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    Synthesis of dihydroxy-terminated poly(2,2,3,3,4,4-hexafluoropentane-1,5-diol formal)
    31.
    发明授权
    Synthesis of dihydroxy-terminated poly(2,2,3,3,4,4-hexafluoropentane-1,5-diol formal) 失效
    合成二羟基封端的聚（2,2,3,3,4,4-六氟戊烷-1,5-二醇缩甲醛）

    公开(公告)号：US4740579A

    公开(公告)日：1988-04-26

    申请号：US52503

    申请日：1987-05-05

    Applicant: Judah M. Goldwasser ,  Horst G. Adolph

    Inventor： Judah M. Goldwasser ,  Horst G. Adolph

    IPC: C07D321/12 ,  C08G4/00 ,  C08G10/02 ,  C08G73/24

    CPC classification number: C08G4/00 ,  C07D321/12

    Abstract: A method of producing dihydroxy-terminated poly(2,2,3,3,4,4-hexafluoropene-1,5-diol formal) of a desired number average molecular weight by controlling the relative amounts of 1,3-dioxa-5,5,6,6,7,7-hexafluorocyclooctane monomer, 2,2,3,3,4,4-hexafluoropentane-1,5-diol, and the catalyst trifluoromethane sulfonic acid (having a determined activity) used to produce the polymer.

    Abstract translation: 通过控制1,3-二氧杂环戊烯-5-酮的相对量，制备具有所需数均分子量的二羟基封端的聚（2,2,3,3,4,4-六氟戊烷-1,5-二醇缩甲醛） ，5,6,6,7,7-六氟环辛烷单体，2,2,3,3,4,4-六氟戊烷-1,5-二醇和用于制备所述三氯甲烷磺酸（具有确定的活性）的催化剂 聚合物。

    Acetals derived from negatively substituted aldehydes and polynitro- or halonitroethanols
    32.
    发明授权
    Acetals derived from negatively substituted aldehydes and polynitro- or halonitroethanols 失效
    衍生自负取代醛和多硝基或卤代硝基乙醇的缩醛

    公开(公告)号：US3946085A

    公开(公告)日：1976-03-23

    申请号：US461554

    申请日：1974-04-17

    Applicant: Horst G. Adolph

    Inventor： Horst G. Adolph

    IPC: C06B43/00 ,  C07C205/29 ,  C07C205/40 ,  C07C205/51 ,  C07C43/30

    CPC classification number: C06B43/00 ,  C07C205/29 ,  C07C205/40 ,  C07C205/51

    Abstract: Acetals of the formulas CHCl.sub.2 CH(OR).sub.2, CCl.sub.3 CH(OR).sub.2, .sub.2 CH(OR).sub.2, CF.sub.3 CH(OR).sub.2, RO.sub.2 CCH(OR).sub.2, and (RO).sub.2 HCCH(OR).sub.2 wherein R can be --CH.sub.2 CYZ(NO.sub.2), --CH.sub.2 CH.sub.2 CYZ(NO.sub.2), --CH.sub.2 C(NO.sub.2).sub.2 CH.sub.3, --CH.sub.2 C(NO.sub.2).sub.2 CYZ(NO.sub.2), --CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 CYZ(NO.sub.2) or --CH.sub.2 C(NO.sub.2).sub.2 C(NO.sub.2).sub.2 CYZ(NO.sub. 2) wherein Y and Z vary independently and can be Cl, F or NO.sub.2. These acetals are produced by contacting a negatively substituted aldehyde such as CHCl.sub.2 CHO, CCl.sub.3 CHO, CHF.sub.2 CHO, CF.sub.3 CHO, HO.sub.2 CCHO, or OHCCHO with a negatively substitute alcohol of the formula ROH wherein R is as defined above. Either FSO.sub.3 H, ClSO.sub.3 H, or CHF.sub.2 SO.sub.3 H, or CF.sub.3 SO.sub.3 H is used to catalyze the condensation. The acetals of this invention are useful as explosives.

