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公开(公告)号：US07820731B2
公开(公告)日：2010-10-26
申请号：US11275147
申请日：2005-12-15
CPC分类号： C09D11/101 , B41M7/0081
摘要： A radiation curable ink includes a curable monomer or oligomer, a curable wax, a colorant, and at least one initiator.
摘要翻译： 辐射固化油墨包括可固化单体或低聚物，可固化蜡，着色剂和至少一种引发剂。
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2.发明授权Phase change inks containing photoinitiator with phase change properties and gellant affinity 失效含有相变性能和胶凝剂亲和力的光引发剂的相变油墨公开(公告)号：US07625956B2
公开(公告)日：2009-12-01
申请号：US11290202
申请日：2005-11-30
申请人： Peter G. Odell , Eniko Toma , Jennifer L. Belelie
发明人： Peter G. Odell , Eniko Toma , Jennifer L. Belelie
IPC分类号： B01F3/04
CPC分类号： C09D11/101 , C08G69/26 , C09D11/34
摘要： Disclosed is a phase change ink comprising a colorant, an initiator, and an ink vehicle, said ink vehicle comprising (a) at least one radically curable monomer compound, and (b) a compound of the formula wherein R1 is an alkylene, arylalkylene, or alkylarylene group, R2 and R2′ each, independently of the other, are alkylene, arylene, arylalkylene, or alkylarylene groups, R3 and R3′ each, independently of the other, are either (a) photoinitiating groups, or (b) groups which are alkyl, aryl, arylalkyl, or alkylaryl groups, provided that at least one of R3 and R3′ is a photoinitiating group, and X and X′ each, independently of the other, is an oxygen atom or a group of the formula —NR4—, wherein R4 is a hydrogen atom, an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group.
摘要翻译： 公开了包含着色剂，引发剂和油墨载体的相变油墨，所述油墨载体包含（a）至少一种可自由基固化的单体化合物，和（b）下式化合物其中R 1是亚烷基，芳基亚烷基， 或烷基亚芳基，R 2和R 2'各自独立地为亚烷基，亚芳基，芳基亚烷基或烷基亚芳基，R 3和R 3'各自独立地为（a）光引发基团，或（b）基团 它们是烷基，芳基，芳基烷基或烷基芳基，条件是R 3和R 3'中的至少一个是光引发基团，X和X'各自独立地是氧原子或式 - NR4-，其中R4是氢原子，烷基，芳基，芳基烷基或烷基芳基。
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公开(公告)号：US07556844B2
公开(公告)日：2009-07-07
申请号：US11276678
申请日：2006-03-09
CPC分类号： C09K9/02 , C09D11/101 , C09D11/50 , C09K2211/1007 , C09K2211/1044 , C09K2211/1088 , C09K2211/1092
摘要： An ink that may be used in ink jet devices is a photochromic ink comprising an ink vehicle that includes at least one radiation curable component, at least one photochromic material and at least one photoinitiator. The ink is cured via exposure to radiation that cures the at least one radiation curable component of the ink. A radiation curable ink capable of exhibiting photochromatic color changes, which may be used to indicate a document's authenticity, is thus achieved.
摘要翻译： 可用于喷墨装置的油墨是包含油墨载体的光致变色油墨，其包含至少一种可辐射固化组分，至少一种光致变色材料和至少一种光引发剂。 油墨通过暴露于固化油墨的至少一种可辐射固化组分的辐射而固化。 因此可以实现能够表现出可以用于指示文件真实性的光色变化的可辐射固化油墨。
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公开(公告)号：US08142557B2
公开(公告)日：2012-03-27
申请号：US11427172
申请日：2006-06-28
申请人： Jennifer L. Belelie , Peter G. Odell , Eniko Toma , Christopher A. Wagner , C. Geoffrey Allen , Stephan V. Drappel
发明人： Jennifer L. Belelie , Peter G. Odell , Eniko Toma , Christopher A. Wagner , C. Geoffrey Allen , Stephan V. Drappel
CPC分类号： C09D11/101 , C09D11/34
摘要： Radiation curable phase change ink comprising an ink vehicle that includes at least one curable carrier, at least one gellant, at least one curable wax and at least one photoinitiator. In a method of forming an image with the ink, the radiation curable phase change ink is melted, then jetted onto an image receiving substrate, wherein the radiation curable phase change ink forms a gel state, and exposed to ultraviolet light to cure the curable components of the radiation curable phase change ink. The wax cures into the structure of the ink, thereby generating a robust image of excellent gloss.
