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公开(公告)号:US20240379952A1
公开(公告)日:2024-11-14
申请号:US18686562
申请日:2022-08-25
Inventor: Jin Zhang , Shogo Esaki , Mitsuhiro Hibino , Kensuke Nakura
Abstract: A positive electrode active material for a secondary battery includes a lithium metal composite oxide having a crystal structure based on a rock-salt structure belonging to a space group Fm-3m. The lithium metal composite oxide contains a first metal element other than Li, and a second metal element other than Li and the first metal element. The first metal element is at least one selected from the group consisting of Gd, Ce, Eu, Sm, and Yb.
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公开(公告)号:US11228033B2
公开(公告)日:2022-01-18
申请号:US16503442
申请日:2019-07-03
Inventor: Kensuke Nakura , Ryuichi Natsui , Shuhei Uchida , Takuji Tsujita
IPC: H01M4/505 , H01M4/131 , H01M4/36 , H01M4/525 , H01M10/0525 , H01M4/02 , C01G25/02 , C01G23/04 , H01M4/62 , B82Y30/00
Abstract: Provided is a cathode active material comprising a lithium composite oxide and a covering material which covers a surface of the lithium composite oxide. The lithium composite oxide is a multi-phase mixture including a first phase having a crystal structure which belongs to a monoclinic crystal; a second phase having a crystal structure which belongs to a hexagonal crystal; and a third phase having a crystal structure which belongs to a cubical crystal. The lithium composite oxide has an integral intensity ratio I(18°-20°)/I(43°-46°) of not less than 0.05 and not more than 0.99, where the integral intensity I(α°-β°) is an integral intensity of a peak which is a maximum peak present within a range of a diffraction angle 2θ of not less than α° and not more than β° in an X-ray diffraction pattern of the lithium composite oxide. The covering material has an electronic conductivity of not more than 106 S/m.
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公开(公告)号:US11183684B2
公开(公告)日:2021-11-23
申请号:US16459614
申请日:2019-07-02
Inventor: Takuji Tsujita , Kensuke Nakura , Shuhei Uchida , Ryuichi Natsui
Abstract: A cathode active material includes a lithium composite oxide and a covering material which covers a surface of the lithium composite oxide. The lithium composite oxide is a multi-phase mixture including a first phase having a crystal structure which belongs to a space group C2/m and a second phase having a crystal structure which belongs to a space group R-3m. The lithium composite oxide has an integral intensity ratio I(18°-20°)/I(43°-46°) of not less than 0.05 and not more than 1.15, where the integral intensity ratio I(18°-20°)/I(43°-46°) is a ratio of an integral intensity I(18°-20°) to an integral intensity I(43°-46°). The integral intensity I(α°-β°) is an integral intensity of a first peak which is a maximum peak present within a range of a diffraction angle 2θ of not less than α° and not more than β° in an X-ray diffraction pattern of the lithium composite oxide.
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公开(公告)号:US11043661B2
公开(公告)日:2021-06-22
申请号:US15838360
申请日:2017-12-12
Inventor: Takayuki Ishikawa , Ryuichi Natsui , Kensuke Nakura
IPC: H01M4/1315 , H01M4/62 , H01M4/505 , H01M4/36 , C07F7/08 , H01M4/525 , H01M4/485 , H01M4/02 , H01M10/0525 , H01M10/0565 , H01M10/0566
Abstract: A positive electrode active material contains a lithium composite oxyfluoride and an organosilicon compound binding to the lithium composite oxyfluoride. The organosilicon compound has insulation property.
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5.
公开(公告)号:US10923711B2
公开(公告)日:2021-02-16
申请号:US16391370
申请日:2019-04-23
Inventor: Akira Kano , Ryohei Miyamae , Kiyohiro Isii , Kensuke Nakura
IPC: H01M4/131 , H01M4/134 , H01M4/66 , H01M4/70 , H01M10/0525 , H01M10/0565 , H01M4/02
Abstract: A lithium secondary battery comprises an electrode group and a nonaqueous electrolyte having lithium-ion conductivity. A negative electrode current collector has a first surface facing outward of winding of the electrode group and a second surface facing inward of the winding of the electrode group. At least the first surface or the second surface includes a first region and a second region that is closer to an innermost circumference of the winding of the electrode group than the first region. Protrusions include outer-circumference-side protrusions disposed on the first region and inner-circumference-side protrusions disposed on the second region. In at least the first surface or the second surface, a first area rate is smaller than a second area rate.
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6.
