公开(公告)号：US20160177033A1

公开(公告)日：2016-06-23

申请号：US14908843

申请日：2014-07-28

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Xinrui Yu ,  Yiyong He ,  Ronald H. Leng

IPC: C08G71/04 ,  B01J19/24

CPC classification number: C08G71/04 ,  B01J19/24 ,  B01J2219/00164 ,  B01J2219/24 ,  C08G65/33303 ,  C09D161/24 ,  C09D175/12

Abstract: A process to produce polycarbamate comprising providing urea in liquid form; and adding the urea in liquid form to a polyol in a reduced gradient profile to form polycarbamate product is provided. Also provided are: (a) a reaction product of the process and (b) an apparatus for operating the process.

Abstract translation: 一种生产聚氨酯的方法，包括以液体形式提供尿素; 并提供液体形式的脲以减少的梯度曲线形式制成多元醇以形成聚氨酯。 还提供了：（a）该方法的反应产物和（b）用于操作该方法的装置。

公开(公告)号：US20160060382A1

公开(公告)日：2016-03-03

申请号：US14835761

申请日：2015-08-26

Applicant: Dow Global Technologies LLC

Inventor： Syed Z. Mahdi ,  Yiyong He

IPC: C08G18/83 ,  C08L75/08

CPC classification number: C08L75/08 ,  C08G18/10 ,  C08G18/2865 ,  C08G18/289

Abstract: An improved silane modified polymer useful in adhesive compositions is made from a silane precursor material made by a process comprising reacting an organic compound having a backbone that is terminated by an amino group having at least one active amino hydrogen and a hydrolysable silane, wherein the backbone is comprised of at least one secondary amino group having one active amino hydrogen and a Michael addition acceptor compound, wherein the Michael addition compound fails to have a group reactive with an isocyanate group to form the silane precursor compound. The silane precursor compound is reacted with an isocyanate terminated polyurethane prepolymer to form a silane modified prepolymer. The silane modified prepolymer may then be cured with moisture and may be employed in an adhesive composition containing other components such as a plasticizer, catalyst and filler.

Abstract translation: 可用于粘合剂组合物的改进的硅烷改性聚合物由硅烷前体材料制成，所述硅烷前体材料通过包括使具有由具有至少一个活性氨基氢的氨基封端的主链与可水解硅烷反应的有机化合物反应而制备，其中主链 由具有一个活性氨基氢和迈克尔加成受体化合物的至少一个仲氨基组成，其中迈克尔加成化合物不能具有与异氰酸酯基反应形成硅烷前体化合物的基团。 将硅烷前体化合物与异氰酸酯封端的聚氨酯预聚物反应以形成硅烷改性预聚物。 硅烷改性预聚物然后可以用水分固化，并且可以用于含有其它组分例如增塑剂，催化剂和填料的粘合剂组合物中。

公开(公告)号：US20150344417A1

公开(公告)日：2015-12-03

申请号：US14721423

申请日：2015-05-26

Applicant: Dow Global Technologies LLC

Inventor： Jeff R. Anderson ,  Daryoosh Beigzadeh ,  Yiyong He ,  Congcong Lu

IPC: C07C269/04

CPC classification number: C07C269/04 ,  C08G18/06 ,  C08G18/38 ,  C08G18/3823 ,  C08G18/79 ,  C08G71/02

Abstract: The present invention provides methods for making a polycarbamate by feeding a) a urea in fluid form into a reaction medium containing b) an alkyd polyol, such as a short or med oil alkyd polyol to form a reaction mixture and then carbamylating the alkyd polyol by heating the reaction mixture while feeding water in to the reaction mixture, preferably, in the presence of one or more c) carbamylation catalysts. The polycarbamate of the present invention when combined with a polyaldehyde or an acetal or hemiacetal thereof as a second component makes a multicomponent composition that is substantially isocyanate-free, and cures at a temperature of from 0° C. to less than 80° C. to form a crosslinked polyurethane.

Abstract translation: 本发明提供了通过将a）流体形式的尿素加入到含有b）醇酸多元醇如短油或中油醇酸多元醇的反应介质中以形成反应混合物，然后通过以下方式氨基甲酰化醇酸树脂多元醇，制备聚氨酯的方法： 加热反应混合物同时将水送入反应混合物中，优选在一种或多种c）氨基甲酰化催化剂存在下进行。 当与多醛或其缩醛或半缩醛组合作为第二组分时，本发明的聚氨基甲酸酯形成基本上不含异氰酸酯的多组分组合物，并且在0℃至小于80℃的温度下固化。 以形成交联的聚氨酯。

公开(公告)号：US20150038670A1

公开(公告)日：2015-02-05

申请号：US13955507

申请日：2013-07-31

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, JR. ,  Paul Foley

IPC: C08G71/04

CPC classification number: C08G71/04 ,  C08G65/33303

Abstract: A first process to produce polycarbamate comprising providing urea in liquid form; and adding the liquid urea to a polyol is provided. A second process for producing polycarbamate comprising adding solid urea to a polyol in liquid form to form a reaction mixture is provided. Also provided is a reaction product produced by the first process or second process.

Abstract translation: 生产聚氨酯的第一种方法，包括提供液态尿素; 并提供液态尿素至多元醇。 提供了生产聚氨酯的第二种方法，其包括将固体尿素加入到液体形式的多元醇中以形成反应混合物。 还提供了通过第一工艺或第二工艺生产的反应产物。

公开(公告)号：US20150038669A1

公开(公告)日：2015-02-05

申请号：US13955612

申请日：2013-07-31

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  Ronald B. Leng

IPC: C08G71/04

CPC classification number: C08G71/04 ,  C08G63/668 ,  C08G63/6852 ,  C08G65/33303

Abstract: A process to produce polycarbamate comprising providing urea in liquid form; and adding the urea in liquid form to a polyol in a reduced gradient profile to form polycarbamate product is provided. Also provided are: (a) a reaction product of the process and (b) an apparatus for operating the process.

Abstract translation: 一种生产聚氨酯的方法，包括以液体形式提供尿素; 并提供液体形式的脲以减少的梯度曲线形式制成多元醇以形成聚氨酯。 还提供了：（a）该方法的反应产物和（b）用于操作该方法的装置。