摘要翻译： 包含油墨载体的可辐射固化相变油墨，其包含至少一种可固化载体，至少一种胶凝剂，至少一种可固化蜡和至少一种光引发剂。 在用油墨形成图像的方法中，将可辐射固化相变油墨熔化，然后喷射到图像接收基板上，其中可辐射固化相变油墨形成凝胶状态，并暴露于紫外光以固化可固化组分 的可辐射固化相变油墨。 蜡固化成油墨的结构，从而产生具有优异光泽的坚固的图像。
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公开(公告)号：US07714040B2
公开(公告)日：2010-05-11
申请号：US11290121
申请日：2005-11-30
申请人： Eniko Toma , Jennifer L. Belelie , Peter G. Odell
发明人： Eniko Toma , Jennifer L. Belelie , Peter G. Odell
CPC分类号： C09D11/101 , C09D11/34
摘要： Disclosed is a phase change ink comprising a colorant, an initiator, and a phase change ink carrier, said carrier comprising at least one radically curable monomer compound and a compound of the formula wherein R1 and R1′ each, independently of the other, is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylenic unsaturation, R2, R2′, and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, and n is an integer representing the number of repeat amide units and is at least 1. Also disclosed herein is a method of printing with the phase change ink.
摘要翻译： 公开了一种相变油墨，其包含着色剂，引发剂和相变油墨载体，所述载体包含至少一种可自由基固化的单体化合物和下式化合物：其中R 1和R 1'各自独立地为 具有至少一个烯属不饱和基团的烷基，具有至少一个烯属不饱和基团的芳基烷基或具有至少一个烯属不饱和键的烷基芳基，R 2，R 2'和R 3各自独立地为亚烷基，亚芳基 ，芳基亚烷基或烷基亚芳基，n是表示重复酰胺单元数的整数，并且至少为1.本文还公开了用相变油墨印刷的方法。
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公开(公告)号：US07279587B2
公开(公告)日：2007-10-09
申请号：US11290207
申请日：2005-11-30
申请人： Peter G. Odell , Eniko Toma , Jennifer L. Belelie
发明人： Peter G. Odell , Eniko Toma , Jennifer L. Belelie
IPC分类号： C07C231/00
CPC分类号： C07C233/34 , C07C233/36 , C08G69/26 , C08G69/28 , C09D11/101 , C09D11/34
摘要： Disclosed is a compound of the formula wherein R1 is an alkylene, arylene, arylalkylene, or alkylarylene group, R2 and R2′ each independently of the other, are alkylene, arylene, arylalkylene, or alklarylene groups, R3 and R3′ each, independently of the other, are either (a) photoinitiating groups, or (b) groups which are alkyl, aryl, arylalkyl, or alkylaryl groups, provide that at least one of R3 and R3′ is a photoinitiating group, and X and X′ each, independently of the other, is an oxygen atom or a group of the formula —NR4—, wherein R4 is a hydrogen atom, an alkyl group, an aryl group, or an alkylaryl group.
摘要翻译： 公开了下式的化合物其中R 1是亚烷基，亚芳基，芳基亚烷基或烷基亚芳基，R 2和R 2各自 独立于亚烷基，亚芳基，芳基亚烷基或亚烷基，R 3和R 3各自独立地是（a）光引发基团 ，或（b）烷基，芳基，芳基烷基或烷基芳基的基团，提供R 3和R 3'中的至少一个是光引发基团，和 X和X'各自独立地是氧原子或式-NR 4 - 的基团，其中R 4是氢原子，烷基 基团，芳基或烷基芳基。
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公开(公告)号：US07276614B2
公开(公告)日：2007-10-02
申请号：US11290122
申请日：2005-11-30
IPC分类号： C07C231/00
CPC分类号： C07C233/34 , C07C233/36 , C08G69/26 , C09D11/101 , C09D11/34
摘要： Disclosed is a compound of the formula wherein R1 and R1′ each, independently of the other, is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylene unsaturation, R2, R2′, and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, and n is an integer representing the number of repeat amide units and is at least 1.
摘要翻译： 公开了下式的化合物，其中R 1和R 2各自独立地是具有至少一个烯属不饱和键的烷基，具有 至少一个烯属不饱和基团或具有至少一个乙烯不饱和键的烷基芳基，R 2，R 2，R 3和R 3各自， 独立地是亚烷基，亚芳基，芳基亚烷基或烷基亚芳基，n是表示重复酰胺单元数的整数，并且至少为1。
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公开(公告)号：US07691920B2
公开(公告)日：2010-04-06
申请号：US11034714
申请日：2005-01-14
申请人： Jennifer L. Belelie , Peter G. Odell , Eniko Toma , Paul F. Smith , Rina Carlini
发明人： Jennifer L. Belelie , Peter G. Odell , Eniko Toma , Paul F. Smith , Rina Carlini
IPC分类号： A61L24/00 , B01F3/04 , B05D1/32 , B41J2/01 , B41J2/16 , B41J2/17 , B41J29/38 , C07D209/48 , C07D303/40 , G01D11/00 , C08F2/00 , C08F2/46 , C08F14/06 , C08F20/22 , C08G59/14 , C08G65/18 , C08J3/28 , C09D5/00 , C09D11/00
CPC分类号： C09D11/101
摘要： An ink jet ink includes an ink vehicle, wherein the ink vehicle includes at least one wax monomer functionalized to include in the chain at least one reactive group curable upon exposure to radiation. The reactive group is preferably curable via cationic or free radical polymerization. In a preferred embodiment, the ink vehicle includes a wax monomer having a structure: wherein C represents a cationically curable group and R represents a radically curable group. The inks may be used to form an image by jetting the ink onto a transfuse member surface, increasing the viscosity of the ink upon the transfuse member surface, subsequently transferring the ink from the transfuse member surface to an image receiving substrate, and exposing the ink to radiation following the transfer to the image receiving substrate to effect reaction of the at least one reactive group.
