公开(公告)号：US07625956B2

公开(公告)日：2009-12-01

申请号：US11290202

申请日：2005-11-30

申请人： Peter G. Odell ,  Eniko Toma ,  Jennifer L. Belelie

发明人： Peter G. Odell ,  Eniko Toma ,  Jennifer L. Belelie

IPC分类号： B01F3/04

CPC分类号： C09D11/101 ,  C08G69/26 ,  C09D11/34

摘要： Disclosed is a phase change ink comprising a colorant, an initiator, and an ink vehicle, said ink vehicle comprising (a) at least one radically curable monomer compound, and (b) a compound of the formula wherein R1 is an alkylene, arylalkylene, or alkylarylene group, R2 and R2′ each, independently of the other, are alkylene, arylene, arylalkylene, or alkylarylene groups, R3 and R3′ each, independently of the other, are either (a) photoinitiating groups, or (b) groups which are alkyl, aryl, arylalkyl, or alkylaryl groups, provided that at least one of R3 and R3′ is a photoinitiating group, and X and X′ each, independently of the other, is an oxygen atom or a group of the formula —NR4—, wherein R4 is a hydrogen atom, an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group.

摘要翻译： 公开了包含着色剂，引发剂和油墨载体的相变油墨，所述油墨载体包含（a）至少一种可自由基固化的单体化合物，和（b）下式化合物其中R 1是亚烷基，芳基亚烷基， 或烷基亚芳基，R 2和R 2'各自独立地为亚烷基，亚芳基，芳基亚烷基或烷基亚芳基，R 3和R 3'各自独立地为（a）光引发基团，或（b）基团 它们是烷基，芳基，芳基烷基或烷基芳基，条件是R 3和R 3'中的至少一个是光引发基团，X和X'各自独立地是氧原子或式 - NR4-，其中R4是氢原子，烷基，芳基，芳基烷基或烷基芳基。

公开(公告)号：US07556844B2

公开(公告)日：2009-07-07

申请号：US11276678

申请日：2006-03-09

申请人： Gabriel Iftime ,  Christopher A Wagner ,  Eniko Toma ,  Jennifer L Belelie ,  Peter G Odell

发明人： Gabriel Iftime ,  Christopher A Wagner ,  Eniko Toma ,  Jennifer L Belelie ,  Peter G Odell

IPC分类号： C08J7/04 ,  C08J7/18 ,  C09D11/10

CPC分类号： C09K9/02 ,  C09D11/101 ,  C09D11/50 ,  C09K2211/1007 ,  C09K2211/1044 ,  C09K2211/1088 ,  C09K2211/1092

摘要： An ink that may be used in ink jet devices is a photochromic ink comprising an ink vehicle that includes at least one radiation curable component, at least one photochromic material and at least one photoinitiator. The ink is cured via exposure to radiation that cures the at least one radiation curable component of the ink. A radiation curable ink capable of exhibiting photochromatic color changes, which may be used to indicate a document's authenticity, is thus achieved.

摘要翻译： 可用于喷墨装置的油墨是包含油墨载体的光致变色油墨，其包含至少一种可辐射固化组分，至少一种光致变色材料和至少一种光引发剂。 油墨通过暴露于固化油墨的至少一种可辐射固化组分的辐射而固化。 因此可以实现能够表现出可以用于指示文件真实性的光色变化的可辐射固化油墨。

公开(公告)号：US08142557B2

公开(公告)日：2012-03-27

申请号：US11427172

申请日：2006-06-28

申请人： Jennifer L. Belelie ,  Peter G. Odell ,  Eniko Toma ,  Christopher A. Wagner ,  C. Geoffrey Allen ,  Stephan V. Drappel

发明人： Jennifer L. Belelie ,  Peter G. Odell ,  Eniko Toma ,  Christopher A. Wagner ,  C. Geoffrey Allen ,  Stephan V. Drappel

IPC分类号： C09D11/00 ,  B01F3/04

CPC分类号： C09D11/101 ,  C09D11/34

摘要： Radiation curable phase change ink comprising an ink vehicle that includes at least one curable carrier, at least one gellant, at least one curable wax and at least one photoinitiator. In a method of forming an image with the ink, the radiation curable phase change ink is melted, then jetted onto an image receiving substrate, wherein the radiation curable phase change ink forms a gel state, and exposed to ultraviolet light to cure the curable components of the radiation curable phase change ink. The wax cures into the structure of the ink, thereby generating a robust image of excellent gloss.

