公开(公告)号：US5362872A

公开(公告)日：1994-11-08

申请号：US28899

申请日：1993-03-10

Applicant: Hans Baumann ,  Rox Phaff

Inventor： Hans Baumann ,  Rox Phaff

IPC: B01J13/02 ,  B41M5/136 ,  B41M5/145 ,  B41M5/20 ,  B41M5/327 ,  C07D471/14 ,  C07D487/04 ,  C07D487/14 ,  C07D498/04 ,  C07D498/14 ,  C09B57/00 ,  C07D265/12

CPC classification number: C07D498/04 ,  B41M5/145 ,  B41M5/327

Abstract: The invention relates to chromogenic lactams, to their preparation and to the use thereof in pressure-sensitive or heat-sensitive recording materials.The novel lactams have the general formula I ##STR1## wherein the ring A is an aromatic or heteroaromatic radical containing 6 ring atoms;the ring B is an unsubstituted or substituted benzene nucleus; andZ is ##STR2## R, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, X.sub.1 and X.sub.2 are as defined in the description.

Abstract translation: 本发明涉及发色内酰胺，其制备方法及其在压敏或热敏记录材料中的应用。 该新型内酰胺具有通式I（I）其中环A是含有6个环原子的芳族或杂芳族基团; 环B是未取代或取代的苯核; 并且Z是R，R1，R2，R3，R4，R5，R6，X1和X2如说明书中所定义。

公开(公告)号：US5329006A

公开(公告)日：1994-07-12

申请号：US755717

申请日：1991-09-06

Applicant: Hans Baumann ,  Ian J. Fletcher

Inventor： Hans Baumann ,  Ian J. Fletcher

IPC: B41M5/132 ,  B41M5/145 ,  B41M5/327 ,  C07D487/04 ,  C07D487/10 ,  C07D498/04 ,  C07D513/04

CPC classification number: B41M5/327 ,  B41M5/145 ,  C07D487/04 ,  C07D487/10 ,  C07D513/04

Abstract: Chromogenic lactam compounds of the formula ##STR1## in which the ring A is an aromatic or heteroaromatic radical which has 6 ring atoms and may contain a fused aromatic ring, it being possible for both the ring A and the fused ring to be substituted;the ring B is an unsubstituted or substituted benzene ring;Z is ##STR2## R is hydrogen; unsubstituted or substituted C.sub.1 -C.sub.12 alkyl, cycloalkyl having 5 to 10 carbon atoms; unsubstituted or substituted aryl or aralkyl; C.sub.1 -C.sub.12 acyl; N-(lower alkyl)carbamoyl; or N-arylcarbamoyl which is unsubstituted or substituted on the ring;Q is C.sub.1 -C.sub.12 alkylene, aryl-C.sub.1 -C.sub.4 alkylene, 1,2-cycloalkylene, 1,2- or 1,8-arylene or aralkylene; andX.sub.1 and X.sub.2, independently of one another, are each hydrogen; unsubstituted or substituted alkyl having a maximum of 12 carbon atoms; acyl having 1 to 8 carbon atoms; cycloalkyl having 5 to 10 carbon atoms; or unsubstituted or ring-substituted aralkyl or aryl; or (X.sub.1 and X.sub.2), together with the common nitrogen atom, are a five- or six-membered, preferably saturated, heterocyclic radical.These lactam compounds are particularly suitable as color formers in pressure- or heat-sensitive recording materials and give light-fast yellow, red, violet, blue, cyan or green shades.

Abstract translation: 式（1）的显色内酰胺化合物，其中环A是具有6个环原子并且可以含有稠合芳环的芳族或杂芳族基团，环A和稠环都可以是 取代 环B是未取代或取代的苯环; Z是氢; 未取代或取代的C 1 -C 12烷基，具有5至10个碳原子的环烷基; 未取代或取代的芳基或芳烷基; C1-C12酰基; N-（低级烷基）氨基甲酰基; 或未被取代或取代在环上的N-芳基氨基甲酰基; Q是C 1 -C 12亚烷基，芳基-C 1 -C 4亚烷基，1,2-亚环烷基，1,2-或者1,8-亚芳基或亚芳基; 且X 1和X 2彼此独立地为氢; 未取代或取代的具有最多12个碳原子的烷基; 具有1至8个碳原子的酰基; 具有5至10个碳原子的环烷基; 或未取代的或环取代的芳烷基或芳基; 或（X 1和X 2）与常见氮原子一起为5或6元，优选饱和的杂环基团。 这些内酰胺化合物特别适合作为压敏或热敏记录材料中的成色剂，并提供轻快的黄色，红色，紫色，蓝色，青色或绿色色调。