摘要翻译： 喷墨油墨包括油墨载体，其中油墨载体包括至少一种蜡官能化的蜡单体，其在链中包含在暴露于辐射时可固化的至少一种反应性基团。 反应性基团优选通过阳离子或自由基聚合可固化。 在优选的实施方案中，油墨载体包括具有以下结构的蜡单体：其中C表示阳离子可固化基团，R表示可自由基固化的基团。 油墨可以用于通过将墨喷射到输入构件表面上来形成图像，增加在输入构件表面上的墨的粘度，随后将墨从输液构件表面转移到图像接收基底，并使墨 在转移到图像接收基板之后进行辐射以实现至少一个反应性基团的反应。
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公开(公告)号：US07271284B2
公开(公告)日：2007-09-18
申请号：US11289882
申请日：2005-11-30
IPC分类号： C07C229/00
CPC分类号： C08F290/06 , C08F220/14 , C08F290/061 , C08F290/067 , C08G69/26 , C08G69/28
摘要： Disclosed is a process for preparing a compound of the formula wherein R1 is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylenic unsaturation, R2 and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, R4 and R5 each, independently of the other, is a hydrogen atom or an alkyl group, and n is an integer representing the number of repeat amide units and is at least 1, said process comprising: (a) reacting a diacid of the formula HOOC—R2—COOH with a diamine of the formula in the presence of a catalyst, a solvent, and a coupling agent to form an oligoamide intermediate; and (b) reacting the oligoamide intermediate with an alcohol of the formula R1—OH to form the product.
摘要翻译： 公开了一种制备下式化合物的方法，其中R 1是具有至少一个烯属不饱和键的烷基，具有至少一个烯属不饱和键的芳基烷基或具有至少一个烯属不饱和键的烷基芳基 R 1，R 2，R 3和R 3各自独立地是亚烷基，亚芳基，芳基亚烷基或烷基亚芳基，R 4， 各自独立地是氢原子或烷基，n是表示重复酰胺单元数的整数，并且至少为1，所述方法包括： （a）使式（Ⅳ）的二酸与式-I-in-line-formula中的二酸反应， 在存在催化剂，溶剂和偶联剂的情况下，使式II的化合物描述=“内联式”末端=“尾”→，形成低聚酰胺中间体; 和（b）使低聚酰胺中间体与式（Ⅳ）的醇反应，其中式（Ⅳ）中，式 -line-formula description =“In-Line Formulas”end =“tail”？>来形成产品。
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公开(公告)号：US07259275B2
公开(公告)日：2007-08-21
申请号：US11290328
申请日：2005-11-30
IPC分类号： C07C229/00
CPC分类号： C07C231/02 , C08G69/26 , C08G69/28 , C09D11/34 , C07C233/34 , C07C233/36
摘要： Disclosed is a process for preparing a compound of the formula wherein R1 is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylenic unsaturation, R2 and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, and n is an integer representing the number of repeat amide units and is at least 1, said process comprising: (a) reacting a diacid of the formula HOOC—R2—COOH with a diamine of the formula in the absence of a solvent while removing water from the reaction mixture to form an acid-terminated oligoamide intermediate; and (b) reacting the acid-terminated oligoamide intermediate with a monoalcohol of the formula R1—OH in the presence of a coupling agent and a catalyst to form the product.
摘要翻译： 公开了一种制备下式化合物的方法，其中R 1是具有至少一个烯属不饱和键的烷基，具有至少一个烯属不饱和键的芳基烷基或具有至少一个烯属不饱和键的烷基芳基 烯键式不饱和键，R 2和R 3各自独立地为亚烷基，亚芳基，芳基亚烷基或烷基亚芳基，n为代表 重复酰胺单元的数目并且至少为1，所述方法包括：（a）使式Ⅳ的二酸与-in-line-formula description =“In-Line Formulas”end =“lead”→> HOOC-R' 在不存在溶剂的情况下，在从反应混合物中除去水的情况下，使用下式所示的二胺，在线式描述=“In-line Formula”中， 以形成酸封端的低聚酰胺中间体; 和（b）使酸封端的低聚酰胺中间体与下式的一元醇反应：式中：=“引入”→R 1 -OH 在偶联剂和催化剂的存在下，<？in-line-formula description =“In-line formula”end =“tail”？>以形成产物。
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