公开(公告)号：US20120245287A1

公开(公告)日：2012-09-27

申请号：US13472619

申请日：2012-05-16

申请人： Mehmet Demirors ,  Teresa P. Karjala ,  Christopher R. Eddy ,  Lonnie G. Hazlitt ,  Pak-Meng Cham ,  Sarat Munjal ,  Wallace W. Yau

发明人： Mehmet Demirors ,  Teresa P. Karjala ,  Christopher R. Eddy ,  Lonnie G. Hazlitt ,  Pak-Meng Cham ,  Sarat Munjal ,  Wallace W. Yau

IPC分类号： C08F110/02 ,  C08F2/01

CPC分类号： C08F255/02 ,  C08F110/02 ,  C08F255/00 ,  C08F297/08 ,  C08F297/083 ,  C08L23/0815 ,  C08L51/06 ,  C08L53/00 ,  C08L2666/02 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/20 ,  C08F2500/17 ,  C08F2500/07 ,  C08F2500/19

摘要： An ethylenic polymer comprising amyl groups from about 0.1 to about 2.0 units per 1000 carbon atoms as determined by Nuclear Magnetic Resonance and both a peak melting temperature, Tm, in ° C., and a heat of fusion, Hf, in J/g, as determined by DSC Crystallinity, where the numerical values of Tm and Hf correspond to the relationship Tm≧(0.2143*Hf)+79.643. An ethylenic polymer comprising at least one preparative TREF fraction that elutes at 95° C. or greater using a Preparative Temperature Rising Elution Fractionation method, where at least one preparative TREF fraction that elutes at 95° C. or greater has a gpcBR value greater than 0.05 and less than 5 as determined by gpcBR Branching Index by 3D-GPC, and where at least 5% of the ethylenic polymer elutes at a temperature of 95° C. or greater based upon the total weight of the ethylenic polymer.

摘要翻译： 包含通过核磁共振测定的约0.1至约2.0单位/ 1000个碳原子的乙烯基聚合物，峰值熔融温度Tm，℃，熔融热，Hf / J， 通过DSC结晶度测定，其中Tm和Hf的数值对应于Tm≥（0.2143×Hf）+79.643的关系。 包含至少一种使用制备型升温洗脱分级方法在95℃或更高洗脱的制备性TREF级分的乙烯性聚合物，其中至少一种在95℃或更高洗脱的制备性TREF级分的gpcBR值大于 通过3D-GPC通过gpcBR分枝指数测定的0.05和小于5，并且其中至少5％的乙烯类聚合物在基于乙烯类聚合物的总重量的95℃或更高的温度下洗脱。

公开(公告)号：US07579407B2

公开(公告)日：2009-08-25

申请号：US10428353

申请日：2003-05-03

申请人： Li-Min Tau ,  Yunwa Wilson Cheung ,  Charles F. Diehl ,  Lonnie G. Hazlitt

发明人： Li-Min Tau ,  Yunwa Wilson Cheung ,  Charles F. Diehl ,  Lonnie G. Hazlitt

IPC分类号： C08F8/00 ,  C08L23/00

CPC分类号： B32B27/32 ,  C08J5/18 ,  C08J2323/10 ,  C08L23/10 ,  C08L23/142 ,  C08L23/16 ,  C08L101/00 ,  C08L2205/02 ,  C08L2207/02 ,  C09K3/10 ,  C09K2200/0617 ,  C09K2200/062 ,  C08L2666/02 ,  C08L2666/06

摘要： A unique thermoplastic olefin composition having: (a) at least 40 percent by weight of a propylene-alpha olefin copolymer based on the total weight of polymers in the composition, the propylene-alpha olefin copolymer having at least 60 percent by weight units derived from propylene, at least 6 percent by weight units derived from an alpha olefin, a molecular weight distribution less than 3.5, and a broad composition distribution; and (b) at least 20 percent by weight of a polypropylene based on the total weight of polymers in the composition, the polypropylene having at least 93 percent by weight units derived from propylene, a molecular weight distribution of greater than 3.5, a heat of fusion greater than the heat of fusion exhibited by the propylene-alpha olefin copolymer, and a melting point Tmax of at least 120° C.