公开(公告)号：US4957847A

公开(公告)日：1990-09-18

申请号：US278989

申请日：1988-12-02

Applicant: Jean-Marie Adam ,  Hans Baumann

Inventor： Jean-Marie Adam ,  Hans Baumann

IPC: B41M5/323 ,  G03C1/52

CPC classification number: G03C1/52

Abstract: A heat-sensitive recording material comprising a base and, on top of the said base, a heat-sensitive layer containing a cyclic diazo component and a coupling component, the cyclic diazo component being a benzotriazine compound of the formula ##STR1## wherein Q is --CH.sub.2 --, --CO-- or --SO.sub.2 --, R is hydrogen, hydroxyl, or aryl or alkenyl, each unsubstituted or substituted by halogen, hydroxyl, cyano, lower alkoxy, lower alkylthio, acyloxy, lower alkoxycarbonyl or lower alkylsulfonyl, or is acyl, acyloxy or acylamino, cycloalkyl, or is aryl or aralkyl such as phenyl, phenylalkyl or naphthyl each unsubstituted or substituted on the ring by cyano, halogen, nitro, trifluoromethyl, lower alkyl, lower alkylthio, lower alkoxy, lower alkylcarbonyl or lower alkoxycarbonyl, or is a heterocyclic radical, and the benzene ring A is unsubstituted or substituted by halogen, cyano, nitro, lower alkyl, lower alkoxy, lower alkylthio, lower alkylcarbonyl or lower alkoxycarbonyl.

Abstract translation: 一种热敏记录材料，其包含碱，并且在所述碱的顶部上包​​含含有环状重氮组分和偶联组分的热敏层，所述环状重氮组分为下式的苯并三嗪化合物（1） 其中Q为-CH 2 - ， - CO - 或-SO 2 - ，R 2为氢，羟基或芳基或链烯基，各自未被取代或被卤素，羟基，氰基，低级烷氧基，低级烷硫基，酰氧基，低级烷氧基羰基或低级烷基磺酰基 或者是酰基，酰氧基或酰氨基，环烷基，或芳基或芳烷基，例如苯基，苯基烷基或萘基，其各自未被取代或在环上被氰基，卤素，硝基，三氟甲基，低级烷基，低级烷硫基，低级烷氧基，低级烷基羰基 或低级烷氧基羰基，或为杂环基，苯环A为未取代的或被卤素，氰基，硝基，低级烷基，低级烷氧基，低级烷硫基，低级烷基羰基或低级烷氧羰基取代。

公开(公告)号：US4544738A

公开(公告)日：1985-10-01

申请号：US190179

申请日：1980-09-24

Applicant: Hans Baumann ,  Hermann Kaack

Inventor： Hans Baumann ,  Hermann Kaack

IPC: C09B62/006 ,  C09B62/008 ,  C09B69/00 ,  C09B62/085 ,  C09B62/245 ,  C09B62/665

CPC classification number: C09B62/006 ,  C09B69/007

Abstract: A dye of the formula ##STR1## wherein R.sup.1 is is fluorine, chlorine, bromine, methyl, ethyl, cyano, carboxyl, nitro, tribfluoromethyl, methylsulfonyl, phenylsulfonyl, acetyl, C.sub.1 -C.sub.4 alkoxy, phenoxy, chlorophenoxy or benzoyl; R.sup.2 is hydrogen, chlorine, bromine, methyl, ethyl, C.sub.1 -C.sub.4 alkoxy, benzthiazol-2-yl, 6-methylbenzthiazol-2-yl, acetylamino, carboxyl aminosulfonyl, or aminocarbonyl; R.sup.3 is hydrogen chlorine, bromine or methyl; R.sup.5 is hydrogen, methyl, methoxy or ethoxy; and X is fluorohydroxyphosphonyl or dihydroxyphosphonyl. The dye of the present invention is useful in the dyeing of cellulose-containing material, polyamides and leather. The high tinctorial strength of the dyes and the very good lightfastness and wetfastness properties of the dyeings are particularly noteworthy.

