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41 条记录 (耗时 0.019 秒)

    Method for preparing substituted mixed alkynyl ethers
    31.
    发明授权
    Method for preparing substituted mixed alkynyl ethers 失效
    制备取代的混合炔基醚的方法

    公开(公告)号：US06881869B1

    公开(公告)日：2005-04-19

    申请号：US10088455

    申请日：2000-09-29

    申请人： Roland Jacquot

    发明人： Roland Jacquot

    IPC分类号： C07B61/00 ,  C07C41/30 ,  C07C43/166 ,  C07C43/215 ,  C07C41/00

    CPC分类号： C07C41/30 ,  C07C43/215

    摘要： The present invention relates to a process for preparing mixed substituted alkynyl ethers. More particularly, the invention concerns the preparation of mixed ethers derived from a benzyl type alcohol and a substituted alkynyl alcohol. The process of the invention for preparing a benzyl/substituted alkynyl type mixed ether is prepared from a benzyl/alkynyl type mixed ether with a hydrogen atom on the triple bond is characterized in that it consists of reacting a mixed ether derived from a benzyl type alcohol and an alkynyl alcohol with a hydrogen atom on the triple bond with an alkylation agent, in the presence of an anionisation agent.

    摘要翻译： 本发明涉及一种制备混合取代炔基醚的方法。 更具体地，本发明涉及由苄基型醇和取代的炔基醇制备的混合醚。 制备苄基/取代的炔基型混合醚的本发明方法由三价键上的氢原子的苄基/炔基型混合醚制备，其特征在于其由衍生自苄基型醇的混合醚 和在烷基化试剂的三键上具有氢原子的炔基醇，在阴离子化剂存在下。

    Method for etherifying a benzyl alcohol, resulting products and applications
    32.
    发明授权
    Method for etherifying a benzyl alcohol, resulting products and applications 失效
    醚化苄醇的方法，得到的产品和应用

    公开(公告)号：US06362378B1

    公开(公告)日：2002-03-26

    申请号：US09462432

    申请日：2000-03-14

    申请人： Roland Jacquot ,  Michel Spagnol

    发明人： Roland Jacquot ,  Michel Spagnol

    IPC分类号： C07C4109

    CPC分类号： C07C41/09 ,  C07C43/23 ,  C07C2601/14

    摘要： The present invention relates to a process for etherification of a benzyl type alcohol, to the products obtained and to their applications, in particular in the perfumery field. The etherification process of the invention consists of reacting a benzyl type alcohol with another alcohol in the presence of a catalyst, characterized in that the etherification reaction is carried out in the presence of an effective quantity of a zeolite.

    摘要翻译： 本发明涉及一种苄基醇的醚化方法，所得到的产物及其应用，特别是在香料领域中。 本发明的醚化方法包括在催化剂存在下使苄基型醇与另一种醇反应，其特征在于醚化反应在有效量的沸石存在下进行。

    Method for preparing a bimetallic ruthenium/tin catalyst and a process for the synthesis of aldehydes
    33.
    发明授权
    Method for preparing a bimetallic ruthenium/tin catalyst and a process for the synthesis of aldehydes 失效
    制备双金属钌/锡催化剂的方法和合成醛的方法

    公开(公告)号：US06180830B2

    公开(公告)日：2001-01-30

    申请号：US09068263

    申请日：1998-05-05

    申请人： Roland Jacquot

    发明人： Roland Jacquot

    IPC分类号： C07C4727

    CPC分类号： C07C45/41 ,  B01J23/626

    摘要： The present invention relates to a new process for the preparation of a bimetallic ruthenium/tin catalyst. The process for the preparation of a bimetallic ruthenium/tin catalyst according to the invention is characterised by the fact that it consists in carrying out the reduction of a ruthenium complex having an electrovalency of −4 and a coordination number of 6, the ligands being either a halogen atom or an anion or a tin halide. The catalyst is further employed for the preparation of aldehydes by reduction, in the vapor phase, of carboxylic acids, esters and anhydrides.