摘要翻译： 一种独特的热塑性烯烃组合物，其具有：（a）基于组合物中聚合物总重量的至少40重量％的丙烯-α烯烃共聚物，丙烯-α烯烃共聚物具有至少60重量％的衍生自 丙烯，至少6重量％衍生自α-烯烃的单元，分子量分布小于3.5，并具有宽的组成分布; 和（b）基于组合物中聚合物总重量的至少20重量％的聚丙烯，该聚丙烯具有至少93重量％的衍生自丙烯的单元，分子量分布大于3.5， 熔点大于丙烯-α烯烃共聚物所显示的熔化热，熔点Tmax至少为120℃。

公开(公告)号：US07459500B2

公开(公告)日：2008-12-02

申请号：US10429651

申请日：2003-05-05

申请人： Li-Min Tau ,  Yunwa Wilson Cheung ,  Charles F. Diehl ,  Lonnie G. Hazlitt

发明人： Li-Min Tau ,  Yunwa Wilson Cheung ,  Charles F. Diehl ,  Lonnie G. Hazlitt

IPC分类号： C08F8/00

CPC分类号： C09K3/10 ,  B32B27/32 ,  C08J5/18 ,  C08J2323/12 ,  C08J2367/02 ,  C08L23/10 ,  C08L23/142 ,  C08L23/16 ,  C08L101/00 ,  C09K2200/0617 ,  C09K2200/062 ,  C08L2666/06

摘要： A unique thermoplastic olefin composition having: (a) at least 40 percent by weight of a propylene-alpha olefin copolymer based on the total weight of polymers in the composition, the propylene-alpha olefin copolymer having at least 60 percent by weight units derived from propylene, at least 6 percent by weight units derived from an alpha olefin, a molecular weight distribution less than 3.5, and a broad composition distribution; and (b) at least 20 percent by weight of a polypropylene based on the total weight of polymers in the composition, the polypropylene having at least 93 percent by weight units derived from propylene, a molecular weight distribution of greater than 3.5, a heat of fusion greater than the heat of fusion exhibited by the propylene-alpha olefin copolymer, and a melting point Tmax of at least 120° C.

摘要翻译： 一种独特的热塑性烯烃组合物，其具有：（a）基于组合物中聚合物总重量的至少40重量％的丙烯-α烯烃共聚物，丙烯-α烯烃共聚物具有至少60重量％的衍生自 丙烯，至少6重量％衍生自α-烯烃的单元，分子量分布小于3.5，并具有宽的组成分布; 和（b）基于组合物中聚合物总重量的至少20重量％的聚丙烯，该聚丙烯具有至少93重量％的衍生自丙烯的单元，分子量分布大于3.5， 熔点大于丙烯-α烯烃共聚物所显示的熔化热，熔点Tmax至少为120℃。

公开(公告)号：US06982311B2

公开(公告)日：2006-01-03

申请号：US10210139

申请日：2002-07-31

申请人： Seema V. Karande ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kaelyn Koch ,  Shih-Yaw Lai ,  Li-Min Tau

发明人： Seema V. Karande ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kaelyn Koch ,  Shih-Yaw Lai ,  Li-Min Tau

IPC分类号： C08F210/16

CPC分类号： B32B27/32 ,  B32B2323/046 ,  B32B2323/10 ,  B32B2369/00 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08L101/00 ,  C08L2314/06 ,  Y10T428/24 ,  Y10T428/269 ,  C08L2666/04

摘要： The subject invention provides a film having at least one layer comprising an interpolymer of ethylene and at least on comonomer selected from the group consisting of C3-C20 α-olefins, dienes, and cycloalkenes, wherein the interpolymer is characterized as having a high degree of processability, good optical performance, and good mechanical properties. The subject invention further provides film fabrication processes and polymer compositions which are useful in preparing the subject films.

摘要翻译： 本发明提供一种膜，其具有至少一层，其包含乙烯和至少一种选自C 3 -C 20α-烯烃的共聚单体的互聚物， 二烯和环烯烃，其中互聚物的特征在于具有高加工性，良好的光学性能和良好的机械性能。 本发明还提供了可用于制备本发明膜的膜制造方法和聚合物组合物。