    Abstract translation: 式CHCl 2 CH（OR）2，CCl 3 CH（OR）2，CHF 2 CH（OR）2，CF 3 CH（OR）2，RO 2 CCH（OR）2和（RO）2 HCH（OR）2）的缩醛，其中R可以是-CH 2 CYZ NO2），-CH2CH2CYZ（NO2），-CH2C（NO2）2CH3，-CH2C（NO2）2CYZ（NO2），-CH2C（NO2）2CH2CYZ（NO2）或-CH2C（NO2）2C（NO2） 其中Y和Z独立地变化，并且可以是Cl，F或NO2。 这些缩醛通过使负取代的醛如CHCl 2 CHO，CCl 3 CHO，CHF 2 CHO，CF 3 CHO，HO 2 CCHO或OHCCHO与式ROH的负取代醇接触来制备，其中R如上所定义。 使用FSO 3 H，ClSO 3 H或CHF 2 SO 3 H或CF 3 SO 3 H来催化冷凝。 本发明的缩醛作为炸药是有用的。

    Process for synthesizing 1,5 dinosyl-3,3,7,7-tetrakis(difluoramino)octahydro-1,5-diazocine (DNTDFD)
    33.
    发明授权
    Process for synthesizing 1,5 dinosyl-3,3,7,7-tetrakis(difluoramino)octahydro-1,5-diazocine (DNTDFD) 失效
    合成1,5二糖基-3,3,7,7-四（二氟氨基）八氢-1,5-二氮辛（DNTDFD）

    公开(公告)号：US07145003B1

    公开(公告)日：2006-12-05

    申请号：US10719856

    申请日：2003-11-24

    Applicant: Horst G. Adolph ,  Alfred G. Stern

    Inventor： Horst G. Adolph ,  Alfred G. Stern

    IPC: C07D245/02

    CPC classification number: C07D247/00

    Abstract: A process for synthesizing 1,5-Dinosyl-3,3,7,7-tetrakis(difluoramino) octahydro-1,5-diazocine (DNTDFD) by reacting tetrahydro-1,5-bis(4-nitrobenzenesulfonyl)-1,5-diazocine-3,7-(2H, 6H) dione with HNF2/oleum initially approximately between −5 and 0 degrees C., and allowing the temperature to rise to between 10 degrees C. and ambient temperature during said reaction to initiate difluoramination producing product DNTDFD. A 2:1 mixture of FREON® 11 refrigerant and pentane or cyclopentane, or pentane alone is used as a diluent and absorbent for the reagent difluoramine. The present invention reduces the time required to produce DNTDFD from about two weeks to one to three days and reduces the need to use relatively large quantities of FREON® 11, a compound which is damaging to the environment.

    Abstract translation: 通过使四氢-1,5-双（4-硝基苯磺酰基）-1,5,5-二氢-1,5-二氮杂（DNTDFD）合成1,5-二脒基-3,3,7,7-四（二氟氨基） （2H，6H）二酮，HNF2 /发烟硫酸最初约为-5至0摄氏度，并允许温度升高至10摄氏度与环境温度在所述反应期间引发二氟化物产生 产品DNTDFD。 作为稀释剂和试剂二氟胺的吸收剂，使用FREON（11）制冷剂与戊烷或环戊烷或戊烷的2:1混合物。 本发明将生产DNTDFD所需的时间从约两周减少到一至三天，并且减少了使用相对大量的对环境有害的化合物的需求。

    Modified polybutadiene polymers that are both chemically degradable and physically compatible with energetic plasticizers for use in propellant and explosive binders
    34.
    发明授权
    Modified polybutadiene polymers that are both chemically degradable and physically compatible with energetic plasticizers for use in propellant and explosive binders 失效
    改性的聚丁二烯聚合物既可化学降解，又与能量增塑剂物理相容，用于推进剂和爆炸性粘合剂

    公开(公告)号：US06783613B1

    公开(公告)日：2004-08-31

    申请号：US10118616

    申请日：2002-04-04

    Applicant: Robert C. Gill ,  Horst G. Adolph

    Inventor： Robert C. Gill ,  Horst G. Adolph

    IPC: C06B4510

    CPC classification number: C06B45/105 ,  C06B45/10

    Abstract: The present invention is a modified HFPB polymer for use in propellants and explosives that is chemically degradable and also is compatible with commonly used energetic plasticizers. The HFPB polymer of the present invention contains ester linkages formed in the backbone of the polymer from a dicarboxylic acid containing either oxymeythylene or oxyethylene moeities. The ester and ether linkages change the polarity of the polybutadiene to make it compatible with polar energetic plasticizers. The ester linkages along with either oxymethylene or oxyethylene moeities make the polymer degradable to basic solutions while still maintaining the structural integrity necessary for a polybutadiene type binder.