    摘要翻译： 本发明涉及一种制备双金属钌/锡催化剂的新方法。 制备根据本发明的双金属钌/锡催化剂的方法的特征在于它包括进行电化学为-4且配位数为6的钌络合物的还原，所述配体为 卤素原子或阴离子或卤化锡。 催化剂还用于通过在气相中还原羧酸，酯和酸酐来制备醛。

    HYDRIDE TRANSFER PROCESS FOR KETONE PREPARATION
    35.
    发明申请
    HYDRIDE TRANSFER PROCESS FOR KETONE PREPARATION 有权
    用于制酮的水转移过程

    公开(公告)号：US20130204046A1

    公开(公告)日：2013-08-08

    申请号：US13813616

    申请日：2011-07-20

    申请人： Roland Jacquot ,  Philippe Marion

    发明人： Roland Jacquot ,  Philippe Marion

    IPC分类号： C07C27/04

    CPC分类号： C07C27/04 ,  C07C29/143 ,  C07C45/29 ,  C07C2601/14 ,  C07C31/10 ,  C07C49/403

    摘要： A hydride transfer process within a reaction between an alcohol and a ketone and in the presence of a heterogeneous catalyst is described. The process can transfer a hydride from an alcohol to a ketone, thus enabling reduction of the ketone and oxidation of the alcohol. Further described, is a process for the simultaneous preparation of cyclohexanone and isopropanol enabling an optimized industrial operation. A mixture of compounds useful for implementing the process and comprising two different ketones and two different alcohols is also described.

    摘要翻译： 描述了在醇和酮之间的反应中和在非均相催化剂存在下的氢化物转移过程。 该方法可以将氢化物从醇转移到酮，从而可以还原酮和醇的氧化。 进一步描述的是同时制备环己酮和异丙醇的方法，能够实现优化的工业操作。 还描述了可用于实施该方法并包含两种不同酮和两种不同醇的化合物的混合物。

    Method for manufacturing compounds including nitrile functions
    37.
    发明授权
    Method for manufacturing compounds including nitrile functions 有权
    制造腈类功能化合物的方法

    公开(公告)号：US08501979B2

    公开(公告)日：2013-08-06

    申请号：US13132964

    申请日：2009-11-26

    申请人： Roland Jacquot ,  Philippe Marion

    发明人： Roland Jacquot ,  Philippe Marion

    IPC分类号： C07C253/00 ,  C07C63/30

    CPC分类号： C07C253/20 ,  C07C255/04

    摘要： A process for the preparation of compounds containing nitrile functions and, more specifically, compounds containing two nitrile functions, such as succinonitrile and adiponitrile, is described. A process for preparing dintrile compounds obtained by reacting ammonia with an aqueous solution of a dicarboxyl compound in the presence of a silicon orthophosphate catalyst is also described.

    摘要翻译： 描述了制备含腈功能的化合物的方法，更具体地说，涉及含有两个腈官能团的化合物，例如丁二腈和己二腈。 还描述了在正磷酸正硅酸盐催化剂存在下，通过使氨与二羧酸化合物的水溶液反应而得到的复合化合物的制备方法。

    Production of difluoroethanol
    38.
    发明授权
    Production of difluoroethanol 有权
    生产二氟乙醇

    公开(公告)号：US07902409B2

    公开(公告)日：2011-03-08

    申请号：US12086747

    申请日：2006-12-19

    申请人： Olivier Buisine ,  Roland Jacquot

    发明人： Olivier Buisine ,  Roland Jacquot

    IPC分类号： C07C31/38

    CPC分类号： C07C29/149 ,  C07C31/38

    摘要： Difluoroethanol is produced by hydrogenation, in the presence of an effective amount of a catalyst containing at least one element of Group VIII of the Periodic Table deposited onto a solid, acidic mineral support, of an acetyl halide having the following formula (I), in which formula X is a halogen atom other than a fluorine atom:

    摘要翻译： 在有效量的催化剂存在下，通过氢化产生二氟乙醇，所述催化剂含有至少一种元素周期表第Ⅷ族元素沉积在具有下式（I）的乙酰卤的固体酸性矿物载体上，在 该式X是除氟原子以外的卤原子：

    Formation of Carbon-nitrogen bond
    39.
    发明申请
    Formation of Carbon-nitrogen bond 审中-公开
    形成碳 - 氮键

