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公开(公告)号:US20240117109A1
公开(公告)日:2024-04-11
申请号:US18262143
申请日:2022-01-19
Applicant: KYOCERA Document Solutions Inc.
Inventor: Jun AZUMA , Keiji MARUO , Kenji KITAGUCHI
IPC: C08G63/187 , G03G5/043 , G03G15/00
CPC classification number: C08G63/187 , G03G5/043 , G03G15/6597 , G03G2215/00518
Abstract: A polyarylate resin includes repeating units represented by formulas (1), (2), (3), and (4). A percentage of the number of repeats of the repeating unit represented by formula (3) relative to the total number of repeats of the respective repeating units represented by formulas (1) and (3) is greater than 0% and less than 20%. In formula (1), R1 and R2 each represent, independently of one another, a hydrogen atom or a methyl group and X represents a divalent group represented by formula (X1) or (X2). In formula (2), W represents, a divalent group represented by formula (W1) or (W2).
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32.
公开(公告)号:US20200233324A1
公开(公告)日:2020-07-23
申请号:US16740196
申请日:2020-01-10
Applicant: KYOCERA Document Solutions Inc.
Inventor: Tomofumi SHIMIZU , Kazuaki EZURE , Hayase YAMAMOTO , Jun AZUMA
Abstract: A photosensitive layer included in an electrophotographic photosensitive member contains at least a charge generating material, a hole transport material, and a binder resin. The hole transport material includes a compound (1). The binder resin includes a polyarylate resin having at least one repeating unit (10) and at least one repeating unit (11). Alternatively, the binder resin includes a polycarbonate resin having a repeating unit (20) and a repeating unit (21). The general formulas (1), (10), (11), (20), and (21) are as follows
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公开(公告)号:US20200233321A1
公开(公告)日:2020-07-23
申请号:US16746274
申请日:2020-01-17
Applicant: KYOCERA Document Solutions Inc.
Inventor: Kazutaka SUGIMOTO , Kensuke OKAWA , Jun AZUMA
Abstract: An electrophotographic photosensitive member includes a conductive substrate, a charge generating layer, and a charge transport layer. The charge generating layer has a thickness of at least 0.07 μm. The charge transport layer contains a binder resin, a hole transport material, and meta-terphenyl. The binder resin includes a polyarylate resin including repeating units and a group represented by respective general formulas (1) to (3). The electrophotographic photosensitive member satisfies at least two conditions of: (A) the charge generating layer has a thickness of at least 0.12 μm; (B) the charge transport layer contains a specific amount of fluororesin particles; and (C) the charge transport layer contains meta-terphenyl in an amount of at least 5.0 parts by mass and no greater than 15.0 parts by mass relative to 100 parts by mass of the binder resin.
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公开(公告)号:US20200026207A1
公开(公告)日:2020-01-23
申请号:US16496487
申请日:2017-12-28
Applicant: KYOCERA Document Solutions Inc.
Inventor: Kensuke OKAWA , Seiki HASUNUMA , Jun AZUMA
Abstract: An electrophotographic photosensitive member (1) includes a conductive substrate (2) and a photosensitive layer (3) disposed directly or indirectly on the conductive substrate (2). The photosensitive layer (3) has a charge generating layer (3a) and a charge transport layer (3b) disposed in order from the conductive substrate (2). The charge generating layer (3a) contains a charge generating material. The charge transport layer (3b) contains a charge transport material, a binder resin, and a pigment that absorbs light having an irradiation wavelength. The binder resin includes a polyarylate resin including a repeating unit represented by general formula (1): In general formula (1), X and Y each represent, independently of one another, a divalent group represented by chemical formula (1-1). (1-2), (1-3), or (1-4): The pigment is a naphthalocyanine compound represented by general formula (2) or (3):
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公开(公告)号:US20190354029A1
公开(公告)日:2019-11-21
申请号:US16411173
申请日:2019-05-14
Applicant: KYOCERA Document Solutions Inc.
Inventor: Jun AZUMA , Tomofumi SHIMIZU , Kenji KITAGUCHI , Kiichiro OJI
Abstract: A method for producing an electrophotographic photosensitive member includes an electrically conductive substrate and a photosensitive layer. The method includes applying an application liquid for photosensitive layer formation containing a solvent, a binder resin, and a hole transport material directly or indirectly onto the electrically conductive substrate, and removing a portion of the solvent, to form the photosensitive layer. The solvent contains a first solvent that is an alcohol having a carbon number of at least 1 and no greater than 3, and a second solvent other than the first solvent. The binder resin includes a polyarylate resin that is a polymerization product of monomers including a first monomer represented by general formula (1) and a second monomer represented by general formula (2),
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公开(公告)号:US20190270846A1
公开(公告)日:2019-09-05
申请号:US16461221
申请日:2017-09-25
Applicant: KYOCERA Document Solutions Inc.
