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公开(公告)号:US20110232692A1
公开(公告)日:2011-09-29
申请号:US13151487
申请日:2011-06-02
申请人: Johannes Zipfel , Nadine Warkotsch , Arnd Kessler , Christian Nitsch , Dorota Sendor-Muller , Britta Strauss
发明人: Johannes Zipfel , Nadine Warkotsch , Arnd Kessler , Christian Nitsch , Dorota Sendor-Muller , Britta Strauss
CPC分类号: C11D1/825 , C11D1/721 , C11D3/3757 , C11D3/378 , C11D3/386
摘要: An automatic dishwashing agent includes builder(s), enzyme(s) and a) a nonionic surfactant A of the general formula R1O(AlkO)xM(OAlk)yOR2, in which R1 and R2 mutually independently denote a branched or unbranched, saturated or unsaturated, optionally hydroxylated alkyl residue with 4 to 22 carbon atoms; Alk denotes a branched or unbranched alkyl residue with 2 to 4 carbon atoms; x and y mutually independently denote values between 1 and 70; and M denotes an alkyl residue from the group CH2, CHR3, CR3R4, CH2CHR3 and CHR3CHR4, with R3 and R4 mutually independently denoting a branched or unbranched, saturated or unsaturated alkyl residue with 1 to 18 carbon atoms; b) a nonionic surfactant B which differs from the nonionic surfactant A; and c) an anionic copolymer C. The agent imparts an improved drying and rinsing result.
摘要翻译: 自动洗碗剂包括助洗剂,酶和a)通式R 1 O(AlkO)x M(OAlk)yOR 2的非离子表面活性剂A,其中R 1和R 2相互独立地表示支链或非支链饱和或 不饱和的,任选羟基化的具有4至22个碳原子的烷基; Alk表示具有2至4个碳原子的支链或非支链烷基; x和y相互独立地表示1和70之间的值; 并且M表示CH 2,CHR 3,CR 3 R 4,CH 2 CHR 3和CHR 3 CHR 4基团的烷基,R3和R4相互独立地表示具有1至18个碳原子的支链或非支链,饱和或不饱和的烷基; b)与非离子表面活性剂A不同的非离子表面活性剂B; 和c)阴离子共聚物C.该试剂赋予改进的干燥和漂洗结果。
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公开(公告)号:US08349784B2
公开(公告)日:2013-01-08
申请号:US13151487
申请日:2011-06-02
申请人: Johannes Zipfel , Nadine Warkotsch , Arnd Kessler , Christian Nitsch , Dorota Sendor-Muller , Britta Strauss
发明人: Johannes Zipfel , Nadine Warkotsch , Arnd Kessler , Christian Nitsch , Dorota Sendor-Muller , Britta Strauss
IPC分类号: C11D17/00
CPC分类号: C11D1/825 , C11D1/721 , C11D3/3757 , C11D3/378 , C11D3/386
摘要: An automatic dishwashing agent includes builder(s), enzyme(s) and a) a nonionic surfactant A of the general formula R1O(AlkO)xM(OAlk)yOR2, in which R1 and R2 mutually independently denote a branched or unbranched, saturated or unsaturated, optionally hydroxylated alkyl residue with 4 to 22 carbon atoms; Alk denotes a branched or unbranched alkyl residue with 2 to 4 carbon atoms; x and y mutually independently denote values between 1 and 70; and M denotes an alkyl residue from the group CH2, CHR3, CR3R4, CH2CHR3 and CHR3CHR4, with R3 and R4 mutually independently denoting a branched or unbranched, saturated or unsaturated alkyl residue with 1 to 18 carbon atoms; b) a nonionic surfactant B which differs from the nonionic surfactant A; and c) an anionic copolymer C. The agent imparts an improved drying and rinsing result.