Abstract translation: 氰基，羧基，硝基，三氟甲基，甲基磺酰基，苯基磺酰基，乙酰基，C 1 -C 4烷氧基，苯氧基，氯代苯氧基或苯甲酰基的式：其中R 1为氟，氯，溴，甲基， R2是氢，氯，溴，甲基，乙基，C1-C4烷氧基，苯并噻唑-2-基，6-甲基苯并噻唑-2-基，乙酰氨基，羧基氨基磺酰基或氨基羰基; R3是氢氯，溴或甲基; R5是氢，甲基，甲氧基或乙氧基; X是氟代羟基膦酰基或二羟基膦酰基。 本发明的染料可用于含纤维素材料，聚酰胺和皮革的染色。 染料的高着色强度和染色的非常好的耐光牢度和耐湿性能是特别值得注意的。

公开(公告)号：US4489002A

公开(公告)日：1984-12-18

申请号：US384945

申请日：1982-06-04

Applicant: Hans Baumann ,  Klaus Grychtol

Inventor： Hans Baumann ,  Klaus Grychtol

IPC: C09B45/06 ,  C09B55/00 ,  C09B45/02 ,  C09B45/16 ,  C09B45/48

CPC classification number: C09B45/06 ,  C09B55/001

Abstract: Compounds of the general formula I ##STR1## where E is --CH.dbd. or --N.dbd., K is the radical of an amine or of a coupling component of the benzene, naphthalene, pyrazole, pyridine, pyrimidine, quinoline or isoquinoline series, or the radical of a 1,3-dicarbonyl compound which can be coupled, X is --O-- or --COO--, Y is --O--, --COO-- or --NH--, Z.sup.1 and Z.sup.2 independently of one another are unsubstituted or substituted alkyl or cycloalkyl, and one of them may furthermore be unsubstituted or substituted aryl, or Z.sup.1 and Z.sup.2 together with the nitrogen atom are a heterocyclic radical, and Z is unsubstituted or substituted C.sub.2 - or C.sub.3 -alkylene, from 1 to 4 sulfonic acid groups can be present and the rings A and B can be further substituted or can carry a fused benzene ring.The compounds of the present invention are suitable for dyeing or printing natural or synthetic N-containing materials, i.e., wool, leather or polyamide or polyurethane fibers, as wells as for coloring inks. The colored salts with amine bases are insoluble in water, but soluble in organic solvent. These colored salts can be used for dyeing organic liquids, resins or surface coatings, wood stains, paste for ball point pens, for coloring anodized aluminum, or for spin-dyeing, i.e., cellulose ester fibers for polyamide fibers.

Abstract translation: 其中E是-CH =或-N =的通式I的化合物，K是苯或萘，吡唑，吡啶，嘧啶，喹啉或异喹啉系列的偶联组分的基团， 或可以偶合的1,3-二羰基化合物的基团，X是-O-或-COO-，Y是-O - ， - COO-或-NH-，Z 1和Z 2彼此独立地是未取代的或 取代的烷基或环烷基，其中一个还可以是未取代的或取代的芳基，或者Z1和Z2与氮原子一起是杂环基，Z是未取代的或取代的C2-或C3-亚烷基，1-4个磺酸 可以存在基团并且环A和B可以被进一步取代或可以携带稠合苯环。 本发明的化合物适用于染色或印刷天然或合成的含N材料，即羊毛，皮革或聚酰胺或聚氨酯纤维，如用于着色油墨的孔。 与胺碱的着色盐不溶于水，但溶于有机溶剂。 这些有色盐可用于染色有机液体，树脂或表面涂层，木材污渍，圆珠笔用糊料，阳极氧化铝着色或纺丝染色，即用于聚酰胺纤维的纤维素酯纤维。

公开(公告)号：US4424153A

公开(公告)日：1984-01-03

申请号：US295373

申请日：1981-08-24

Applicant: Hans Baumann ,  Klaus Grychtol

Inventor： Hans Baumann ,  Klaus Grychtol

IPC: C09B56/02 ,  C09B55/00 ,  C09B45/14

CPC classification number: C09B55/001

Abstract: 1:2 Chromium complexes of arylazo-azamethines of the general formula ##STR1## where A is a naphthalene or benzene radical which may be monosubstituted or polysubstituted by alkyl, alkoxy or halogen.

