公开(公告)号：US3936429A

公开(公告)日：1976-02-03

申请号：US437564

申请日：1974-01-29

申请人： Yoshio Seoka ,  Masato Satomura ,  Akira Umehara

发明人： Yoshio Seoka ,  Masato Satomura ,  Akira Umehara

IPC分类号： C08F8/00 ,  C08F20/08 ,  G03F7/038 ,  C08F28/00 ,  C08G75/22 ,  G03C1/76

CPC分类号： G03F7/0388 ,  C08F20/08 ,  C08F8/00 ,  G03F7/038 ,  Y10S526/923

摘要： A quaternary salt-type reactive polymer composition comprising therein repeating monomer units represented by the following general formula ##SPC1##Wherein R represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; R.sub.1 represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxycarbonyl group, having 2 to 8 carbon atoms an aryl group, a carbamoyl group having 1 to 8 carbon atoms, a carboxy group, or an acyl group having 1 to 8 carbon atoms; R.sub.2 represents a hydrogen atom, a methyl group or a cyano group; R.sub.3 represents a hydrogen atom, a carbamoyl group having 1 to 8 carbon atoms, a nitro group, a cyano group, an alkoxy group having 1 to 3 carbon atoms or an alkoxy carbonyl group having 2 to 8 carbon atoms; Y represents a divalent radical having 1 to 12 carbon atoms; and X.sup.- represents a halogen atom, such as Br, Cl or I, an alkanesulfonyloxy group having 1 to 4 carbon atoms, an alkanesulfonyloxy group having 1 to 4 carbon atoms a styrenesulfonyloxy group, or an arylsulfonyloxy group having 6 to 10 carbon atoms. A preferred -Y- moiety is ##EQU1## wherein R.sub.4 represents ##SPC2##Wherein m is 0, 1, 2, or 3; p, q and r is 0 or 1; R.sub.5 represents a hydrogen atom or a methyl group.The quaternary salt-type functional polymer described above can be synthesized by reacting (1) a vinylpyridine with a halide or a sulfonic ester compound containing at least one unsaturated group or (2), a vinyl pyridine unit containing polymer with a halide or a sulfonic ester compound containing at least one unsaturated group, and processes for the preparation thereof.

摘要翻译： 包含其中由以下通式表示的重复单体单元的季盐型反应性聚合物组合物，其中R表示氢原子或具有1至4个碳原子的烷基; R1表示氢原子，碳原子数1〜6的烷基，碳原子数2〜8的烷氧基羰基，芳基，碳原子数1〜8的氨基甲酰基，羧基或具有1个碳原子的酰基 至8个碳原子; R2表示氢原子，甲基或氰基; R3表示氢原子，碳原子数1〜8的氨基甲酰基，硝基，氰基，碳原子数1〜3的烷氧基或碳原子数2〜8的烷氧基羰基。 Y表示碳原子数1〜12的二价基团。 X'表示卤素原子，例如Br​​，Cl或I，具有1至4个碳原子的烷磺酰氧基，具有1至4个碳原子的烷磺酰氧基，苯乙烯磺酰氧基或具有6至10个碳的芳基磺酰氧基 原子 优选的-Y-部分是-CH-R 4 - ，| R 5，其中R 4表示其中M为0,1,2或者3; P，Q和R是0或1; R5表示氢原子或甲基。