    Abstract translation: 本发明是一种用于推进剂和爆炸物的改性HFPB聚合物，其具有化学降解性，并且与常用的能量增塑剂相容。 本发明的HFPB聚合物含有由含有氧基乙烯或氧乙烯的二羧酸的聚合物主链中形成的酯键。 酯和醚键改变聚丁二烯的极性，使其与极性能量增塑剂相容。 酯键与氧亚甲基或氧乙烯聚合物一起使得聚合物可降解成碱性溶液，同时仍保持聚丁二烯型粘合剂所必需的结构完整性。

    Energetic melt cast explosives
    35.
    发明授权
    Energetic melt cast explosives 失效
    精力充沛的熔铸炸药

    公开(公告)号：US5949016A

    公开(公告)日：1999-09-07

    申请号：US737522

    申请日：1991-07-29

    Applicant: Edward E. Baroody ,  Carl Gotzmer ,  Horst G. Adolph

    Inventor： Edward E. Baroody ,  Carl Gotzmer ,  Horst G. Adolph

    IPC: C06B21/00 ,  C06B33/08 ,  C06B45/10

    CPC classification number: C06B33/08 ,  C06B21/005

    Abstract: A melt cast explosive containing bis(2,2-dinitropropyl)fumarate or 2,2-diropropyl-4,4-dinitropentanoate and a metal fuel such as aluminum, magnesium, boron, hafnium, zirconium or alloys or mixtures thereof. An inert thermoplastic elastomer diluent may be added to improve the strength of the explosive.

    Abstract translation: 含有富马酸二（2,2-二硝基丙酯）或2,2-二硝基丙基-4,4-二硝基戊酸酯的熔融铸造炸药和金属燃料如铝，镁，硼，铪，锆或其合金或其混合物。 可以加入惰性热塑性弹性体稀释剂以提高爆炸物的强度。

    Copolyformals of 1,2-bis(2-hydroxyethyl)-1,2-dicarbadodecaborane and polynitroalkyl diols
    36.
    依法登记的发明
    Copolyformals of 1,2-bis(2-hydroxyethyl)-1,2-dicarbadodecaborane and polynitroalkyl diols 失效
    1,2-BIS（2-羟基乙基）-1,2-二胺十二烷和多羟基烷基二醇的共聚物

    公开(公告)号：USH786H

    公开(公告)日：1990-06-05

    申请号：US389239

    申请日：1989-08-02

    Applicant: Horst G. Adolph ,  Lori A. Nock

    Inventor： Horst G. Adolph ,  Lori A. Nock

    IPC: C08G4/00

    CPC classification number: C08G4/00

    Abstract: Dihydroxy-terminated copolyformals formed fromA. formaldehyde andB. a diol comonomer mixture of(1) 1,2-bis(2-hydroxyethyl)-1,2-dicarbadodecaborane(12) and(2) a nitrodiol which is HOCH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 CH.sub.2 , HOCH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 CH.sub.2 OH, HOCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 CH.sub.2 OH, or mixtures thereof. A fraction of the nitrodiol may be replaced with an equal number of moles of a fluorodiol which is HOCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH, HOCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH, HOCH.sub.2 CF(CF.sub.3)OCF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH, or mixtures thereof.

    Copolyformals of 1,2-bis(2-hydroxyethyl)-1,2-dicarbadodecaborane(12) and polyfluoroalkyl diols
    37.
    依法登记的发明
    Copolyformals of 1,2-bis(2-hydroxyethyl)-1,2-dicarbadodecaborane(12) and polyfluoroalkyl diols 失效
    1,2-双（2-羟基乙基）-1,2-二胺十二硼烷（12）和聚氟代醇二醇的共聚物

    公开(公告)号：USH784H

    公开(公告)日：1990-06-05

    申请号：US389217

    申请日：1989-08-02

    Applicant: Horst G. Adolph ,  Lori A. Nock

    Inventor： Horst G. Adolph ,  Lori A. Nock

    IPC: C08G4/00 ,  C08G6/00

    CPC classification number: C08G4/00

    Abstract: Dihydroxy-terminated copolyformals formed fromA. formaldehyde andB. a diol comonomer mixture of(1) 1,2-bis(2-hydroxyethyl)-1,2-dicarbadodecaborane(12) and(2) a fluorodiol which is HOCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 HOCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH, HOCH.sub.2 CF(CF.sub.3)OCF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH, HOCH.sub.2 CF.sub.2 OCF.sub.2 CF.sub.2 OCF.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.2 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.4 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.6 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.8 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.10 CH.sub.2 CH.sub.2 OH, or mixtures thereof. A fraction of the fluorodiol may be replaced with an equal number of moles of a suitable nitrodiol.

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