Abstract translation: 1：2通式为“IMAGE”的芳基偶氮 - 氮杂异构体的铬络合物，其中A是可被烷基，烷氧基或卤素单取代或多取代的萘​​或苯基。

公开(公告)号：US4390045A

公开(公告)日：1983-06-28

申请号：US184783

申请日：1980-09-08

Applicant: Hans Baumann

Inventor： Hans Baumann

IPC: D03C9/06 ,  D03D9/00

CPC classification number: D03C9/0625 ,  D03C9/0691

Abstract: A heddle frame stave for heddle frames includes a light metal hollow construction having, at least on one side wall, and preferably on opposing side walls, a flat groove-shaped recess. A flat steel strip is adhesively secured in the recess, the strip having a thickness of less than half the side wall thickness and covering preferably at least 60% of the surface of the side wall of the hollow stave. Vibration dampening of the heddle frame stave is thereby achieved, so that the sound produced due to vibrations and the noise development associated therewith, will be reduced considerably especially for fast running weaving machines.

Abstract translation: 用于综框的综框框架包括轻金属中空结构，其至少在一个侧壁上，优选地在相对的侧壁上具有平坦的凹槽形凹部。 扁平钢带粘合地固定在凹部中，该条具有小于侧壁厚度的一半的厚度，优选地覆盖中空壁的侧壁的表面的至少60％。 由此实现了综框框架的振动衰减，使得由于振动产生的声音和与之相关的噪声发展将大大降低，特别是对于快速运行的织机。

公开(公告)号：US4367771A

公开(公告)日：1983-01-11

申请号：US192858

申请日：1980-10-01

Applicant: Hans Baumann

Inventor： Hans Baumann

IPC: D03D51/30

CPC classification number: D03D51/30

Abstract: The connecting part for electrical warp stop motions on weaving machines has two rectangular housing shells (2,3) pressed against each other at their open sides by means of a threaded pin (10) screwed into the first housing shell (2). The screw-head of the threaded pin is in the shape of a knob (11) and presses against the second housing shell (3). In the longitudinal sides (4,6) of both housing shells (2,3) are supporting slots (9) at equal distances to take up the contact bars. On the interior base (12,15) of each housing shell (2,3) is a strip (13,16) of elastic material and on each strip a contact foil (14,17) for conducting electricity to all the contact bars, the narrow edges of which have perfect contact with the contact foils, even at varying height resulting from deviations in manufacture, due to the elastic material under them. A plug pin (18), in the second housing shell (3) is in direct electrical contact to the contact foil (17) in this housing shell and a further plug pin (19) is electrically connected to the contact foil (14) in the first housing shell (2) by means of a rod (23) on the exterior of the longitudinal side of the second housing shell and by means of the screw-head (11) and the threaded pin (10).

Abstract translation: 用于编织机上的电翘曲停止运动的连接部分具有通过螺纹连接到第一壳体壳体（2）中的螺纹销（10）在其开口侧彼此压靠的两个矩形壳体壳体（2,3）。 螺纹销的螺钉头是旋钮（11）的形状并且压靠第二壳体壳体（3）。 两个壳体（2,3）的纵向侧面（4,6）是相等距离的支撑槽（9）以吸收接触杆。 在每个壳体（2,3）的内部基座（12,15）上是弹性材料的条带（13,16），并且在每个条带上具有用于向所有接触杆传导电力的接触箔片（14,17） 其窄边缘与接触箔完全接触，即使在由于其下面的弹性材料而导致的制造偏差导致的变化的高度处。 在第二壳体壳体（3）中的插头销（18）与该壳体壳体中的接触箔片（17）直接电接触，并且另一插头销（19）电连接到接触箔片 所述第一壳体（2）通过杆（23）在所述第二壳体壳体的纵向侧的外部上并且借助于所述螺钉头（11）和所述螺纹销（10）。

公开(公告)号：US4280955A

公开(公告)日：1981-07-28

申请号：US47246

申请日：1979-06-11

Applicant: Hans Baumann

Inventor： Hans Baumann

IPC: C09B45/20 ,  C09B29/33 ,  D06P3/06 ,  D06P3/24

CPC classification number: C09B45/20

Abstract: A 1:2 cobalt complex of the formula ##STR1## and its alkali metal salts and ammonium salts and methods of preparing the same are disclosed. On wool and nylons, the compounds give yellow dyeings which exhibit good wetfastness and very good lightfastness.