Inventor: Jun AZUMA , Kenji KITAGUCHI
IPC: C08G63/181 , C08G63/193 , G03G5/06 , G03G5/05
Abstract: A polyarylate resin is represented by general formula (1) shown below. In general formula (1), R1, R2, R3, and R4 each represent, independently of one another, a hydrogen atom or a methyl group. r and s each represent an integer of at least 0 and no greater than 49. t and u each represent an integer of at least 1 and no greater than 50. r+s+t+u=100. r+t=s+u. r and t may be the same as or different from each other. s and u may be the same as or different from each other. X represents a divalent group represented by chemical formula (2A), (2B), (2C), or (2D). Y represents a divalent group represented by chemical formula (4A), c (4B), or (4C). X and Y are different from each other.
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公开(公告)号:US20180148538A1
公开(公告)日:2018-05-31
申请号:US15824745
申请日:2017-11-28
Applicant: KYOCERA Document Solutions Inc.
Inventor: Jun AZUMA , Kenji KITAGUCHI , Kensuke OKAWA , Seiki HASUNUMA , Tomofumi SHIMIZU
IPC: C08G63/19 , C08G63/181 , C08L67/02 , G03G5/05
CPC classification number: C08G63/19 , C08G63/181 , C08L67/025 , C08L2203/16 , G03G5/056 , G03G5/0567 , G03G5/0614 , G03G5/0672
Abstract: A polyarylate resin is represented by general formula (1) shown below. In general formula (1), R1 and R2 each represent, independently of one another, a hydrogen atom or a methyl group. r and s each represent an integer of at least 0 and no greater than 49. t and u each represent an integer of at least 1 and no greater than 50. r+s+t+u=100. r+t=s+u. X and Y each represent, independently of one another, a divalent group represented by chemical formula (1-1), chemical formula (1-2), chemical formula (1-3), or chemical formula (1-4). X and Y are different from one another.
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38.
公开(公告)号:US20180046100A1
公开(公告)日:2018-02-15
申请号:US15668774
申请日:2017-08-04
Applicant: KYOCERA Document Solutions Inc.
Inventor: Keiji MARUO , Tomofumi SHIMIZU , Jun AZUMA
CPC classification number: G03G5/056 , G03G5/0609 , G03G5/0614 , G03G5/0616 , G03G5/0668 , G03G5/0672 , G03G5/0696 , G03G5/102 , G03G15/75
Abstract: An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer is a single-layer photosensitive layer. The photosensitive layer contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The binder resin contains a polyarylate resin. The polyatylate resin is represented by general formula (1). The hole transport material contains a compound represented by general formula (HTM1), (HTM2), (HTM3), (HTM4), (HTM5), (HTM6), or (HTM7). The photosensitive layer has a scratch resistance depth of no greater than 0.50 μm. The photosensitive layer has a Vickers hardness of at least 17.0 HV.
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公开(公告)号:US20180046099A1
公开(公告)日:2018-02-15
申请号:US15668759
申请日:2017-08-04
Applicant: KYOCERA Document Solutions Inc.
Inventor: Jun AZUMA , Kensuke OKAWA , Seiki HASUNUMA , Tomofumi SHIMIZU
Abstract: An electrophotographic photosensitive member includes a photosensitive layer. The photosensitive layer contains a charge generating material, a hole transport material, and a binder resin. The binder resin contains a polyarylate resin represented by general formula (1). In general formula (1), r and s each represent an integer of at least 0 and no greater than 49 and t and u represents an integer of at least 1 and no greater than 50. Furthermore, r+s+t+u=100 and r+t=s+u. X and Y each represent, independently of one another, a divalent group represented by chemical formula (1-1), (1-2), (1-3), or (1-4).
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公开(公告)号:US20170131647A1
公开(公告)日:2017-05-11
申请号:US15345726
申请日:2016-11-08
Applicant: KYOCERA Document Solutions Inc.
Inventor: Kensuke OKAWA , Hideki OKADA , Jun AZUMA , Fumio SUGAI , Kensuke KOJIMA
IPC: G03G5/06 , C07C211/54
CPC classification number: G03G5/0612 , C07C211/54 , C07C217/92 , G03G5/0525 , G03G5/0567 , G03G5/0609 , G03G5/0614 , G03G5/0618 , G03G5/0672 , G03G5/0696
Abstract: A triarylamine derivative represented by general formula (1) below. In the general formula (1), R1, R2, R4, R5, R6, R7, R8, and R9 each represent, independently from one another, a hydrogen atom, an optionally substitute alkyl group having a carbon number of at least 1 and no greater than 6, an optionally substituted alkoxy group having a carbon number of at least 1 and no greater than 6, or an optionally substituted aryl group having a carbon number of at least 6 and no greater than 14, R3 represents an alkyl group having a carbon number of at least 1 and no greater than 4, X represents an alkylene group having a carbon number of at least 1 and no greater than 6 or an oxygen atom, and n represents an integer of 1 to 3.
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