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公开(公告)号：US20160145466A1
公开(公告)日：2016-05-26
申请号：US14900106
申请日：2014-06-18
发明人： Gary E. Spilman , Jeff R. Anderson , John N. Argyropoulos , Paul Foley , Xinrui Yu , John W. Hull , Congcong Lu , Daryoosh Beigzadeh
IPC分类号： C09D175/12
CPC分类号： C09D175/12 , C09D161/24 , C09D167/00 , C09D167/08 , C08L67/08
摘要： The instant invention provides a crosslinkable coating composition, and method of producing the same. The crosslinkable coating composition according to the present invention comprises: (a) one or more polycarbamates derived from one or more polyesters comprising the condensation reaction product of one or more polyols with one or more polyacids, wherein said one or more polyols comprise at least 25 percent by weight of one or more units having 4 or more hydroxyl groups; (b) one or more crosslinking agents; (c) one or more acid catalysts; and (d) optionally one or more organic solvents.
摘要翻译： 本发明提供一种可交联涂料组合物及其制备方法。 根据本发明的可交联涂料组合物包含：（a）一种或多种衍生自一种或多种聚酯的聚氨酯，其包含一种或多种多元醇与一种或多种多元酸的缩合反应产物，其中所述一种或多种多元醇包含至少25 一个或多个具有4个或更多个羟基的单元的重量百分比; （b）一种或多种交联剂; （c）一种或多种酸催化剂; 和（d）任选的一种或多种有机溶剂。
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2.发明申请CARBAMYLATION COMPOSITIONS OF MONOVALENT METAL CONTAINING CATALYSTS, POLYOLS AND UREA COMPOUNDS AND CARBAMYLATION PROCESSES USING THE SAME 审中-公开含有催化剂，多元醇和尿素化合物的单一金属的羰基化组合物和使用该化合物的羰基化方法公开(公告)号：US20160083517A1
公开(公告)日：2016-03-24
申请号：US14855426
申请日：2015-09-16
发明人： Daryoosh Beigzadeh , Thomas P. Clark , Paul Foley , Congcong Lu , Peter Margl , Duane R. Romer
IPC分类号： C08G73/00
CPC分类号： C08G73/00 , C08G71/04 , C08L33/066
摘要： The present invention provides carbamylation compositions of one or more urea compounds, one or more polyols and a monovalent transition metal or alkali metal catalyst (i), such as lithium ethylhexanoate, which compositions are substantially isocyanate free, enjoy reduced toxicity in comparison to tin catalysts, and which are useful in making polycarbamates which themselves provide compositions for making crosslinked polyurethanes.
摘要翻译： 本发明提供了一种或多种脲化合物，一种或多种多元醇和单价过渡金属或碱金属催化剂（ⅰ）的氨基甲酰化组合物，其中所述组合物基本上不含异氰酸酯，与锡催化剂相比具有降低的毒性 ，并且其可用于制备本身提供用于制备交联聚氨酯的组合物的聚氨酯。
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公开(公告)号：US09290675B2
公开(公告)日：2016-03-22
申请号：US13920343
申请日：2013-06-18
IPC分类号： C08L77/00 , C08G69/44 , C08G63/02 , C09D179/00 , C09D167/00 , C09D167/08
CPC分类号： C09D175/06 , C09D167/00 , C09D167/08 , C09D179/00
摘要： The instant invention provides a crosslinkable coating composition, and method of producing the same. The crosslinkable coating composition according to the present invention comprises: (a) one or more polycarbamates derived from one or more polyesters comprising the condensation reaction product of one or more polyols with one or more polyacids, wherein said one or more polyols comprise at least 25 percent by weight of one or more units having 4 or more hydroxyl groups; (b) one or more crosslinking agents; (c) one or more acid catalysts; and (d) optionally one or more organic solvents.