Abstract translation: 公开了具有式“IMAGE”的1：2钴络合物及其碱金属盐和铵盐及其制备方法。 在羊毛和尼龙上，化合物产生黄色染色，其表现出良好的耐湿性和非常好的耐光性。

公开(公告)号：US4119622A

公开(公告)日：1978-10-10

申请号：US737720

申请日：1976-11-01

Applicant: Hans Baumann ,  Andreas Oberlinner

Inventor： Hans Baumann ,  Andreas Oberlinner

IPC: B41M5/136 ,  C09B29/00 ,  C09B29/036 ,  C09B29/06 ,  C09B29/24 ,  C09B29/08

CPC classification number: C09B29/24 ,  C09B29/0037 ,  C09B29/06 ,  Y10T428/25

Abstract: An azo compound useful in copying processes of the formula ##STR1## where R.sup.1 is hydrogen or alkyl of 1 to 4 carbon atoms, R.sup.2 and R.sup.3 are each alkyl of 1 to 4 carbon atoms, or one of the radicals R.sup.1, R.sup.2 and R.sup.3 is unsubstituted phenyl or phenyl substituted by alkyl of 1 to 4 carbon atoms, methoxy or ethoxy, and A denotes ##STR2## where R.sup.4 and R.sup.5 are each hydrogen; alkyl of 1 to 8 carbon atoms which may be substituted by hydroxy, alkoxy, halogen or alkoxycarbonyl; cyanoethyl; alkylcarbonyl with 1 to 3 carbon atoms in the alkyl; cyclohexyl; phenalkyl of 7 to 10 carbon atoms; or substituted or unsubstituted phenyl, or R.sup.4 is N,N-dialkylaminoalkyl or N,N-bisphenalkylaminoalkyl, or the group ##STR3## is a 5-membered or 6-membered saturated heterocyclic ring which may contain an --O-- or --S-- group as ring member, Y is hydroxy, alkyl, alkoxy, chlorine, bromine or alkylcarbonylamino, n is 0, 1 or 2, R.sup.6 and R.sup.7 are each hydrogen, alkyl of 1 to 4 carbon atoms, cyclohexyl or unsubstituted phenyl or phenyl substituted by alkyl or alkoxy, and Z is hydrogen, hydroxy, methoxy, ethoxy or a sulfonic acid group. The light absorption of the yellow to orange colored compounds (I) is displaced, upon protonation of the compounds, by 150 to 200 nm toward the longer wavelength range, i.e. the salts are violet to blue in color.The compounds (I) are suitable for the production of pressure-sensitive n.c.r. papers.

Abstract translation: 用于复制式（I）的方法的偶氮化合物，其中R 1是氢或1至4个碳原子的烷基，R 2和R 3各自是1至4个碳原子的烷基或基团R 1，R 2中的一个 且R 3为未取代的苯基或被1至4个碳原子的烷基取代的苯基，甲氧基或乙氧基，A表示其中R 4和R 5各自为氢; 可以被羟基，烷氧基，卤素或烷氧基羰基取代的1至8个碳原子的烷基; 氰乙基; 在烷基中具有1至3个碳原子的烷基羰基; 环己基 7至10个碳原子的苯基烷基; 或取代或未取代的苯基，或R4是N，N-二烷基氨基烷基或N，N-双酚烷基氨基烷基，或者“IMAGE”是5元或6元饱和杂环，其可以含有-O-或-S- 作为环成员，Y是羟基，烷基，烷氧基，氯，溴或烷基羰基氨基，n是0,1或2，R 6和R 7各自是氢，1至4个碳原子的烷基，环己基或未被取代的苯基或被 烷基或烷氧基，Z是氢，羟基，甲氧基，乙氧基或磺酸基。 当化合物质子化时，黄色至橙色化合物（I）的光吸收在较长波长范围内被移位150至200nm，即盐为紫色至蓝色。