公开(公告)号:US10916810B2
公开(公告)日:2021-02-09
申请号:US16383219
申请日:2019-04-12
Inventor: Akira Kano , Kiyohiro Isii , Ryohei Miyamae , Kensuke Nakura
IPC: H01M10/0587 , H01M4/134 , H01M4/38 , H01M10/052 , H01M4/02
Abstract: A lithium secondary battery comprises an electrode group and a nonaqueous electrolyte having lithium-ion conductivity. A negative electrode current collector has a first surface facing outward of winding of the electrode group and a second surface facing inward of the winding of the electrode group. At least the first surface or the second surface includes a first region and a second region that is closer to an innermost circumference of the winding of the electrode group than the first region. Protrusions include outer-circumference-side protrusions disposed on the first region and inner-circumference-side protrusions disposed on the second region. A first average height of the outer-circumference-side protrusions is larger than a second average height of the inner-circumference-side protrusions.
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公开(公告)号:US10680243B2
公开(公告)日:2020-06-09
申请号:US16026047
申请日:2018-07-03
Inventor: Akira Kano , Ryohei Miyamae , Kensuke Nakura
IPC: H01M4/583 , H01M10/0525 , H01M10/0562 , H01M4/58 , H01M4/133 , H01M4/136 , H01M4/66 , H01M4/587 , H01M4/36 , H01M4/02
Abstract: A negative electrode active material includes a plurality of layers and lithium located between the plurality of layers, each of the plurality of layers containing carbon and boron, and nitrogen or phosphorus, wherein a molar ratio of the boron to the carbon is more than 0.6.
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8.
公开(公告)号:US20190221838A1
公开(公告)日:2019-07-18
申请号:US16214208
申请日:2018-12-10
Inventor: Takayuki Ishikawa , Ryuichi Natsui , Issei Ikeuchi , Kensuke Nakura
CPC classification number: H01M4/366 , H01M4/483 , H01M4/505 , H01M4/525 , H01M2004/028 , H01M2300/0034 , H01M2300/004 , H01M2300/0065
Abstract: A positive electrode active material includes a lithium composite oxide and a covering material that covers a surface of the lithium composite oxide. The covering material has an electron conductivity of 106 S/m or less. The lithium composite oxide is a multiphase mixture including a first phase having a first crystal structure that belongs to a space group Fm-3m and a second phase having a second crystal structure that belongs to a space group other than a space group Fm-3m. The ratio I(18°-20°)/I(43°-46°) of a first integrated intensity I(18°-20°) of a first maximum peak present at a first diffraction angle 2θ of 18° or more and 20° or less to a second integrated intensity I(43°-46°) of a second maximum peak present at a second diffraction angle 2θ of 43° or more and 46° or less in an XRD pattern of the lithium composite oxide satisfies 0.05≤I(18°-20°)/I(43°-46°)≤0.90.
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公开(公告)号:US09893356B2
公开(公告)日:2018-02-13
申请号:US14675871
申请日:2015-04-01
Inventor: Ryuichi Natsui , Kensuke Nakura
IPC: H01M4/505 , H01M10/052 , H01M4/485 , C01G45/12 , H01M4/04 , H01M4/131 , H01M4/1391 , H01M2/16 , H01M4/62 , H01M10/0568 , H01M10/0569
CPC classification number: H01M4/505 , C01G45/1221 , C01G45/1228 , C01P2002/72 , C01P2002/76 , C01P2006/40 , H01M2/16 , H01M4/0471 , H01M4/131 , H01M4/1391 , H01M4/621 , H01M4/624 , H01M10/052 , H01M10/0568 , H01M10/0569 , H01M2300/0034 , H01M2300/004
Abstract: The cathode active material for a nonaqueous electrolyte secondary battery according to an aspect of the present disclosure mainly comprises a compound represented by a composition formula: LixNay(LiαNaβMn1−α−β)O2, where x, y, α, and β satisfy 0.75≦x≦1.0, 0
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公开(公告)号:US20250105274A1
公开(公告)日:2025-03-27
申请号:US18724795
申请日:2022-10-31
Inventor: Youshin Lee , Mitsuhiro Hibino , Kensuke Nakura
IPC: H01M4/525 , H01M4/02 , H01M4/04 , H01M10/0525
Abstract: This positive electrode comprises a positive electrode current collector, and a positive electrode mixture layer disposed on the positive electrode current collector, wherein: the positive electrode mixture layer has a positive electrode active material containing a lithium-containing composite oxide composed of secondary particles in which primary particles are aggregated; the lithium-containing composite oxide has a Nb element; the average particle diameter of the primary particles is 1 μm or less; and in a depth profile obtained by time-of-flight secondary ion mass spectrometry (TOF-SIMS) of a cross-section of the positive electrode mixture layer, when the minimum ionic strength of Nb in the region from the surface of the positive electrode mixture layer to 500 nm in the thickness direction is Imin and the maximum ionic strength of Nb in a region from 500 nm to 1000 nm in the thickness direction is Imax, Imax/Imin is at least 1.5.
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