摘要翻译： 包含油墨载体的可辐射固化相变油墨，其包含至少一种可固化载体，至少一种胶凝剂，至少一种可固化蜡和至少一种光引发剂。 在用油墨形成图像的方法中，将可辐射固化相变油墨熔化，然后喷射到图像接收基板上，其中可辐射固化相变油墨形成凝胶状态，并暴露于紫外光以固化可固化组分 的可辐射固化相变油墨。 蜡固化成油墨的结构，从而产生具有优异光泽的坚固的图像。

公开(公告)号：US07714040B2

公开(公告)日：2010-05-11

申请号：US11290121

申请日：2005-11-30

申请人： Eniko Toma ,  Jennifer L. Belelie ,  Peter G. Odell

发明人： Eniko Toma ,  Jennifer L. Belelie ,  Peter G. Odell

IPC分类号： C09D11/00 ,  G01D11/00

CPC分类号： C09D11/101 ,  C09D11/34

摘要： Disclosed is a phase change ink comprising a colorant, an initiator, and a phase change ink carrier, said carrier comprising at least one radically curable monomer compound and a compound of the formula wherein R1 and R1′ each, independently of the other, is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylenic unsaturation, R2, R2′, and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, and n is an integer representing the number of repeat amide units and is at least 1. Also disclosed herein is a method of printing with the phase change ink.

摘要翻译： 公开了一种相变油墨，其包含着色剂，引发剂和相变油墨载体，所述载体包含至少一种可自由基固化的单体化合物和下式化合物：其中R 1和R 1'各自独立地为 具有至少一个烯属不饱和基团的烷基，具有至少一个烯属不饱和基团的芳基烷基或具有至少一个烯属不饱和键的烷基芳基，R 2，R 2'和R 3各自独立地为亚烷基，亚芳基 ，芳基亚烷基或烷基亚芳基，n是表示重复酰胺单元数的整数，并且至少为1.本文还公开了用相变油墨印刷的方法。

公开(公告)号：US07279587B2

公开(公告)日：2007-10-09

申请号：US11290207

申请日：2005-11-30

申请人： Peter G. Odell ,  Eniko Toma ,  Jennifer L. Belelie

发明人： Peter G. Odell ,  Eniko Toma ,  Jennifer L. Belelie

IPC分类号： C07C231/00

CPC分类号： C07C233/34 ,  C07C233/36 ,  C08G69/26 ,  C08G69/28 ,  C09D11/101 ,  C09D11/34

摘要： Disclosed is a compound of the formula wherein R1 is an alkylene, arylene, arylalkylene, or alkylarylene group, R2 and R2′ each independently of the other, are alkylene, arylene, arylalkylene, or alklarylene groups, R3 and R3′ each, independently of the other, are either (a) photoinitiating groups, or (b) groups which are alkyl, aryl, arylalkyl, or alkylaryl groups, provide that at least one of R3 and R3′ is a photoinitiating group, and X and X′ each, independently of the other, is an oxygen atom or a group of the formula —NR4—, wherein R4 is a hydrogen atom, an alkyl group, an aryl group, or an alkylaryl group.

摘要翻译： 公开了下式的化合物其中R 1是亚烷基，亚芳基，芳基亚烷基或烷基亚芳基，R 2和R 2各自 独立于亚烷基，亚芳基，芳基亚烷基或亚烷基，R 3和R 3各自独立地是（a）光引发基团 ，或（b）烷基，芳基，芳基烷基或烷基芳基的基团，提供R 3和R 3'中的至少一个是光引发基团，和 X和X'各自独立地是氧原子或式-NR 4 - 的基团，其中R 4是氢原子，烷基 基团，芳基或烷基芳基。

公开(公告)号：US07276614B2

公开(公告)日：2007-10-02

申请号：US11290122

申请日：2005-11-30

申请人： Eniko Toma ,  Peter G. Odell ,  Adela Goredema ,  Jennifer L. Belelie

发明人： Eniko Toma ,  Peter G. Odell ,  Adela Goredema ,  Jennifer L. Belelie

IPC分类号： C07C231/00

CPC分类号： C07C233/34 ,  C07C233/36 ,  C08G69/26 ,  C09D11/101 ,  C09D11/34

摘要： Disclosed is a compound of the formula wherein R1 and R1′ each, independently of the other, is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylene unsaturation, R2, R2′, and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, and n is an integer representing the number of repeat amide units and is at least 1.