摘要翻译： 本发明提供一种可交联涂料组合物及其制备方法。 根据本发明的可交联涂料组合物包含：（a）一种或多种衍生自一种或多种聚酯的聚氨酯，其包含一种或多种多元醇与一种或多种多元酸的缩合反应产物，其中所述一种或多种多元醇包含至少25 一个或多个具有4个或更多个羟基的单元的重量百分比; （b）一种或多种交联剂; （c）一种或多种酸催化剂; 和（d）任选的一种或多种有机溶剂。
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公开(公告)号：US10604626B2
公开(公告)日：2020-03-31
申请号：US14908795
申请日：2014-07-28
发明人： Xinrui Yu , Yiyong He , John W. Hull, Jr. , Paul Foley
IPC分类号： C08G71/04
摘要： A first process to produce polycarbamate comprising providing urea in liquid form; and adding the liquid urea to a polyol is provided. A second process for producing polycarbamate comprising adding solid urea to a polyol in liquid form to form a reaction mixture is provided. Also provided is a reaction product produced by the first process or second process.
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公开(公告)号：US20170029590A1
公开(公告)日：2017-02-02
申请号：US15124230
申请日：2015-03-10
发明人： Paul Foley , Xin Jin , Mark F. Sonnenschein , Nicole L. Wagner , Chaofang Yue
IPC分类号： C08J9/14 , C08G65/333 , C08J3/24
CPC分类号： C08J9/146 , C08G8/38 , C08G65/333 , C08G65/33344 , C08G2650/50 , C08J3/24 , C08J9/14 , C08J2201/026 , C08J2203/142 , C08J2205/05 , C08J2205/10 , C08J2361/20 , C08J2361/22 , C08L61/20 , C08L71/02 , C08L2203/14
摘要： A biodegradable crosslinked polymer which is a reaction product of a polymer having aldehyde-reactive functional groups and a polyaldehyde, wherein the polymer having aldehyde-reactive functional groups comprises a biodegradable structure or the polyaldehyde comprises a biodegradable structure.
摘要翻译： 一种可生物降解的交联聚合物，其是具有醛反应性官能团和聚醛的聚合物的反应产物，其中具有醛反应性官能团的聚合物包括可生物降解的结构，或多醛包括可生物降解的结构。
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公开(公告)号：US20140369850A1
公开(公告)日：2014-12-18
申请号：US13920341
申请日：2013-06-18
发明人： Paul J. Popa , Ben W. Schaefer , John N. Argyropoulos , Kenneth E. Wohltmann , Sandra Hofmann , Daniel Haile , Paul Foley , YanXiang Li
IPC分类号： C09D133/08 , F03D1/06 , B64C27/46 , F01D5/28
CPC分类号： B64C27/46 , C08G12/46 , C08K5/07 , C09D133/10 , C09D161/20 , F01D5/288 , F05B2280/6011 , F05D2300/43 , Y02E10/721 , Y02T50/672 , C09D133/14 , C08F2220/1825 , C08F220/20 , C08F2220/1858 , C08F220/14 , C08F2220/1875 , C08F220/06
摘要： The instant invention provides cross-linkable coating compositions, process for producing the same, and substrates coated therewith. The cross-linkable coating composition comprises: (a) polyaldehyde, or acetal or hemiacetal thereof; (b) an acid catalyst having pKa of less than 6; (c) a liquid media; (d) an acrylic polycarbamate comprising at least an average of 2.0 carbamate functional groups, wherein said polycarbamate has a glass transition (Tg) of less than 25° C.; and (e) one or more fillers having a pH in the range of equal to or less than 9 and/or one or more pigments having a pH in the range of equal to or less than 9, and/or one or more additives having a pH in the range of equal to or less than 9, wherein said composition has a curing temperature in the range of less than 70° C.