摘要翻译: 自动洗碗剂包括助洗剂,酶和a)通式R 1 O(AlkO)x M(OAlk)yOR 2的非离子表面活性剂A,其中R 1和R 2相互独立地表示支链或非支链饱和或 不饱和的,任选羟基化的具有4至22个碳原子的烷基; Alk表示具有2至4个碳原子的支链或非支链烷基; x和y相互独立地表示1和70之间的值; 并且M表示CH 2,CHR 3,CR 3 R 4,CH 2 CHR 3和CHR 3 CHR 4基团的烷基,R3和R4相互独立地表示具有1至18个碳原子的支链或非支链,饱和或不饱和的烷基; b)与非离子表面活性剂A不同的非离子表面活性剂B; 和c)阴离子共聚物C.该试剂赋予改进的干燥和漂洗结果。
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公开(公告)号:US08551930B2
公开(公告)日:2013-10-08
申请号:US13418658
申请日:2012-03-13
申请人: Dorota Sendor-Muller , Johannes Zipfel , Arnd Kessler , Volker Blank , Thorsten Bastigkeit , Christian Nitsch , Thomas Eiting
发明人: Dorota Sendor-Muller , Johannes Zipfel , Arnd Kessler , Volker Blank , Thorsten Bastigkeit , Christian Nitsch , Thomas Eiting
CPC分类号: C11D3/378 , C11D3/3757
摘要: The present invention is a phosphate-free automatic dishwashing agent containing a builder, said agent comprising: a) a copolymer A comprising i) at least one mono- or polyunsaturated carboxylic acid monomer, ii) at least one mono- or polyunsaturated sulfonic acid monomer, and iii) at least one additional nonionic monomer; and b) an acrylic acid homopolymer B, wherein the weight ratio of copolymer A to homopolymer B is between 10:1 and 1:3. The present agent is characterized by excellent residue inhibition, good cleaning, and clear rinsing performance in automatic dishwashing.
摘要翻译: 本发明是含有助洗剂的无磷酸盐自动洗碗剂,所述试剂包括:a)共聚物A,其包含i)至少一种单或多不饱和羧酸单体,ii)至少一种单或多不饱和磺酸单体 ,和iii)至少一种另外的非离子单体; 和b)丙烯酸均聚物B,其中共聚物A与均聚物B的重量比为10:1至1:3。 本发明的特征在于在自动洗碗中具有优异的残留抑制,良好的清洁和漂洗性能。
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公开(公告)号:US08328951B2
公开(公告)日:2012-12-11
申请号:US13248246
申请日:2011-09-29
CPC分类号: C11D3/38663 , C11D3/3418 , C11D17/041
摘要: Liquid detergent or cleaning agent preparations include a) at least 5 wt % of at least one enzyme preparation active in washing or cleaning; and b) at least 0.5 wt % cumenesulfonate, wherein the liquid detergent or cleaning agent preparations are characterized by a good phase stability and enzyme stability and good cleaning performance.
摘要翻译: 液体洗涤剂或清洁剂制剂包括a)至少5重量%的至少一种在洗涤或清洁中有活性的酶制剂; 和b)至少0.5重量%的磺酸盐,其中液体洗涤剂或清洁剂制剂的特征在于良好的相稳定性和酶稳定性以及良好的清洁性能。
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公开(公告)号:US08268768B2
公开(公告)日:2012-09-18
申请号:US13161269
申请日:2011-06-15
IPC分类号: C11D17/00
CPC分类号: C11D3/10 , C11D3/2086 , C11D3/33
摘要: The invention relates to a phosphate- and bleach-free automatic dishwashing agent containing: a) 5 to 60 wt % citrate, b) (hydrogen) carbonate, c) 2 to 40 wt % ethylenediamine disuccinic acid, wherein the weight ratio of the components b) and c) is between 1:5 and 10:1, and wherein said automatic dishwashing agent is characterized by good cleaning performance, particularly improved cleaning of tea.
