摘要:
In a process for selectively separating 1-butene from a C4 feed stream comprising at least 1-butene, cis-2-butene and trans-2-butene, the feed stream is passed through a first bed of an adsorbent comprising a crystalline microporous material to form a substantially trans-2-butene-free effluent stream. Then, the substantially trans-2-butene-free effluent stream is passed through a second bed of an adsorbent comprising a crystalline microporous material to form a substantially 1-butene-free effluent stream, whereby the 1-butene is separated from the feed stream. The adsorbed 1-butene is then typically desorbed from the second adsorbent bed either by lowering the pressure or raising the temperature of the bed.
摘要翻译:在从包含至少1-丁烯,顺式-2-丁烯和反式-2-丁烯的C 4 H 4进料流中选择性分离1-丁烯的方法中,使进料流通过第一床 的吸附剂,其包含结晶微孔材料以形成基本上反式-2-丁烯的流出物流。 然后,将基本上反式-2-丁烯的流出物流通过包含结晶微孔材料的吸附剂的第二床,以形成基本上不含1-丁烯的流出物流,由此从进料流中分离出1-丁烯 。 吸附的1-丁烯通常通过降低压力或升高床的温度而从第二吸附剂床解吸。
摘要:
The identification, synthesis, and use of an isomorphously substituted molecular sieve material having structural frameworks substituted with a preselected substitution element for a framework element of the molecular sieve material can result in a preferred transport controlling window size range for the optimal separation of a target gas component from a gaseous mixture containing said target gas component.