摘要翻译： 公开了下式的化合物，其中R 1和R 2各自独立地是具有至少一个烯属不饱和键的烷基，具有 至少一个烯属不饱和基团或具有至少一个乙烯不饱和键的烷基芳基，R 2，R 2，R 3和R 3各自， 独立地是亚烷基，亚芳基，芳基亚烷基或烷基亚芳基，n是表示重复酰胺单元数的整数，并且至少为1。

公开(公告)号：US07838570B2

公开(公告)日：2010-11-23

申请号：US11034856

申请日：2005-01-14

申请人： Peter G. Odell ,  Eniko Toma

发明人： Peter G. Odell ,  Eniko Toma

IPC分类号： C09D11/00 ,  C08F2/50

CPC分类号： C09D11/101

摘要： An ink used preferably in jet ink devices includes an ink vehicle, the ink vehicle being made up either (a) a first component curable by a first polymerization route and an associated photointiator, and a second component curable by a second polymerization route and as associated photoinitiator, wherein the second polymerization route is different from the first polymerization route, or (b) a component curable by a single polymerization route with a first and a second photoinitiator system in which the first system responds to longer wavelengths. An image may be formed by such inks by jetting onto a transfer member surface, curing the first component or partially curing the single component while upon the transfer member surface, transferring the ink to an image receiving surface, and completing curing. The first component is preferably curable via cationic polymerization and the second component is preferably curable via free radical polymerization.

摘要翻译： 用于喷墨油墨装置的油墨最好包括油墨载体，油墨载体由（a）可通过第一聚合路线固化的第一组分和相关的感光剂组成，和由第二聚合路线固化的第二组分 光引发剂，其中第二聚合路线不同于第一聚合路线，或（b）通过第一和第二光引发剂体系通过单一聚合途径固化的成分，其中第一系统响应较长波长。 通过这样的油墨可以通过喷射到转印部件表面上，固化第一部件或部分固化单个部件，同时在转印部件表面上，将油墨转印到图像接收表面，并完成固化，可以形成图像。 第一组分优选通过阳离子聚合固化，并且第二组分优选通过自由基聚合可固化。

公开(公告)号：US07531582B2

公开(公告)日：2009-05-12

申请号：US11466687

申请日：2006-08-23

申请人： Eniko Toma ,  Peter G. Odell ,  C. Geoffrey Allen ,  Jennifer Lynne Belelie

发明人： Eniko Toma ,  Peter G. Odell ,  C. Geoffrey Allen ,  Jennifer Lynne Belelie

IPC分类号： C09D11/00 ,  G01D11/00

CPC分类号： C09D11/101 ,  C09D11/34

摘要： Ink vehicles having improved gellant solubility and ink compositions including such ink vehicles are provided. Exemplary ink vehicles include first and second co-monomers, and a gellant that includes that includes a curable epoxy-polyamide composite gellant; in which the first and second co-monomers are radiation curable are different from each other. Additional exemplary ink vehicles include at least two chemically distinct gellants. The chemically distinct gellant materials include a first gellant that includes a curable epoxy-polyamide composite gellant, and a second gellant that includes an amide gellant. Methods for making and using these ink vehicles and ink compositions are also provided.