摘要翻译： 本发明提供了可交联的涂料组合物，其制备方法和用其涂布的基材。 可交联涂料组合物包含：（a）多醛，或其缩醛或半缩醛; （b）pKa小于6的酸催化剂; （c）液体介质; （d）包含至少平均2.0个氨基甲酸酯官能团的丙烯酸聚氨酯，其中所述聚氨酯具有小于25℃的玻璃化转变温度（Tg）。 和（e）一种或多种pH值在等于或小于9的范围内的一种或多种填料和/或一种或多种pH值在等于或小于9的范围内的颜料，和/或一种或多种添加剂具有 pH在等于或小于9的范围内，其中所述组合物的固化温度在小于70℃的范围内。
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公开(公告)号：US20130172472A1
公开(公告)日：2013-07-04
申请号：US13728037
申请日：2012-12-27
发明人： Eric Greyson , John N. Argyropouls , Paul Foley , Andrew Swartz , Nahrain E. Kamber , Caroline Slone , Manesh N. Sekharan
CPC分类号： C09D133/14 , C08L61/02 , C08L75/14 , C09D175/04
摘要： The instant invention provides a crosslinkable aqueous composition, method of producing the same, crosslinked compositions, and method of producing the same. The crosslinkable composition comprising: an aqueous dispersion comprising; (a) water; (b) a polycarbamate comprising at least an average of 2.0 carbamate functional groups; (c) a polyaldehyde comprising at least two aldehyde groups; (d) an acid catalyst; and (e) optionally one or more surfactants; wherein said aqueous dispersion has a pH in the range of less than 7; and wherein said composition is capable of being crosslinked at a temperature in range of less than 80° C. upon substantial removal of water.
摘要翻译： 本发明提供了一种可交联水性组合物，其制备方法，交联组合物及其制备方法。 所述可交联组合物包含：水分散体，其包含： （一杯水; （b）包含至少平均2.0个氨基甲酸酯官能团的聚氨酯; （c）包含至少两个醛基的多醛; （d）酸催化剂; 和（e）任选的一种或多种表面活性剂; 其中所述水性分散体的pH值在小于7的范围内; 并且其中所述组合物能够在基本除去水后在低于80℃的温度范围内交联。
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公开(公告)号：US20180009947A1
公开(公告)日：2018-01-11
申请号：US15712181
申请日：2017-09-22
发明人： Xinrui Yu , Yiyong He , John W. Hull, JR. , Paul Foley
IPC分类号： C08G71/04 , C08G65/333
CPC分类号： C08G71/04 , C08G65/33303
摘要： A first process to produce polycarbamate comprising providing urea in liquid form; and adding the liquid urea to a polyol is provided. A second process for producing polycarbamate comprising adding solid urea to a polyol in liquid form to form a reaction mixture is provided. Also provided is a reaction product produced by the first process or second process.
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公开(公告)号：US09783650B2
公开(公告)日：2017-10-10
申请号：US15124230
申请日：2015-03-10
发明人： Paul Foley , Xin Jin , Mark F. Sonnenschein , Nicole L. Wagner , Chaofang Yue
CPC分类号： C08J9/146 , C08G8/38 , C08G65/333 , C08G65/33344 , C08G2650/50 , C08J3/24 , C08J9/14 , C08J2201/026 , C08J2203/142 , C08J2205/05 , C08J2205/10 , C08J2361/20 , C08J2361/22 , C08L61/20 , C08L71/02 , C08L2203/14
摘要： A biodegradable crosslinked polymer which is a reaction product of a polymer having aldehyde-reactive functional groups and a polyaldehyde, wherein the polymer having aldehyde-reactive functional groups comprises a biodegradable structure or the polyaldehyde comprises a biodegradable structure.
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公开(公告)号：US09695335B2
公开(公告)日：2017-07-04
申请号：US14734205
申请日：2015-06-09
发明人： John N. Argyropoulos , Paul Foley , Eric Greyson , Jeff R. Anderson , Gary E. Spilman , Caroline Slone , Nahrain E. Kamber
IPC分类号： C08G63/91 , C09D135/02 , C09D167/08 , C08F22/10 , C08G63/12 , C09J133/06
CPC分类号： C09D167/08 , C08F22/10 , C08G63/12 , C08G63/914 , C08L2312/00 , C09D135/02 , C09J133/066
摘要： The instant invention provides crosslinkable compositions, and method of producing the same. The non-aqueous single phase crosslinkable composition comprises: (a) a polyol having an average of 2 or more hydroxyl functional groups; (b) polyaldehyde, or acetal or hemiacetal thereof; and (c) an acid catalyst having pK of less than 6; and (d) optionally one or more organic solvents.
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