摘要翻译: 本发明涉及一种不含磷酸盐和无漂白剂的自动洗碗剂,其含有:a)5至60重量%的柠檬酸盐,b)(氢)碳酸盐,c)2至40重量%的乙二胺二琥珀酸,其中组分 b)和c)为1:5至10:1,并且其中所述自动洗碗剂的特征在于良好的清洁性能,特别是改进的茶的清洁。
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公开(公告)号:US20120167922A1
公开(公告)日:2012-07-05
申请号:US13417623
申请日:2012-03-12
申请人: Dorota Sendor-Muller , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Thorsten Bastigkeit , Thomas Eiting , Volker Blank
发明人: Dorota Sendor-Muller , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Thorsten Bastigkeit , Thomas Eiting , Volker Blank
CPC分类号: C11D1/825 , C11D1/721 , C11D1/722 , C11D11/0023
摘要: The invention relates to a phosphate-free automatic dishwashing agent containing a builder, comprising a) 0.5 to 7.0 wt % of a nonionic surfactant A; b) 0.2 to 5.0 wt % of a nonionic surfactant B with a melting point above 25° C., each based on the total weight of the automatic dishwashing agent, wherein the nonionic surfactant A has a melting point which is at least 5° C. below the melting point of nonionic surfactant B, wherein said washing agent is characterized by excellent residue inhibition and good cleaning and clear rinsing performance.
摘要翻译: 本发明涉及含有助洗剂的无磷酸盐自动洗碟剂,其包含a)0.5-7.0重量%的非离子表面活性剂A; b)0.2-5.0重量%的熔点高于25℃的非离子表面活性剂B,分别基于自动洗碗剂的总重量,其中非离子表面活性剂A的熔点至少为5℃ 低于非离子表面活性剂B的熔点,其中所述洗涤剂的特征在于优异的残留物抑制和良好的清洁和清澈的漂洗性能。
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公开(公告)号:US20100222247A1
公开(公告)日:2010-09-02
申请号:US12720919
申请日:2010-03-10
申请人: Johannes Zipfel , Nadine Warkotsch , Arnd Kessler , Christian Nitsch , Sven Müller , Luca Bellomi
发明人: Johannes Zipfel , Nadine Warkotsch , Arnd Kessler , Christian Nitsch , Sven Müller , Luca Bellomi
IPC分类号: C11D3/00
摘要: Liquid, low-alkaline and bleach-free dishwasher detergent having a pH value (20° C.) of 8 to 12 and containing: a) 10 to 60 percent by weight of a builder; b) more than 1.5 percent by weight of a phosphonate; c) 0.1 to 20 percent by weight of an anionic copolymer comprising: i) unsaturated carboxylic acid(s) and ii) sulfonic acid group-containing monomer(s). Detergents according to the invention exhibit a good cleaning power on bleachable dirt, particularly tea stains.
摘要翻译: 具有8至12的pH值(20℃)的液体,低碱性和无漂白洗碗机洗涤剂,其含有:a)10至60重量%的助洗剂; b)超过1.5重量%的膦酸酯; c)0.1至20重量%的阴离子共聚物,其包含:i)不饱和羧酸和ii)含磺酸基团的单体。 根据本发明的洗涤剂对可漂洗的污垢特别是茶渍表现出良好的清洁力。
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公开(公告)号:US20100031976A1
公开(公告)日:2010-02-11
申请号:US12536885
申请日:2009-08-06
申请人: Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
发明人: Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
CPC分类号: C11D3/33 , C11D3/2086 , C11D3/3757 , C11D3/378 , C11D3/3942
摘要: Phosphate-free automatic dishwashing agents containing a) citrate, b) sodium percarbonate, c) nonionic surfactant, d) copolymer encompassing i) monomers from the group of the mono- or polyunsaturated carboxylic acids, ii) monomers of the general formula R1(R2)C═C(R3)—X—R4, in which R1 to R3, mutually independently, denote —H, —CH3, or —C2H5, X denotes an optionally present spacer group that is selected from —CH2—, —C(O)O—, and —C(O)—NH—, and R4 denotes a straight-chain or branched saturated alkyl residue having 2 to 22 carbon atoms or an unsaturated, preferably aromatic residue having 6 to 22 carbon atoms, e) 0.05 to 1 wt % methylglycinediacetic acid, are notable for washing and rinsing results that are comparable or even superior to those of phosphate-containing automatic dishwashing agents.