摘要翻译： 提供具有改善的胶凝剂溶解性的油墨载体和包括这种油墨载体的油墨组合物。 示例性油墨载体包括第一和第二共聚单体，和包含可固化环氧 - 聚酰胺复合胶凝剂的胶凝剂; 其中第一和第二共聚单体是可辐射固化的彼此不同。 另外的示例性油墨载体包括至少两种化学上不同的胶凝剂。 化学不同的胶凝剂材料包括包含可固化环氧 - 聚酰胺复合胶凝胶的第一胶凝剂和包含酰胺胶凝剂的第二胶凝剂。 还提供了制造和使用这些油墨载体和油墨组合物的方法。

公开(公告)号：US07271284B2

公开(公告)日：2007-09-18

申请号：US11289882

申请日：2005-11-30

申请人： Eniko Toma ,  Adela Goredema ,  Jennifer L. Belelie ,  Peter G. Odell

发明人： Eniko Toma ,  Adela Goredema ,  Jennifer L. Belelie ,  Peter G. Odell

IPC分类号： C07C229/00

CPC分类号： C08F290/06 ,  C08F220/14 ,  C08F290/061 ,  C08F290/067 ,  C08G69/26 ,  C08G69/28

摘要： Disclosed is a process for preparing a compound of the formula wherein R1 is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylenic unsaturation, R2 and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, R4 and R5 each, independently of the other, is a hydrogen atom or an alkyl group, and n is an integer representing the number of repeat amide units and is at least 1, said process comprising: (a) reacting a diacid of the formula HOOC—R2—COOH with a diamine of the formula in the presence of a catalyst, a solvent, and a coupling agent to form an oligoamide intermediate; and (b) reacting the oligoamide intermediate with an alcohol of the formula R1—OH to form the product.

摘要翻译： 公开了一种制备下式化合物的方法，其中R 1是具有至少一个烯属不饱和键的烷基，具有至少一个烯属不饱和键的芳基烷基或具有至少一个烯属不饱和键的烷基芳基 R 1，R 2，R 3和R 3各自独立地是亚烷基，亚芳基，芳基亚烷基或烷基亚芳基，R 4， 各自独立地是氢原子或烷基，n是表示重复酰胺单元数的整数，并且至少为1，所述方法包括： （a）使式（Ⅳ）的二酸与式-I-in-line-formula中的二酸反应， 在存在催化剂，溶剂和偶联剂的情况下，使式II的化合物描述=“内联式”末端=“尾”→，形成低聚酰胺中间体; 和（b）使低聚酰胺中间体与式（Ⅳ）的醇反应，其中式（Ⅳ）中，式 -line-formula description =“In-Line Formulas”end =“tail”？>来形成产品。

公开(公告)号：US07259275B2

公开(公告)日：2007-08-21

申请号：US11290328

申请日：2005-11-30

申请人： Jennifer L. Belelie ,  Adela Goredema ,  Peter G. Odell ,  Eniko Toma

发明人： Jennifer L. Belelie ,  Adela Goredema ,  Peter G. Odell ,  Eniko Toma

IPC分类号： C07C229/00

CPC分类号： C07C231/02 ,  C08G69/26 ,  C08G69/28 ,  C09D11/34 ,  C07C233/34 ,  C07C233/36

摘要： Disclosed is a process for preparing a compound of the formula wherein R1 is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylenic unsaturation, R2 and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, and n is an integer representing the number of repeat amide units and is at least 1, said process comprising: (a) reacting a diacid of the formula HOOC—R2—COOH with a diamine of the formula in the absence of a solvent while removing water from the reaction mixture to form an acid-terminated oligoamide intermediate; and (b) reacting the acid-terminated oligoamide intermediate with a monoalcohol of the formula R1—OH in the presence of a coupling agent and a catalyst to form the product.

摘要翻译： 公开了一种制备下式化合物的方法，其中R 1是具有至少一个烯属不饱和键的烷基，具有至少一个烯属不饱和键的芳基烷基或具有至少一个烯属不饱和键的烷基芳基 烯键式不饱和键，R 2和R 3各自独立地为亚烷基，亚芳基，芳基亚烷基或烷基亚芳基，n为代表 重复酰胺单元的数目并且至少为1，所述方法包括：（a）使式Ⅳ的二酸与-in-line-formula description =“In-Line Formulas”end =“lead”→> HOOC-R' 在不存在溶剂的情况下，在从反应混合物中除去水的情况下，使用下式所示的二胺，在线式描述=“In-line Formula”中， 以形成酸封端的低聚酰胺中间体; 和（b）使酸封端的低聚酰胺中间体与下式的一元醇反应：式中：=“引入”→R 1 -OH 在偶联剂和催化剂的存在下，<？in-line-formula description =“In-line formula”end =“tail”？>以形成产物。