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    Products and process
    32.
    发明授权
    Products and process 失效
    产品和工艺

    公开(公告)号：US3887583A

    公开(公告)日：1975-06-03

    申请号：US30241472

    申请日：1972-10-31

    Applicant: COMMERCIAL SOLVENTS CORP

    Inventor： WEHRMEISTER HERBERT L ,  JOHNSTON DAVID B R ,  WINDHOLZ THOMAS B

    IPC: A23K1/16 ,  A23K1/18 ,  C07D313/00 ,  C07D9/00

    CPC classification number: C07D313/00 ,  A23K20/116 ,  A23K20/126 ,  A23K50/30

    Abstract: Compounds of the formula:

    WHEREIN T is a radical selected from the group consisting of CH CH- and -CH2CH2-; Z is >C O, >CH2, or >CHOR; R is hydrogen, alkyl, aromatic hydrocarbon radicals or acyl; X is hydrogen, -OR or -OR''; R'' is benzoxazolyl, benzothiazolyl, or phenyltetrazolyl, X'' is X or tetrahydropyranyloxy; Y is hydrogen, or hydroxyl; and unless at least one of X and X'' is tetrahydropyranyloxy, benzoxazolyloxy, benzothiazolyloxy, or phenyltetrazolyloxy, then at least one of X and X'' is hydrogen; and animal feeds containing growth promoting amounts of these compounds. The novel compounds can be prepared from zearalenone and appropriate derivatives or zearalenone by (a) etherifying at least one or both of the substituents in the 2 and 4 positions (the X substituents) of the A ring with certain heterocyclic compounds and subjecting the ether to hydrogenolysis to cleave the heterocyclic ether radical and replace at least one of these substituents with hydrogen and (b) when producing compounds having at least one hydroxyl, amino or nitro substituent in the 3 and 5 positions (the Y substituents) of the A ring, nitrating either one or both, depending upon the final compound desired, of the 3 and 5 positions of compounds produced by process (a) and converting, when desired, the nitro substituent to an amino or a hydroxyl substituent. Alternatively, compounds having at least one of a hydroxyl, amino or nitro substituent can be used as a starting material in process (a).

    Abstract translation: 下式的化合物：

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