摘要翻译: 含有a)柠檬酸盐,b)过碳酸钠的无磷酸盐自动洗碗剂,c)非离子表面活性剂,d)共聚物,包括i)单或多不饱和羧酸基团的单体,ii)通式R 1(R 2 )CC(R3)-X-R4,其中R1至R3相互独立地表示-H,-CH3或-C2H5,X表示任选存在的间隔基,其选自-CH 2 - , - C(O) O-和-C(O)-NH-,R 4表示具有2至22个碳原子的直链或支链饱和烷基或不饱和的,优选具有6至22个碳原子的芳族残基,e)0.05至1 重量%甲基甘氨酸二乙酸,对于与含磷酸盐的自动洗碗剂相当甚至更优异的洗涤和漂洗结果是显着的。
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公开(公告)号:US20100029536A1
公开(公告)日:2010-02-04
申请号:US12535956
申请日:2009-08-05
申请人: Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
发明人: Nadine Warkotsch , Johannes Zipfel , Arnd Kessler , Christian Nitsch , Arno Dueffels , Thomas Holderbaum
IPC分类号: C11D3/36
CPC分类号: C11D3/378 , C11D3/2086 , C11D3/361
摘要: Phosphate-free dishwasher detergents which contain a builder, bleaching agents, a nonionic surfactant, and also a) a copolymer comprising i) sulfonic acid group-containing monomers, ii) further ionic and/or nonionic monomer, and b) phosphonate. The detergents have good scale-inhibiting, cleaning and rinsing results which are comparable to those of phosphate-containing dishwasher detergents or even outdo them.
摘要翻译: 含有助洗剂,漂白剂,非离子表面活性剂,以及a)包含i)含磺酸基单体的共聚物,ii)其它离子和/或非离子单体和b)膦酸酯的无磷酸盐洗碗机洗涤剂。 洗涤剂具有良好的阻垢,清洁和漂洗结果,与含磷酸盐的洗碗机洗涤剂相当,甚至超过它们。
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公开(公告)号:US20100160204A1
公开(公告)日:2010-06-24
申请号:US12720781
申请日:2010-03-10
IPC分类号: C11D3/37
摘要: Dishwasher detergents containing: a) 10 to 60 percent by weight of a builder; and b) non-ionic surfactant of the general formula R1O[CH2CH(CH3)O]x[CH2CH2O]y[CH2CH(CH3)O]zCH2CH(OH)R2 wherein R1 is a linear or branched aliphatic hydrocarbon radical having 4 to 22 carbon atoms or mixtures thereof, R2 is a linear or branched hydrocarbon radical having 2 to 26 carbon atoms or mixtures thereof, x and z represent values between 0 and 40, and y represents a value of at least 15; c) anionic copolymer comprising: i) unsaturated carboxylic acids, ii) sulfonic acid group-containing monomers, wherein the weight ratio of components c) to b) is less than 3:1. In addition to exhibiting good cleaning and rinsing efficiency, dishwasher detergents according to the invention enhance the drying process of the cleaned dishes.
摘要翻译: 洗碗机洗涤剂,其含有:a)10至60重量%的助洗剂; 和b)具有通式R 1 O [CH 2 CH(CH 3)O] x [CH 2 CH 2 O] y [CH 2 CH(CH 3)O] z CH 2 CH(OH)R 2的非离子表面活性剂,其中R 1是具有4至22的直链或支链脂族烃基 碳原子或其混合物,R2是具有2至26个碳原子的直链或支链烃基或其混合物,x和z表示0至40之间的值,y表示至少15的值; c)阴离子共聚物,其包含:i)不饱和羧酸,ii)含磺酸基团的单体,其中组分c)至b)的重量比小于3:1。 除了表现出良好的清洁和漂洗效率之外,根据本发明的洗碗机洗涤剂增强了清洁的餐具的干燥过程。
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