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公开(公告)号:US20230141498A1
公开(公告)日:2023-05-11
申请号:US17794076
申请日:2021-01-21
Inventor: Kazuko Asano , Yukihiro Oki , Nanami Takeda , Mitsuhiro Hibino
IPC: H01M4/38 , H01M10/0525 , H01M4/62
CPC classification number: H01M4/387 , H01M4/622 , H01M10/0525 , H01M2004/027
Abstract: Provided is a lithium ion battery with a positive electrode having a positive electrode mixture layer that contains a positive electrode active material, and a negative electrode having a negative electrode mixture layer that contains a negative electrode active material, the lithium ion battery being charged and discharged by the movement of lithium ions between the positive electrode and the negative electrode. The negative electrode mixture layer contains a negative electrode active material represented by general formula M3Me2X7 (in the formula, M includes at least one of La and Ca; Me includes at least one of Mn, Ni, Fe, and Co; and X includes at least one of Ge, Si, Sn, and Al), and a binding agent that contains cyano groups, the ratio of the binding agent in the negative electrode mixture layer being 0.5-7.0 mass% (inclusive).
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公开(公告)号:US20230100030A1
公开(公告)日:2023-03-30
申请号:US17800768
申请日:2021-02-25
Inventor: Kazuko Asano , Yukihiro Oki , Nanami Takeda , Mitsuhiro Hibino
IPC: H01M4/38 , H01M10/0525
Abstract: The present invention provides a lithium ion battery which comprises a positive electrode having a positive electrode mixture layer that contains a positive electrode active material, and a negative electrode having a negative electrode mixture layer that contains a negative electrode active material, and which is charged and discharged by the movement of lithium ions between the positive electrode and the negative electrode. The negative electrode mixture layer contains a negative electrode active material represented by general formula La3(1-x)M3xNi2(1-y)Me2yX7 (wherein M contains at least one of Ca, Mg and Sr; Me contains at least one of Mn, Co, Cu and Fe; X contains at least one of Ge, Si, Sn and Al; 0.1≤x
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公开(公告)号:US20230082835A1
公开(公告)日:2023-03-16
申请号:US17800359
申请日:2021-01-21
Inventor: Youshin Lee , Ryuichi Natsui , Mitsuhiro Hibino , Kensuke Nakura
Abstract: This positive-electrode active material for a non-aqueous electrolyte secondary battery contains a lithium and transition metal composite oxide represented by the composition formula: LixMnyNizSraMbO2-cFc (where, M is at least two elements selected from Ti, Co, Si, Al, Nb, W, Mo, P, Ca, Mg, Sb, Na, B, V, Cr, Fe, Cu, Zn, Ge, Zr, Ru, K, and Bi; 1.0
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公开(公告)号:US20230045802A1
公开(公告)日:2023-02-16
申请号:US17792962
申请日:2021-01-26
Inventor: Jin Zhang , Issei Ikeuchi , Mitsuhiro Hibino , Kensuke Nakura
IPC: H01M4/525 , H01M4/505 , H01M4/485 , H01M50/46 , H01M10/0525
Abstract: This positive electrode active substance for a non-aqueous electrolyte secondary battery contains a lithium-transition metal composite oxide which has a crystal structure belonging to the space group Fm-3m and is represented by the compositional formula LixMnyMaObFc (in the formula: M is at least one type of metal element excluding Mn; x+y+a=b+c=2; 1
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公开(公告)号:US20220376244A1
公开(公告)日:2022-11-24
申请号:US17772409
申请日:2020-10-13
Inventor: Kosuke Kuroda , Mitsuhiro Hibino
IPC: H01M4/525 , H01M4/485 , H01M4/505 , H01M10/0525
Abstract: The positive electrode active material for a secondary battery includes a lithium-transition metal composite oxide. The lithium-transition metal composite oxide is represented by the general formula Liα[LixMnyCozMe(1−x−y−z)]O2 (in the formula, Me is at least one selected from Ni, Fe, Ti, Bi, and Nb, 0.5
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公开(公告)号:US20220344644A1
公开(公告)日:2022-10-27
申请号:US17763930
申请日:2020-09-29
Inventor: Hiroshi Kawada , Mitsuhiro Hibino
Abstract: A positive electrode active material for nonaqueous electrolyte secondary batteries according to the present invention comprises: a lithium transition metal composite oxide which has a spinel structure; and a coating layer which is provided on the surface of the lithium transition metal composite oxide, while having a spinel structure, and which contains Li but does not contain Mn.
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公开(公告)号:US20250140820A1
公开(公告)日:2025-05-01
申请号:US18681201
申请日:2022-06-10
Inventor: Kazuko Asano , Yukihiro Oki , Mitsuhiro Hibino , Nanami Takeda
IPC: H01M4/38 , H01M4/02 , H01M4/134 , H01M10/0525
Abstract: The negative electrode active material is represented by general formula M3Me2X7 (where: M includes La and/or Ca; Me includes at least one element selected from the group consisting of Mn, Ni, Fe and Co; X includes at least one element selected from the group consisting of Ge, Si, Sn, and Al). The dislocation density of the negative electrode active material is at least 1×1015 cm−2.
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公开(公告)号:US12283692B2
公开(公告)日:2025-04-22
申请号:US17763987
申请日:2020-09-29
Inventor: Hiroshi Kawada , Akiko Murata , Mitsuhiro Hibino
Abstract: This positive electrode active material for nonaqueous electrolyte secondary batteries includes a lithium transition metal complex oxide that has a spinel structure and that is represented by general formula Li1+αNi0.5-xMn1.5-y-zGeyMx+zO4 (in the formula, 0≤α
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公开(公告)号:US20250105274A1
公开(公告)日:2025-03-27
申请号:US18724795
申请日:2022-10-31
Inventor: Youshin Lee , Mitsuhiro Hibino , Kensuke Nakura
IPC: H01M4/525 , H01M4/02 , H01M4/04 , H01M10/0525
Abstract: This positive electrode comprises a positive electrode current collector, and a positive electrode mixture layer disposed on the positive electrode current collector, wherein: the positive electrode mixture layer has a positive electrode active material containing a lithium-containing composite oxide composed of secondary particles in which primary particles are aggregated; the lithium-containing composite oxide has a Nb element; the average particle diameter of the primary particles is 1 μm or less; and in a depth profile obtained by time-of-flight secondary ion mass spectrometry (TOF-SIMS) of a cross-section of the positive electrode mixture layer, when the minimum ionic strength of Nb in the region from the surface of the positive electrode mixture layer to 500 nm in the thickness direction is Imin and the maximum ionic strength of Nb in a region from 500 nm to 1000 nm in the thickness direction is Imax, Imax/Imin is at least 1.5.
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公开(公告)号:US20240282946A1
公开(公告)日:2024-08-22
申请号:US18681158
申请日:2022-06-14
Inventor: Kazuko Asano , Yukihiro Oki , Nanami Takeda , Mitsuhiro Hibino
CPC classification number: H01M4/387 , C22C1/02 , C22C13/00 , H01M4/134 , H01M10/0525 , H01M2004/027
Abstract: A negative electrode active material is represented by general formula M3Me2X7 (wherein M comprises at least one of La and Ca; Me comprises at least one element that is selected from the group consisting of Mn, Ni, Fe and Co; and X comprises at least one element that is selected from the group consisting of Ge, Si, Sn, and Al). With respect to the XRD pattern obtained by XRD measurement wherein Cu is used for an anticathode, the half-value width of the diffraction peak of the (1 171) plane of the negative electrode active material is 0.4713° or more.
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