    公开(公告)号：US20100113800A1

    公开(公告)日：2010-05-06

    申请号：US11990012

    申请日：2006-08-04

    申请人： Christelle Mauger ,  Gerard Mignani ,  Roland Jacquot

    发明人： Christelle Mauger ,  Gerard Mignani ,  Roland Jacquot

    IPC分类号： C07D233/00

    CPC分类号： C07D233/56

    摘要： The present invention relates to a process to create a carbon-nitrogen bond by the reaction of an aromatic compound carrying at least one electro attractive group with one nitrogenous heterocyclic type nucleophile compound. The invention aims, in particular, at a link reaction between an aromatic compound carrying at least one electro attractive group and an imidazole heterocycle type. The invention process, consisting of the reaction of an aromatic compound carrying one leaving group and at least one electro attractive group and a nitrogenous heterocyclic type nucleophile compound comprising a N—H pattern likely to substitute the leaving group, thereby creating a carbon-nitrogen bond in the presence of a copper catalyst, of a base in an organic solvent, is characterized by the fact that the said nitrogenous heterocycle reacts with an aromatic type electrophile compound carrying one leaving group (Y) chosen from bromine, chlorine or sulfonic ester and at least one electro attractive group (Z1), in the presence of a copper catalyst, of a mineral or organic base, of an extracting agent selected from aliphatic diamines, aliphatic amino alcohols and diols in a polar aprotic organic solvent with a dielectric constant less than about 20 and a basicity such that its “donor number” is less than about 25.

    摘要翻译： 本发明涉及通过携带至少一个电吸引基团的芳族化合物与一种含氮杂环型亲核化合物的反应产生碳 - 氮键的方法。 本发明特别涉及携带至少一个电吸引基团的芳族化合物和咪唑杂环类型之间的连接反应。 本发明方法由携带一个离去基团的芳族化合物和至少一个电吸引基团和含氮杂环型亲核化合物的反应组成，该化合物包含可能代替离去基团的N-H型，从而产生碳 - 氮键 在铜催化剂存在下，在有机溶剂中存在碱，其特征在于所述含氮杂环与携带选自溴，氯或磺酸酯的一个离去基团（Y）的芳香族亲电子试剂反应，并且在 在铜催化剂存在下，在介电常数小于或等于的极性非质子有机溶剂中的选自脂族二胺，脂族氨基醇和二醇的萃取剂的至少一个电吸引组（Z1） 大约20岁，并且其“捐赠人数”小于约25的碱度。

    Method for preparing a benzylic-type ether
    40.
    发明授权
    Method for preparing a benzylic-type ether 失效
    苄型醚的制备方法

    公开(公告)号：US06608232B1

    公开(公告)日：2003-08-19

    申请号：US09869743

    申请日：2001-07-03

    申请人： Roland Jacquot ,  Michel Spagnol

    发明人： Roland Jacquot ,  Michel Spagnol

    IPC分类号： C07C4109

    CPC分类号： C07C45/46 ,  C07C41/09 ,  C07C41/30 ,  Y02P20/582 ,  C07C49/84 ,  C07C43/23 ,  C07C43/215

    摘要： The invention concerns a method for preparing a benzylic-type ether from an aromatic compound. The inventive method for preparing a benzylic-type ether from an aromatic compound is characterised in that it consists in: in a first step, acylating an aromatic compound by reacting said aromatic compound with an acylating agent, in the presence of an efficient amount of zeolite or a Friedel-Crafts catalyst leading to a ketonic compound; in a second step, reducing the carbonyl group into carbinol leading to a benzylic alcohol; in a third step, etherifying the hydroxyl group, by reacting the benzylic alcohol with another alcohol, in the presence of an efficient amount of zeolite.

    摘要翻译： 本发明涉及一种由芳族化合物制备苄型醚的方法。 从芳族化合物制备苄型醚的本发明方法的特征在于：在第一步中，通过使所述芳族化合物与酰化剂反应，在有效量的沸石 或通过引入酮化合物的Friedel-Crafts催化剂; 在第二步中，将羰基还原成苄醇，得到苄醇; 在第三步中，通过使苄醇与另一种醇反应，在有效量的沸石存在下，醚化羟基。