2011-08-18
申请号:US13096104
申请日:2011-04-28
申请人: Dorota Sendor-Müller , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Sven Müller , Wolfgang Wick
发明人: Dorota Sendor-Müller , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Sven Müller , Wolfgang Wick
CPC分类号: C11D3/3757 , C11D1/72 , C11D3/2086 , C11D11/0023
摘要: The invention relates to low-alkaline and bleach-free dishwasher detergents having a pH value (20° C.) between 8 and 12, comprising a) 10 to 60 wt % of citrate, b) 1.5 to 30 wt % anionic copolymer, comprising i) unsaturated monocarboxylic acid(s) A ii) unsaturated dicarboxylic acid(s) B, characterized by good cleaning action, particularly improved cleaning of tea.
摘要翻译: 本发明涉及具有8-12之间的pH值(20℃)的低碱性和无漂白洗碗机洗涤剂,其包含a)10至60重量%的柠檬酸盐,b)1.5至30重量%的阴离子共聚物,其包含 i)不饱和一元羧酸A ii)不饱和二羧酸B,其特征在于良好的清洁作用,特别是改进的茶清洁。
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公开(公告)号:US20100041575A1
公开(公告)日:2010-02-18
申请号:US12535991
申请日:2009-08-05
申请人: Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
发明人: Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
IPC分类号: C11D3/395
CPC分类号: C11D3/33 , C11D1/72 , C11D1/722 , C11D3/042 , C11D3/075 , C11D3/361 , C11D3/3757 , C11D3/378 , C11D3/3902 , C11D3/3942
摘要: Phosphate-free dishwasher detergents which contain a builder, bleaching agents, a nonionic surfactant, and also a) a copolymer comprising i) sulfonic acid group-containing monomers, ii) further ionic and/or nonionic monomers, b) methyl glycine diacetic acid. The detergents according to the invention have good cleaning and rinsing results which are comparable to those of phosphate-containing dishwasher detergents or even outdo them.
摘要翻译: 含有助洗剂,漂白剂,非离子表面活性剂的a)含有i)含磺酸基单体的共聚物,ii)其它离子和/或非离子单体,b)甲基甘氨酸二乙酸。 根据本发明的洗涤剂具有良好的清洁和漂洗结果,其与含磷酸盐洗碗机洗涤剂的洗涤剂相当,甚至超过它们。
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公开(公告)号:US20110232692A1
公开(公告)日:2011-09-29
申请号:US13151487
申请日:2011-06-02
申请人: Johannes Zipfel , Nadine Warkotsch , Arnd Kessler , Christian Nitsch , Dorota Sendor-Muller , Britta Strauss
发明人: Johannes Zipfel , Nadine Warkotsch , Arnd Kessler , Christian Nitsch , Dorota Sendor-Muller , Britta Strauss
CPC分类号: C11D1/825 , C11D1/721 , C11D3/3757 , C11D3/378 , C11D3/386
摘要: An automatic dishwashing agent includes builder(s), enzyme(s) and a) a nonionic surfactant A of the general formula R1O(AlkO)xM(OAlk)yOR2, in which R1 and R2 mutually independently denote a branched or unbranched, saturated or unsaturated, optionally hydroxylated alkyl residue with 4 to 22 carbon atoms; Alk denotes a branched or unbranched alkyl residue with 2 to 4 carbon atoms; x and y mutually independently denote values between 1 and 70; and M denotes an alkyl residue from the group CH2, CHR3, CR3R4, CH2CHR3 and CHR3CHR4, with R3 and R4 mutually independently denoting a branched or unbranched, saturated or unsaturated alkyl residue with 1 to 18 carbon atoms; b) a nonionic surfactant B which differs from the nonionic surfactant A; and c) an anionic copolymer C. The agent imparts an improved drying and rinsing result.
摘要翻译: 自动洗碗剂包括助洗剂,酶和a)通式R 1 O(AlkO)x M(OAlk)yOR 2的非离子表面活性剂A,其中R 1和R 2相互独立地表示支链或非支链饱和或 不饱和的,任选羟基化的具有4至22个碳原子的烷基; Alk表示具有2至4个碳原子的支链或非支链烷基; x和y相互独立地表示1和70之间的值; 并且M表示CH 2,CHR 3,CR 3 R 4,CH 2 CHR 3和CHR 3 CHR 4基团的烷基,R3和R4相互独立地表示具有1至18个碳原子的支链或非支链,饱和或不饱和的烷基; b)与非离子表面活性剂A不同的非离子表面活性剂B; 和c)阴离子共聚物C.该试剂赋予改进的干燥和漂洗结果。
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